Far Eastern New Century Corporation

Xin-An Lu

Shu-Wei Liu

Cheng-Han Chou

Ruey-Fen Liao

Fa-Chen Chi

Guei-San Chen

A method for purifying a crude 2,5-furandicarboxylic acid composition including 2,5-furandicarboxylic acid and 2-furoic acid is disclosed. The method includes the steps of: (a) mixing the crude 2,5-furandicarboxylic acid composition with a solvent solution that includes alcohol so as to obtain a mixture; (b) heating the mixture to permit full dissolution of the crude 2,5-furandicarboxylic acid composition in the solvent solution; and (c) cooling the mixture to permit recrystallization of the 2,5-furandicarboxylic acid from the mixture so as to obtain purified 2,5-furandicarboxylic acid.

Method for purifying crude 2,5-furandicarboxylic acid composition

A method for purifying a crude 2,5-furandicarboxylic acid composition including 2,5-furandicarboxylic acid and 5-formylfuran-2-carboxylic acid is disclosed. The method includes the steps of: (a) subjecting the crude 2,5-furandicarboxylic acid composition to complete dissolution in a solvent solution to obtain a mixture, the solvent solution including an organic solvent and water; (b) subjecting 5-formylfuran-2-carboxylic acid in the mixture to an addition reaction with sodium hydrogen sulfite to obtain an addition product; and (c) subjecting 2,5-furandicarboxylic acid to precipitation after step (b) to obtain purified 2,5-furandicarboxylic acid.

A method for producing terephthalic acid comprises the steps of: subjecting methyl acrylate to contact with aluminum chloride so as to form a complex; adding isoprene to the complex to result in a Diels-Alder reaction which is kept at a temperature no higher than 50&#xb0; C. by cooling so as to obtain a cyclic adduct product; subjecting the cyclic adduct product to separation so as to obtain a cyclic para-precursor; and subjecting the cyclic para-precursor to a chemical reaction so as to obtain terephthalic acid.

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Taipei, Taiwan

Xin-An Lu