Planet Polymer Technologies, Inc.

Agway Inc.

Nv Bekaert Sa

Xiaoming Yang

Robert J Petcavich

Lijun Mao

Li Yang

Robert H Stock

Raymond B Turner

Stephen M Emanuele

Douglas Merrill

A process for the continuous dyeing of plastic films, such as polyethylene terephthalate, is characterized by passing the film through a dye bath comprised of dye stuffs dissolved, suspended or dispersed in a liquid carrier comprised at least in part of a polymer, preferably a polyol, having at least one free hydroxyl group and a molecular weight within the range of from about 200 to about 600. The hydrogen bonding provided by the hydroxyl group, together with the high molecular weight and high boiling point of the polyol, mitigate against migration of the dye stuff out of the film, i.e., fading of the film, and impart long lasting color fastness to the film. Rapid diffusion of the dye bath into the film is enhanced by thermal and ultrasonic energization of the bath.

Color dyeing system for plastic films

Controlled release urea-based feed supplements for ruminant animals and controlled release urea-based plant nutrients are comprised of particles or granules comprised in whole or in principal part of urea or having urea at or on the exterior surfaces thereof, and a moisture resistant interpenetrating polymer network coating on the particles comprised of the reaction products of urea and a polyisocyanate, and the reaction products of polyisocyanate, an alkyd resin having at least one double bond in each repeat unit and an oil having at least one double bond, the double bonds being reactive with one another and with themselves. The coated plant nutrients have a substantially linear rate of release of nutrients to the soil over a controlled period of time, e.g., 30 to 120 days. The coated ruminant feed supplements have a substantially linear rate of NPN release in the rumen over a controlled period of time, e.g., 12 to 24 hours. The ratio of nutrients to control agents is high, controlled release is achieved at minimal expense, and the products are economical to use.

Controlled release urea-based products

This invention provides a ruminant feedstock with a content of non-protein nitrogen supplement which yields a safe controlled-release generation of ammonia under rumen incubation conditions. In another embodiment, this invention provides a ruminant feedstock supplement for controlled-release of non-protein nitrogen which comprises urea particles encapsulated with a rumen-degradable polymeric coating.

Feedstock for ruminants with controlled-release non-protein nitrogen

Fresh produce is preserved by coating the exterior surface of the produce with a coating composition comprising an aqueous solution of from about 0.5 to about 4 percent by weight of a cellulose derivative, preferably sodium carboxymethylcellulose, from about 0.05 to about 0.5 percent by weight of konjac, and from about 0.03 to about 0.1 percent by weight of surfactant, preferably dioctyl sodium sulfosuccinate. Optional constituents include antimicrobials, plasticizers and antifoaming agents. The coating composition is effective to control respiratory exchange, i.e., the passage of gases, particularly oxygen, ethylene, carbon dioxide and water vapor, into and out of the produce, thereby to control maturation and ripening of the produce.

Process for preserving fresh produce

Fresh produce is preserved by coating the exterior surface of the produce with a coating composition comprising an aqueous solution of from about 1 to about 20 percent by weight of substantially hydrolyzed cold water insoluble polyvinyl alcohol, about 0.1 to about 10 percent by weight of low molecular weight cold water soluble starch, and about 0.03 to about 5 percent by weight of surfactant. Optional constituents include antimicrobials and plasticizers. The coating composition is effective to control respiratory exchange, i.e., the passage of gases, particularly oxygen, ethylene and carbon dioxide, into and out of the produce, thereby to control maturation and ripening of the produce.

Process for preventing fresh produce and coating composition therefor

A powder injection molding composition or feedstock is made of 70% or more by weight of a powdered metal or ceramic and 30% or less by weight of a binder system. The binder system contains a sufficient amount of polypropylene or polyethylene to hold the so-called brown preform of the molded metal or ceramic powder together for the sintering step of the injection molding process and a sufficient amount of partially hydrolyzed cold water soluble polyvinyl alcohol water and plasticizer to facilitate molding of the composition into the so- called green preform of the article to be manufactured. The debinding step of the injection molding process for transforming the green preform into the brown preform consists simply of immersing the green preform in water at ambient temperature to dissolve the polyvinyl alcohol. The binder system is nonhazardous, safe, harmless and fully degradable.

Powder and binder systems for use in metal and ceramic powder injection

A powder injection molding composition or feedstock is made of 70% or more by weight of a powdered metal or ceramic and 30% or less by weight of a binder system. The binder system contains a sufficient amount of polypropylene or polyethylene to hold the so-called brown preform of the molded metal or ceramic powder together for the sintering step of the injection molding process and a sufficient amount of partially hydrolyzed cold water soluble polyvinyl alcohol, water and plasticizer to facilitate molding of the composition into the so-called green preform of the article to be manufactured. The debinding step of the injection molding process for transforming the green preform into the brown preform consists simply of immersing the green preform in water at ambient temperature to dissolve the polyvinyl alcohol. The binder system is nonhazardous, safe, harmless and fully degradable.

Plant nutrients that are released in soil over a controlled period of time are comprised of plant nutrient particles containing urea and on the surface of the particles a water insoluble, biodegradable, interpenetrating polymer network comprised of a biuret, a urethane and tung oil; more specifically, an interpenetrating network comprised of the reaction product of the urea and an isocynate reactive with urea, the reaction product of the isocyanate and an alcohol reactive with isocyanate to form a urethane, and the reaction product of the urethane and tung oil. A method of making the controlled release plant nutrient conveniently and economically is also disclosed.

Controlled release plant nutrients

Cold water insoluble, hot water soluble and/or dispersible, disposable films, fabrics and other useful articles of manufacture are formed from a miscible polymeric resin blend comprised of cold water soluble partially hydrolyzed polyvinyl alcohol, cold water insoluble hot water disintegrable aliphatic polyester, and minor proportions of processing and performance aids. The aliphatic polyester has a melt temperature above the normal body temperature of a human (37 degrees C.; 98.6 degrees F.) and is present in the resin blend at a concentration sufficient to constitute the continuous phase of the blend, with the polyvinyl alcohol constituting a discontinuous phase of the blend. The aliphatic polyester thus renders the resin blend, and the partially hydrolyzed polyvinyl alcohol in the blend, cold water insoluble and determines the temperature at which articles formed from the blend will be subject to dissolution in an aqueous bath and subsequent disposal in an environmentally and ecologically sound fashion.

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San Diego, CA, United States of America

Xiaoming Yang