China Petroleum & Chemical Corporation

Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation

Xiaofan Zhang

Haitao Liu

Jie Lin

Zifang Guo

Junling Zhou

Jing Yan Ma

Xiaoxia Cai

Mingzhi Gao

Changxiu Li

Jianhua Chen

Jixing Ma

Junhui Zhang

Qingqiang Gou

Ming Wang

Hui Zhao

Rong Gao

Dongbing Liu

Xianzhong Li

Xinyang Li

Jianjun Hu

Jingyan An

Jingjing Lai

Yuanning Gu

Yan Li

Jie Fu

Zhihui Zhang

Ting Huang

Zhufang Sun

Ruilin Duan

Changyou Ma

Linna Yang

Tingjie Huang

Meiyan Fu

Yu Wang

Dong Ma

Shijun Zhang

Jin Zhao

Xianzhi Xia

Wenbo Song

Jigui Zhang

Lunjia Xie

Hongtao Wang

Shiyuan Xu

Hongxu Yang

Lin Qi

Peng Kou

Bingyi Li

Ruen Wang

Jing Ma

Yonghua Ma

Wei Cen

Lian Yan

Yanhong Wan

A diimine metal complex represented by Formula I, a preparation method therefor, and application thereof are provided. The complex is used as a main catalyst in catalysts for olefin polymerization, and can achieve catalytic ethylene polymerization at a high temperature to prepare high molecular weight branched polyethylene.

Diimine metal complex, preparation method therefor, and application thereof

A method for preparing an olefin-olefinic alcohol copolymer and an olefin-olefinic alcohol copolymer prepared by the method are provided. The catalyst used in the method for preparing the olefin-olefinic alcohol copolymer has a diimine metal complex as shown in Formula I.

Method for preparing olefin-polar monomer copolymer

An amino-imine metal complex represented by Formula I, its preparation method and an application thereof are provided. The complex is used as a main catalyst in catalysts for olefin polymerization, and can catalyze the polymerization of ethylene at a relatively high temperature to prepare branched polyethylene having high molecular weight.

Amino-imine metal complex and preparation method therefor and application thereof

A catalyst system for olefin polymerization contains a main catalyst and a cocatalyst. The cocatalyst contains a twelve-membered ring compound represented by formula (M). The catalyst system is suitable for preparing polypropylene products having high stereoregularity and low ash, and can regulate the melt index of the products within a wide range by adjusting the amount of hydrogenation. It is also suitable for copolymerization systems to improve the copolymerization yield.

Catalyst system for olefin polymerization and use thereof

The present invention discloses a Ziegler-Natta catalyst system for olefin polymerization, comprising at least one compound represented by formula (I) as (i) an internal electron donor, (ii) an external electron donor, or (iii) the both, wherein M, M, M, M, M, M, M', M&#x2032;, M&#x2032;, M&#x2032;, M&#x2032; and M&#x2032; are each independently selected from the group consisting of hydrogen, hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, &#x2014;Rand &#x2014;OR, wherein Rand Rare each independently a C-Chydrocarbyl, which is unsubstituted or substituted by a substituent selected from the group consisting of hydroxy, amino, aldehyde group, carboxy, acyl, halogen atoms, C-Calkoxy and heteroatoms; and wherein, when among M-Mand M&#x2032;-M&#x2032;, any two adjacent groups on the same phenyl ring are each independently selected from the group consisting of Rand &#x2014;OR, the two adjacent groups may optionally be linked to form a ring, with a proviso that M, M, M, M, M, M, M&#x2032;, M&#x2032;, M&#x2032;, M&#x2032;, M&#x2032; and M&#x2032; are not simultaneously hydrogen. 

Olefin polymerization catalyst comprising cyclotriveratrylene and derivatives thereof

The present invention provides a catalyst component for olefin polymerization, obtained by a reaction of magnesium, titanium, halogen and an internal electron donor, the internal electron donor comprising an imine compound as shown in Formula Z. The present invention also provides a preparation method of the catalyst component, and a catalyst for olefin polymerization containing the same. When the catalyst of the present invention is used for olefin polymerization reaction, the catalyst has a high activity, and a slow rate of activity decay, and the obtained polymer has a high isotacticity index, and a wide molecular weight distribution. 

Catalyst component for olefin polymerization, and catalyst containing the same

The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C-Chydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C-Calkyl, C-Caryl, C-Cheteroaryl, C-Calkylaryl and C-Carylalkyl; Rand Rmay be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C-Chydrocarbyl, preferably from hydrogen and substituted or unsubstituted C-Calkyl, C-Caryl, C-Calkylaryl and C-Carylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.

Catalyst component for propene polymerization, preparation method thereof, and catalyst containing the same

The present disclosure provides a solid catalyst component for olefin polymerization, comprising magnesium, titanium, a halogen, and an electron donor, wherein the electron donor is at least one selected from the group consisting of diol diester compounds as shown in Formula (I). The catalyst according to the present disclosure has significantly improved polymerization activity, hydrogen response, and stereoselectivity. According to the present disclosure, when the catalyst system containing a diol diester compound as shown in Formula (I) of the present disclosure is used in olefin polymerization, the catalyst shows good comprehensive performance, including high catalytic activity. In particular, in the presence of highly concentrated hydrogen, the catalyst has an improved hydrogen response and/or isotacticity of the polymers obtained can be significantly improved. The catalyst of the present disclosure is beneficial for obtaining polymers with a high melt index and high isotacticity, and for development of polymers of different grades. 

Catalyst component for olefin polymerization, catalyst, and use thereof

A catalyst component for olefin polymerization comprising magnesium, titanium, halogen and electron donor, wherein the electron donor is selected from at least one of the diol diester compounds, when the diol diester comprised contains a certain amount of isomer with Fischer projection formula as shown in Formula (II), the activity and stereospecificity of the catalyst are greatly improved, especially in the production of polymers with high melt index, the isotactic index of the obtained polymers is improved substantially. 

Catalyst component for olefin polymerization reaction and catalyst comprising same

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Beijing, China

Xiaofan Zhang