Xi'an Modern Chemistry Research Institute

Xiaobo Tang

Bo Wang

Wei Zhang

Hui Ma

Zhenhua Zhang

Jian Lv

Wei Mao

Jijun Zeng

Yujie Gu

Zhiqiang Yang

A process for the joint preparation of 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropene, comprising: (a) starting materials comprising at least one compound having the structure of formula I, II or III are reacted with hydrogen fluoride, producing 1,2,3-trichloro-3,3-difluoropropene, 1,2,3-trichloro-1,1,2-trifluoropropane, and 1,2,3-trichloro-1,1,3-trifluoropropane; in the compounds of said formulae CFCl&#x2550;CCl&#x2014;CHFCl(Formula I), CFClCHCl&#x2550;CHCl (Formula II), and CFClCFClCHFCl(Formula III), m=0, 1, 2; n=1, 2; p=2, 3; x=1, 2, 3; y=1, 2; z=1, 2 and 4&#x2266;x+y+z&#x2266;6; (b) the 1,2,3-trichloro-3,3-difluoropropene, 1,2,3-trichloro-1,1,2-trifluoropropane and 1,2,3-trichloro-1,1,3-trifluoropropane undergo dechlorination, producing 3-chloro-3,3-difluoropropyne, 3-chloro-2,3,3-trifluoropropene and 3-chloro-1,3,3-trifluoropropene; and (c) the 3-chloro-3,3-difluoropropyne, 3-chloro-2,3,3-trifluoropropene and 3-chloro-1,3,3-trifluoropropene are reacted with hydrogen fluoride, simultaneously yielding 1,3,3,3-tetrafluoropropene and 2,3,3,3-tetrafluoropropen.

Process for the joint preparation of 1, 3, 3, 3-tetrafluoropropene and 2, 3, 3, 3-tetrafluoropropene

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Shaanxi, China

Xiaobo Tang