China University of Petroleum

Xianzhu Wu

Guancheng Jiang

Lili Yang

Yinbo He

Fan Liu

Deli Gao

Xianmin Zhang

Liexiang Han

Guangchang Ma

Junbin Chen

Li Li Zhao

Yang Xuan

Haifang Sun

Gang Qu

Chunyao Peng

Wei Ouyang

Taotao Luo

Shuo Zhang

Yong Wang

Xi Wang

Zhong Xian Li

Yanjun Li

Yongqing Zhang

Jienian Yan

Xiangzeng Wang

Hongguo Zuo

Wei Ou'Yang

Jinsheng Sun

Le Wang

Lan Jun Wang

Tengfei Dong

Xiaolin Pu

Xiaoxiao Ni

Ranran Song

Wei Ou Yang

The present invention relates to the well drilling field in petrochemical industry, in particular to use of dual-cation fluorocarbon surfactant as amphiphobic wettability reversal agent in drilling fluid. The dual-cation fluorocarbon surfactant is a dual-cation fluorocarbon surfactant of which the cation part is represented by the following formula (1). The dual-cation fluorocarbon surfactant of the present invention can serve as wettability reversal agent when it is used for oil-gas drilling to enable rock amphiphobic, and is an amphiphobic wettability reversal agent which can cause rock surface to be non-hydrophilic and non-lipophilic. Using of dual-cation fluorocarbon surfactant, especially when drilling highly hydrous mud shale, can avoid permeation of water and oil into the rock effectively and thereby a capillary phenomenon can be prevented, and an effect of stabilizing the well wall and protecting the reservoir is attained. 

Use of dual-cation fluorocarbon surfactant as amphiphobic wettability reversal agent in drilling fluid

The present invention relates to well drilling field in the petroleum industry, particularly to accelerator used for drilling fluids, water-based drilling fluid and usage thereof. The accelerator contains: sulfonated polyglycerol long-chain fatty acid ester, fatty alcohol polyoxyethylene ether, alcohol ether carboxylate, glycidyl ether, and polyoxyethylene alkylphenol ether; wherein, the weight ratio of the sulfonated polyglycerol long-chain fatty acid ester:the fatty alcohol polyoxyethylene ether:the alcohol ether carboxylate:the glycidyl ether:the polyoxyethylene alkylphenol ether is 100:1-10:0.5-10:1-10:1-10. The accelerator provided in the present invention can lubricate the drill bit and drilling tool, prevent accumulation of drill cuttings, reduce friction, and improve rate of penetrate.

Accelerator used for drilling fluids, water-based drilling fluid and usage thereof

The present invention relates to the well drilling field in the petroleum industry, particularly to film former used for coal-bed gas well drilling and preparation method thereof, drilling fluid and usage thereof. The preparation method of the film former includes: (1) controlling polycaprolactone diol and diisocyanate to have a first polymerization reaction in the presence of a polyurethane catalyst, to obtain a polyurethane prepolymer with two ends blocked by diisocyanate; (2) controlling the product of the first polymerization reaction to have a chain extension reaction with a polyalcohol; (3) controlling the product of the chain extension reaction and one part of hydroxyalkyl acrylate monomer to have an additive reaction, and then introducing the other part of hydroxyalkyl acrylate monomer and a styrene monomer, and emulsifying in water to obtain an emulsion; (4) mixing a radical initiator with the emulsion to have a second polymerization reaction.

Film former used for coal-bed gas well drilling and preparation method thereof, drilling fluid and usage thereof

The present invention relates to the well drilling field in petrochemical industry, and discloses a drilling fluid additive composition comprising a nano-plugging agent, a bionic wall bracing agent, a bionic shale inhibitor, an emulsifier, and an amphiphobic wettability reversal agent, wherein, the nano-plugging agent is modified silicon dioxide nano-particle, and its modifying group includes a modifying copolymer chain; the bionic wall bracing agent is carboxymethyl chitosan with a dopamine-derived group grafted on its main chain; the bionic shale inhibitor is composed of structural units of arginine and structural units of lysine; and the amphiphobic wettability reversal agent is a dual-cation fluorocarbon surfactant. The present invention further provides a pseudo oil-based drilling fluid suitable for horizontal shale gas wells containing the above composition. When the water-based drilling fluid contains the drilling fluid additive composition provided in the present invention, the water-based drilling fluid would have high temperature-resistance, high plugging and high inhibition performance, is environment friendly, especially have high density, and is especially suitable for horizontal shale gas well mining.

Drilling fluid additive composition and pseudo oil-based drilling fluid suitable for horizontal shale gas wells

The present invention relates to the well drilling field in petrochemical industry, and discloses a high-density water-based drilling fluid suitable for horizontal shale gas wells comprising a nano-plugging agent, a bionic wall bracing agent, a bionic shale inhibitor, a filler, an emulsifier, and an amphiphobic wettability reversal agent, wherein, the nano-plugging agent is modified silicon dioxide nano-particle, and its modifying group includes a modifying copolymer chain; the bionic wall bracing agent is carboxymethyl chitosan with a dopamine-derived group grafted on its main chain; the bionic shale inhibitor is composed of structural units of arginine and structural units of lysine; the filler consists of calcium carbonate of 1,600-2,500 mesh, calcium carbonate of 1,050-1,500 mesh, and calcium carbonate of 500-1,000 mesh at a weight ratio of 1:0.55-6:0.55-6; and the amphiphobic wettability reversal agent is a dual-cation fluorocarbon surfactant. The drilling fluid provided herein is suitable for use in shale gas mining.

High-density water-based drilling fluid suitable for horizontal shale gas wells

The present invention relates to the well drilling field in petrochemical industry, and discloses a drilling fluid additive composition and water-based drilling fluid suitable for horizontal shale gas wells. The composition comprises a nano-plugging agent, a bionic wall bracing agent, a bionic shale inhibitor, an emulsifier, and an amphiphobic wettability reversal agent, wherein, the nano-plugging agent is modified silicon dioxide nano-particles, and its modifying group includes an acrylic copolymer chain; the bionic wall bracing agent is carboxymethyl chitosan with a dopamine-derived group grafted on its main chain; the bionic shale inhibitor is composed of structural units of arginine and structural units of lysine; and the amphiphobic wettability reversal agent is a dual-cation fluorocarbon surfactant. The drilling fluid containing the additive composition provided in the present invention has high temperature-resistance, high plugging and high inhibition performance, is environment friendly, especially has high density, and is applicable to shale gas mining.

Drilling fluid additive composition and water-based drilling fluid suitable for horizontal shale gas wells

The present invention relates to the well drilling field in petrochemical industry, and discloses an environment-friendly water-based drilling fluid applicable to horizontal shale gas wells comprising a nano-plugging agent, a bionic wall bracing agent, a bionic shale inhibitor, a filler, an emulsifier, and an amphiphobic wettability reversal agent, wherein, the nano-plugging agent is modified silicon dioxide nano-particle, and its modifying group includes an acrylic copolymer chain; the bionic wall bracing agent is carboxymethyl chitosan with a dopamine-derived group grafted on its main chain; the bionic shale inhibitor is composed of structural units of arginine and structural units of lysine; the filler consists of calcium carbonate of 1,600-2,500 mesh, calcium carbonate of 1,050-1,500 mesh, and calcium carbonate of 500-1,000 mesh at a weight ratio of 1:0.55-6:0.55-6; and the amphiphobic wettability reversal agent is a dual-cation fluorocarbon surfactant. The drilling fluid provided in the present invention has high temperature-resistance, high plugging and high inhibition performance, is environment friendly, especially has high density, and is applicable to shale gas mining.

Environment-friendly water-based drilling fluid applicable to horizontal shale gas wells

The present subject matter relates to the drilling fluid field, and discloses a bionic drilling fluid and a method for preparation of the bionic drilling fluid. The bionic drilling fluid comprises a specific bionic wall bracing agent, a bionic shale inhibitor, a filtrate reducer, and an amphiphilic reservoir protectant, wherein, the filtrate reducer comprises microcrystalline cellulose. The bionic drilling fluid provided in the present subject matter can effectively solve the problem of well wall instability, and has great industrial application prospects.

Bionic drilling fluid and preparation method thereof

The present invention provides a biomimetic polymer for stabilizing wellbore, a method for preparation of the biomimetic polymer, and a drilling fluid. The polymer contains carboxymethyl chitosan that serves as a backbone and dopamine-derived groups grafted on the backbone. The polymer provided in the present invention can improve the strength of shale in the wellbore, seal the shale pores and reduce the filter loss of drilling fluid, and thereby attains an effect of stabilizing the wellbore in shale formation in drilling process.

Biomimetic polymer for stabilizing wellbore and method for preparation of the same and drilling fluid

Method for preparation of biomimetic polymer for stabilizing wellbore and drilling fluid

The present subject matter relates to an amphiphilic reservoir protecting agent, including structural units denoted by the following formula (1), (2), (3) and (4). The present subject matter further provides a method for preparation of an amphiphilic reservoir protecting agent. The present subject matter further provides a drilling fluid that contains the amphiphilic reservoir protecting agent. The amphiphilic reservoir protecting agent and drilling fluid obtained in the present subject matter have high reservoir protection property and high shale inhibition property. 

Amphiphilic reservoir protecting agent and preparation method thereof and drilling fluid

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Beijing, China

Xianzhu Wu