Petrochina Company Limited

Tsinghua University

Huaneng Clean Energy Research Institute

Xianming Xu

Yali Wang

Libo Wang

Tong Liu

Yan Jiang

Zhixiang Zhang

Sihan Wang

Yulong Wang

Xiuhui Wang

Guizhi Wang

Fuling Huang

Buwei Yu

Hongling Chu

Fengrong Wang

Hongliang Huo

Fangwei Li

Yuanyuan Cao

Kecun Ma

Enhao Sun

Wei Zhang

Chang Zhang

Ning Zhang

Han Gao

Huan Zhang

Jinyi Wang

Pengjie Wang

Yong Jin

Jianzhong Li

Yinghui Li

Xuemei Han

Weihong Guan

Yunguang Han

Huaiqi Shao

Huimin Yuan

Shubao Wan

Fengbo Ma

Jing Wei

Jina Zhao

Lijun Liu

Dawei Zhang

Wenpeng Li

Fengshou Xiao

Haicheng Xiao

Ruhai Lin

Fujian Liu

Xiangju Meng

Xiangmin Yu

Kezhong Xu

Guoquan Song

Haotian Pei

Legang Feng

Qunying Zeng

Yueman Li

Zhongtao Zhang

Zhibo Ren

Yi Cheng

Xuli Zhai

A method for preparing a COF-protected electrode and an electrode are provided. The method includes mixing an organic framework, a small molecular organic acid and a solvent, adding a polar aqueous solution containing a substrate thereto, mixing the above uniformly and heating the system at a low temperature under an inert atmosphere, filtering the solution to obtain precipitates, washing and drying the precipitates to obtain a COF film grown on a surface of the substrate; coating a protective layer on the COF film to obtain a substrate/COF/protective layer film; etching off the substrate to obtain a COF/protective layer film; and transferring the COF/protective layer film to a surface of the electrode, and removing the protective layer.

Method for preparing COF-protected electrolytic hydrogen production electrode

The present invention provides a low viscosity poly-&#x3b1;-olefin lubricating oil and a synthesis method thereof. The method comprises: (1) the &#x3b1;-olefin raw material is subjected to dehydration treatment so that the water content in the raw material is &#x2264;10 ppm; (2) a reaction of the dehydration treated &#x3b1;-olefin raw material is carried out in the presence of a complex catalyst and gaseous BFto obtain a reaction product, wherein the pressure of the gaseous BFis 0.01 to 1 MPa; (3) the reaction product obtained in step (2) is sequentially subjected to flash distillation, gas stripping, centrifugation, and washing treatment to obtain an intermediate product; (4) the intermediate product obtained in step (3) is subjected to distillation under reduced pressure to separate the unreacted &#x3b1;-olefin raw material and &#x3b1;-olefin dimers, and the remaining heavy fractions are subjected to hydrogenation saturation treatment followed by fractionation and cutting-off.

Low viscosity poly-a-olefin lubricating oil and synthesis method thereof

The present disclosure provides a method and a catalyst for selective oligomerization of ethylene. The raw material for the catalyst consists of a dehydropyridine annulene-type ligand, a transition metal compound, and an organometallic compound in a molar ratio of 1:0.5-100:0.1-5000. The present disclosure also provides a method for selective oligomerization of ethylene accomplished by using the above-mentioned catalyst. The catalyst for selective oligomerization of ethylene has high catalytic activity, high selectivity for the target products 1-hexene and 1-octene, and low selectivity for 1-butene and 1-C.

Method and catalyst for selective oligomerization of ethylene

A method for preparing catalyst coating on a metal base plate comprising: thermal-spraying a layer of &#x3b1;-aluminum oxide nano-particles on a metal base plate using a high temperature flame powder spray gun, at a temperature of 2500-3500&#xb0; C. and a pressure of 0.2-1.2 MPa; coating an aluminum sol, the weight concentration of the aluminum sol aqueous solution being 2-30%, at a pH of 0.5-4, the drying temperature being 50-150&#xb0; C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200&#xb0; C., and the calcination time being 0.5-24 hours; immersing in an active component, the immersing temperature being 20-120&#xb0; C., the duration being 0.5-24 hours, the drying temperature being 50-150&#xb0; C., the drying time being 0.5-24 hours, the calcination temperature being 200-1200&#xb0; C., and the calcination time being 0.5-24 hours. The method is suitable for the preparation of various catalyst coatings with active components.

Method for preparing catalyst coating on metal base plate

The invention relates to a catalyst for the catalytic esterification and acylation reaction. The catalyst is prepared by the steps of adding a divinyl benzene monomer into a solvent prepared by mixing azobisisobutyronitrile, tetrahydrofuran and water, performing hydrothermal treatment at the normal temperature under the constant pressure, and volatilizing the solvent at the room temperature to obtain polydivinylbenzene; grinding the polydivinylbenzene into 200-mesh powder and performing degassing treatment under the nitrogen condition; adding polydivinylbenzene blocks into 1,1',2-trichloroethane to explode and crack into small blocks, wherein the small blocks swell; evenly mixing 1,1&#x2032;,2-trichloroethane and concentrated sulfuric acid, adding silver sulfate serving as a catalyst, adding processed polydivinylbenzene, performing sulfonation, filtering and washing with dioxane and water till it is neutral, performing drying, using dilute sulphuric acid to activate, performing washing till the it is neutral and performing drying. The catalyst has high catalytic activity and conversion rate.

Use of organic framework porous solid acid

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Beijing, China

Xianming Xu