USA As Represented by Secretary of the Navy

Woohong Kim

Jasbinder Singh Sanghera

Ishwar Dayal Aggarwal

Shyam S Bayya

Guillermo R Villalobos

Colin C Baker

Bryan Sadowski

Jason D Myers

Vinh Q Nguyen

Jesse A Frantz

Daniel Joseph Gibson

L Brandon Shaw

Michael Hunt

Darryl A Boyd

Rafael R Gattass

Walter J Dressick

Steven R Bowman

Zakya H Kafafi

Edward J Friebele

Rajesh Thapa

Benjamin Rock

Frederic Hau Kung

Alex E Moser

Daniel L Rhonehouse

Robert E Miklos

Gryphon A Drake

Gary P Kushto

Christopher G Brown

Nia A Pollard

Frederic H Kung

A polymer comprising one or more chalcogenide elements and one or more crosslinking moieties. The crosslinking moieties may be organic, inorganic, or both. Also disclosed is the related method for making a polymer comprising purifying a chalcogenide polymer powder comprising one or more chalcogenide elements, melting the purified chalcogenide polymer powder, adding one or more crosslinking moieties to the melted chalcogenide polymer, and curing the modified chalcogenide polymer at a temperature between 150 and 200° C.

Organically modified chalcogenide polymers

Methods for synthesizing fibers having nanoparticles therein are provided, as well as preforms and fibers incorporating nanoparticles. The nanoparticles may include one or more rare earth ions selected based on fluorescence at eye-safer wavelengths, surrounded by a low-phonon energy host. Nanoparticles that are not doped with rare earth ions may also be included as a co-dopant to help increase solubility of nanoparticles doped with rare earth ions in the silica matrix. The nanoparticles may be incorporated into a preform, which is then drawn to form fiber. The fibers may beneficially be incorporated into lasers and amplifiers that operate at eye safer wavelengths. Lasers and amplifiers incorporating the fibers may also beneficially exhibit reduced Stimulated Brillouin Scattering.

Nanoparticle doping for lasers and amplifiers operating at eye-safer wavelengths, and/or exhibiting reduced stimulated Brillouin scattering

A bonded optical assembly comprising infrared-transparent materials. The assembly comprises two or more infrared transparent optical elements and a polymer comprising at least one chalcogenide element and crosslinking moieties between the infrared-transparent optical elements. The crosslinking moieties may be organic, inorganic, or both.

Organically modified chalcogenide polymers for use as optical adhesive materials

This application relates generally to an optical fiber for the delivery of infrared light where the polarization state of the light entering the fiber is preserved upon exiting the fiber and the related methods for making thereof. The optical fiber has a wavelength between about 0.9 μm and 15 μm, comprises at least one infrared-transmitting glass, and has a polarization-maintaining (PM) transverse cross-sectional structure. The infrared-transmitting, polarization-maintaining (IR-PM) optical fiber has a birefringence greater than 10and has applications in dual-use technologies including laser power delivery, sensing and imaging.

Infrared-transmitting, polarization-maintaining optical fiber and method for making

A method for bonding infrared transparent materials by placing a polymer comprising at least one chalcogenide element and crosslinking moieties between infrared-transparent optical elements and applying heat, pressure, or both. The crosslinking moieties may be organic, inorganic, or both. Also disclosed is the related bonded assembly comprising infrared transparent optical elements.

The present invention provides a method for making a high strength, small grain size ceramic having a transgranular fracture mode by rapid densification of a green body and subsequent cooling of the densified ceramic. The ceramic may include dislocations, defects, dopants, and/or secondary phases that are formed as a result of the process and resulting in stress fields capable of redirecting or arresting cracks within the material. This ceramic can maintain transparency from ultraviolet to mid-wave infrared.

High strength ceramics with novel fracture mode

The present invention provides a method for making a high strength, small grain size ceramic having a trans-granular fracture mode by rapid densification of a green body and subsequent cooling of the densified ceramic. The ceramic may include dislocations, defects, dopants, and/or secondary phases that are formed as a result of the process and resulting in stress fields capable of redirecting or arresting cracks within the material. This ceramic can maintain transparency from ultraviolet to mid-wave infrared.

A composition of matter having a coated silicon substrate with multiple alternating layers of polydopamine and polyallylamine bound copper-indium-gallium oxide (CIGO) nanoparticles on the substrate. A related composition of matter having polyallylamine bound to CIGO nanoparticles to form PAH-coated CIGO nanoparticles. A related CIGO thin film made via conversion of layer-by-layer assembled CIGO nanoparticles and polyelectrolytes. CIGO nanoparticles are created via a flame-spray pyrolysis method using metal nitrate precursors, subsequently coated with polyallylamine (PAH), and dispersed in aqueous solution. Multilayer films are assembled by alternately dipping a substrate into a solution of either polydopamine or polystyrenesulfonate and then in the CIGO-PAH dispersion to fabricate CIGO films as thick as 1-2 microns.

Method for fabrication of copper-indium gallium oxide and chalcogenide thin films

A nanoparticle containing monoclinic lutetium oxide. A method of: dispersing a lutetium salt solution in a stream of oxygen gas to form droplets, and combusting the droplets to form nanoparticles containing lutetium oxide. The combustion occurs at a temperature sufficient to form monoclinic lutetium oxide in the nanoparticles. An article containing lutetium oxide and having an average grain size of at most 10 microns.

Flame spray synthesis of nanoparticles of monoclinic Lu203 and dopant

Nanoparticle doping for lasers and amplifiers operating at eye-safer wavelengths, and/or exhibiting reduced Stimulated Brillouin Scattering

A transparent composite armor is made of tens to hundreds or even thousands of thin layers of material each with a thickness of 10-500 &#x3bc;m. An appropriate amount of impedance mismatch between the layers causes some reflection at each interface but limit the amplitude of the resulting tensile wave below the tensile strength of the constituent materials. The result is an improvement in ballistic performance and that will result is a significant impact in reducing size, weight, and volume of the armor.

Shockwave controlled ballistic protection

Systems and methods are disclosed for splicing crystal fibers to silica glass fibers. Embodiments of the present disclosure provide mechanically stable bonds with negligible optical transmission loss by splicing fibers through a thermally enhanced reaction bonding process at lower temperatures than the melting point of the crystal. In an embodiment, mixing of the materials at elevated temperatures forms a stable intermediary material which enhances strength and reduces the transmission losses.

Splicing of crystal fiber to silica fiber with reaction bonding

A method of purifying a spinel powder includes contacting a spinel powder with an acid solution to form an acid-washed spinel composition and contacting the acid-washed spinel composition with a basic solution to form a purified composition. The purified powder is suited to formation of low-absorption shaped bodies, such as windows for high intensity laser devices.

Low absorption spinel formed by acidic and basic treatments

The invention relates to rare-earth-doped ternary sulfides. The rare-earth-doped ternary sulfides may be used as an active material for mid-wave infrared and long-wave infrared lasers and amplifiers. Methods for producing laser materials including rare-earth-doped ternary sulfides, as well as lasers and amplifiers incorporating the laser materials, are also provided.

Growing community of inventors

Lorton, VA, United States of America

Woohong Kim