Lg Chem, Ltd

Korea Advanced Institute of Science and Technology

Woo Hyuk Choi

Hyun Kyu Kim

Jeong Ju Moon

Seok Ho Jeong

Joo Ho Kim

Yun Ki Cho

Eun Suk Kim

Ui Chin Lee

Jeung Min Oh

Seung Taek Woo

The present disclosure is characterized in comprising a terephthalate-based composition and a citrate-based composition, wherein the terephthalate-based composition comprises di(2-ethylhexyl) terephthalate, hexyl(2-ethylhexyl) terephthalate and dihexyl terephthalate, the citrate-based composition comprises trihexyl citrate, and the hexyl group of the terephthalate and the hexyl group of the citrate are derived from an isomer mixture of hexyl alcohols. If the composition is applied to a resin, migration resistance and stress resistance may be improved, and on the other hand, mechanical properties may be improved.

Plasticizer composition and resin composition comprising the same

The present invention relates to a plasticizer composition including a lower alkyl-based citrate and a higher alkyl-based citrate simultaneously as citrates, wherein effects are achieved through controlling the ratio of hybrid and nonhybrid types, and the ratio of lower alkyl and higher alkyl, and if the plasticizer composition is applied in a resin, stress resistance and mechanical properties may be maintained to the equal or better levels, balance between migration and loss properties, and plasticization efficiency may be achieved, and light resistance and heat resistance may be markedly improved.

Citrate-based plasticizer composition and resin composition comprising the same

The present invention relates to a tetraester-based plasticizer composition characterized in including a product derived from esterification reaction of an isomer mixture of hexanoic acid and a tetraol, wherein the degree of branching of the isomer mixture of hexanoic acid is 2.0 or less. If the plasticizer composition is applied to a resin, plasticization efficiency and absorption rate may be maintained to equal or better levels when compared to a case applying the conventional plasticizer, and mechanical properties, migration resistance, stress migration and loss properties may be markedly improved.

Plasticizer composition and resin composition including the same

The present disclosure relates to a plasticizer composition characterized in including two or more isophthalates of the same carbon number type, in which alkyl groups bonded to two ester groups have the same carbon number; one or more isophthalates of a different carbon number type, in which alkyl groups bonded to two ester groups have different carbon numbers; wherein the different carbon number type includes both a higher alkyl and a lower alkyl, the carbon number of the higher alkyl is 8 to 10, and the carbon number of the lower alkyl is selected from 5 to 7, thereby, when applied to a resin, showing improved viscosity stability, migration resistance and stress resistance, while maintaining and improving plasticization efficiency and mechanical properties to the same or better level.

The present disclosure relates to a plasticizer composition including a cyclohexane 1,4-diester-based material and a cyclohexane 1,2,4-triester-based material, and may provide a plasticizer maintaining an excellent level of plasticization efficiency when compared with a common phthalate-based plasticizer product and improving mechanical properties, and may also provide a plasticizer having excellent stress resistance as an advantage.

Provided is a plasticizer composition, comprising: two or more kinds of terephthalates of the same carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is the same; and one or more kinds of terephthalates of a different carbon number type, wherein the carbon number of alkyl groups bonded to two ester groups is different, the different carbon number type comprises a higher alkyl and a lower alkyl, the higher alkyl is selected from alkyl groups having a carbon number of 8 or less, and the lower alkyl is selected from alkyl groups having a carbon number of 5 or more.

The present disclosure relates to a plasticizer composition characterized in having alkyl groups derived from an isomer mixture of hexyl alcohol with the degree of branching of less than 2.0 as a cyclohexane triester. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties may be maintained to equal or better levels, migration and loss properties and plasticization efficiency may keep balance, and light resistance and heat resistance may be markedly improved.

Cyclohexane triester-based plasticizer composition and resin composition including the same

A plasticizer composition including a citrate-based material and an epoxidized oil, and the plasticizer composition capable of maintaining an excellent plasticization efficiency and providing an improved mechanical properties and stress resistance when compared with conventional phthalate-based plasticizer products.

A plasticizer composition which includes a lower non-hybrid-type cyclohexane triester, a lower hybrid-type cyclohexane triester, a higher hybrid-type cyclohexane triester, and a higher non-hybrid-type cyclohexane triester, wherein the alkyl groups of the cyclohexane triesters are a combination of C3-C6 alkyl groups and C7-C10 alkyl groups. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties are maintained at an equivalent level or improved, migration properties, volatile loss characteristics, and plasticization efficiency are balanced, and light resistance and heat resistance are significantly improved.

Cyclohexane triester based plasticizer composition and resin composition comprising the same

Provided is a plasticizer composition comprising a cyclohexane polyester-based substance which is a compound of Chemical Formula 1 as a plasticizer: Also provided are resin compositions containing the plasticizer composition and methods of preparing the plasticizer composition.

Plasticizer composition comprising cyclohexane polyester-based substance and resin composition comprising the same

Provided is a plasticizer composition including a cyclohexane-1,2-diester-based material of Formula 1 and a trimellitate-based material of Formula 2:

Provided is a plasticizer composition including: a cyclohexane-1,2-diester-based substance of the following Chemical Formula 1; and a citrate-based substance of the following Chemical Formula 2: 

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Daejeon, South Korea

Woo Hyuk Choi