Bayer Aktiengesellschaft

Wolfgang Wenzel

Dieter Dieterich

Walter Meckel

Helmut Reiff

Artur Reischl

Josef Pedain

Bernd Quiring

Rudolf Hombach

Wilhelm Goyert

Manfred Dollhausen

Georg Niederdellmann

Hans Wagner

Jurgen Grammel

Hans-Joachim Koch

Manfred Preuss

Schroer

Gunter Mertens

The present invention relates to water-dispersible plastics precursors which are solid at temperatures below about 40.degree. C. The plastics precursors are based on isocyanate-terminated prepolymers which have been hydrophilically modified with ionic groups and/or ethylene oxide units and which contain specified amounts of isocyanate groups and --NH-- groups. The present invention also relates to processes for preparing aqueous dispersions from the solid plastics precursors and to using the plastics precursors for cross-linking dispersed plastics containing isocyanate-reactive groups.

Solid, water-dispersible plastics precursors containing isocyanate

The invention relates to aqueous adhesives which are based on water-dispersible polymers and which contain water-dispersible polyisocyanate preparations having an average NCO-functionality of at least 2.2, which, in addition to an aromatic polyisocyanate or a mixture of aromatic polyisocyanates, contain a quantity of emulsifier sufficient to guarantee the dispersibility of the polyisocyanates, as additives capable of improving the bonding properties of these adhesives.

Aqueous adhesives containing water-dispersible polyisocyanate

The present invention relates to the use of soluble electrolytes as additive to aqueous dispersions of self-dispersible anionically and/or nonionically hydrophilically modified synthetic materials for the purpose of improving the water resistance and/or blocking resistance of sheet products produced from the dispersions.

Use of water soluble electrolytes as additives in aqueous dispersions of

The present invention relates to aqueous dispersions or solutions of oligomers or polymers, polycondensates or polyaddition products containing from about 2 to 200 milliequivalents per 100 g of solids, of incorporated ammonium groups obtained by neutralizing incorporated tertiary nitrogen atoms with organic acids, characterized in that the organic acids on which the ammonium groups are based are acids which lose their acid character at temperatures in the range from about 20.degree. to 200.degree. C. in the absence of water without releasing corrosive decomposition products. The present invention further relates to a process for the production of these novel aqueous dispersions or solutions and to their use.

Aqueous dispersions or solutions of oligomeric or polymeric plastics, a

A process is provided for preparing storage stable, aqueous dispersions of oligourethanes or polyurethanes in admixture with auxiliary agents and additives which are not soluble nor dispersible in water. The oligourethanes or polyurethanes are rendered dispersible in water by incorporating ionic and/or non-ionic hydrophilic groups. In order that the final product remains storage stable, the auxiliary agents or additives are added to the oligourethanes or polyurethanes before they are dispersed in water.

Process for the preparation of stable aqueous dispersions of

This invention relates to a new process for the production of aqueous dispersions or solutions of polyurethane-polyureas by reacting NCO-prepolymers which have been hydrophilically modified and/or which contain external emulsifiers with organic polyamines and/or hydrazines in the aqueous phase, the above-mentioned chain extenders - in the form of their solid adducts with inorganic or organic acids - being mixed with the NCO-prepolymers to form a suspension before production of the dispersion or solution. The invention also relates to the dispersions or solutions obtainable by this process and to their use for the production of coatings or bonds.

Process for the production of aqueous dispersions or solutions of

The present invention relates to a process for the preparation of polyurethane ureas from relatively high molecular weight polyols, diisocyanates, water as chain lengthening agent and optionally short chain glycols in a multishaft extruder equipped with kneading elements.

Extrusion process for the preparation of polyurethane ureas

The present invention relates to a process for the preparation of aqueous dispersions or solutions of isocyanate polyaddition products characterized in that oligourethanes

Process for the preparation of aqueous dispersions or solutions of

The present invention relates to a process for the preparation of aqueous dispersions or solutions of polyurethanes which have urea end groups and contain non-ionic hydrophilic segments and which are capable of being cross-linked with the aid of cross-linking agents which are reactive with urea groups, characterized in that prepolymers which have isocyanurate end groups and which

Process for the preparation of aqueous dispersions of polyurethanes

This invention relates to coating compositions based on aqueous polyurethane dispersions and to the use of these coating compositions for the production of top coats or finishes on PVC. The coating compositions according to the invention contain a mixture of two aqueous polyurethane dispersions which have particular chemico-physical properties.

Coating compositions based on a mixture of aqueous polyurethane

A process for preparing modified aqueous synthetic resin dispersions, comprising introducing organic diisocyanates which are liquid at room temperature into polyurethane-containing, non-sedimenting, aqueous synthetic resin dispersions, optionally in the presence of catalysts which accelerate the isocyanate polyaddition reaction and/or the dimerization of isocyanate groups and/or the carbodiimidization of isocyanate groups and/or the trimerization of isocyanate groups, mixing the organic diisocyanate with the aqueous dispersion at a temperature at which no visible foaming occurs, maintaining the temperature after addition of all the diisocyanate until at least 50% of the isocyanate groups in the added diisocyanate have undergone reaction and, if desired, completing the reaction by subsequently heating to temperatures up to 100.degree. C. These modified aqueous dispersions contain dispersed latex particles which are enveloped with polyurea formed from the diisocyanates. These modified dispersions are useful as water-resistant surface coatings and leather dressings which are abrasion resistant in the wet.

Process for the preparation of modified aqueous synthetic resin

This invention relates to a process for the production of new, non-foamed urethane and/or urea group-containing polyisocyanate polyaddition products which contain both cationic and also anionic groups chemically bound into the same molecule of said polyisocyanate polyaddition products, to the polyaddition products obtainable by this process and to the use thereof for coating flexible and non-flexible sheet-form materials.

Production of solutions or dispersions of polyisocyanate polyaddition

The present invention is concerned with a process for preparing aqueous dispersions from solid polymer precursors which are polyester or polyurethane oligomers containing both hydrophilic centers and cross-linking sites and subsequently coating substrates with the thus obtained dispersions. The aqueous dispersion is applied to a substrate and dried with resultant cross-linking of the film.

Process for the manufacture of plastics containing ester and/or urethane

This invention relates to a process for the production of water dispersible polyurethanes by reacting polyisocyanates with sulphonate group containing diols. The sulphonate diols have the general formula: ##STR1## WHEREIN A and B, which may be the same or different, each represents a divalent aliphatic hydrocarbon group containing from 1 to 6 carbon atoms,

Aqueous polyurethane dispersions from solvent-free prepolymers using

This invention relates to a novel process for the production of polyurethane via an intermediate stage of aqueous dispersions of oligomeric polyurethane prepolymers having ionic and/or non-ionic hydrophilic groups which ensure their dispersibility in water, followed by conversion of these water-dispersible oligomers into cross-linked high molecular weight sheets.

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Bergisch-Gladbach, Germany

Wolfgang Wenzel