Bayer Aktiengesellschaft

Wolfgang Rambold

Franz Hund

Jakob Rademachers

Horst Brunn

Manfred Mansmann

Peter Kresse

Gunter Buxbaum

Heinrich Heine

Gunter Linde

Rolf Naumann

Ingo Pflugmacher

Peter Kiemle

Hans-Peter Biermann

Karl-Werner Ganter

Gerhard Trenczek

Willi Hennings

Bruno Raederscheidt

Gerd Von Szadkowski

Iron oxide black pigments useful as coloring pigments for lacquers and plastics are prepared by an improved process wherein finely divided iron oxide black suspensions obtained from the precipitation processor the aniline process are filtered, washed, dried and ground with the improvement in the process comprising grinding the dried iron oxide pigment in a jet mill with air as the grinding medium and with a water content of from about 1 to 6% by weight based on the iron oxide black pigment input to the process.

Finely divided iron oxide black pigments, a process for their

This invention relates to corrosion-inhibiting paints and lacquers containing pigments comprising an organic corrosion inhibitor intercalated into an inorganic matrix said pigment having the formula wherein ##EQU1## wherein Me(II)O is at least one divalent metal oxide;

Corrosion-inhibiting paints and lacquers

Spherical agglomerates of surface-stabilized primary particles substantially consisting of iron, having a BET surface of about 5 to 50 m.sup.2 /g, measured on the agglomerate, in non-pyrophoric form and having a bulk density of about 0.5 to 2.0 kg/l and an agglomerate diameter of about 0.5 to 10 mm are produced by

Agglomerated ferromagnetic iron particles

A zinc ferrite pigment comprising, by weight, about 99.8 to 90% of ZnFe.sub.2 O.sub.4 and about 0.2 to 10% of the component system (1-x)Al.sub.2 O.sub.3 and xP.sub.2 O.sub.5 wherein 0&lt;x&lt;1 is produced by calcining a suitable mixture of compounds. The resulting pigments are of high color quality and are substantially halogen-free, rendering them especially useful industrially even as anti-corrosion pigments.

Halogen-free zinc ferrite yellow pigments containing alumina and

A process for increasing the color purity of iron oxide pigment particles admixed with color-modifying impurities and obtained by the Penniman process or the aniline process, comprising introducing the particles into a magnetic field, and removing from the magnetic field two fractions of different magnetizability, the first fraction being iron oxide pigment particles of increased color purity and the second fraction being enriched in impurities.

Magnetic separation to improve purity of iron oxide pigments

A process for the production of low sulphur chromium(III) oxide comprising annealing at a calcining temperature from about 800.degree. C. to 1100.degree. C. a mixture of alkali metal chromate and about 0.7 to 0.96 times its molar amount of ammonium sulfate, and separating the chromium(III) oxide formed from the alkali metal salt. Advantageously the ammonium sulfate in the form of a concentrated solution is mixed with solid alkali metal dichromate and the mixture thereafter is adjusted prior to calcination to a water concentration of less than about 15% by weight of water.

Production of low sulphur chromium (III) oxide

A process for the production of chromium oxide green pigment comprising heating a mixture of ammonium dichromate with at least the stoichiometrically equivalent quantity of a sodium salt selected from the group consisting of chloride and sulfate over a period of at most about 15 minutes to a pigment-forming temperature of about 800 to 1100.degree. C in the presence of about 1 to 45% water based on the weight of the mixture, calcining the mixture at a temperature in the above-mentioned range, and separating the formed pigment from the salts. The mixture may be formed in situ by reaction of sodium dichromate with ammonium chloride or sulfate in the presence of water. The presence during calcining of organic modifiers such as sawdust or of boron compounds such as borax increases, tinting strength and disproportionately affect color. The pigments are brighter, and of higher tinting strength than heretofore produced.

Production of improved chromium oxide green pigment

In the production of chromium oxide green pigment by heating a substantially stoichiometrically equivalent mixture of sodium dichromate dihydrate and an ammonium salt selected from the group consisting of the sulfate and chloride, the improvement which comprises dry mixing sodium dichromate dihydrate having a particle size less than 2 mm with the ammonium salt having a particle size less than about 0.5 mm, heating the resulting mixture over a period of about 15 minutes to a pigment-forming temperature of about 800.degree. to 1100.degree. C, calcining the mixture at a temperature in that range, and separating the formed pigment from the salts. To the mixture prior to heating there may be added sodium hydroxide solution, boron compounds such as borax and/or organic modifiers such as sawdust which improve the color and tinting strength of the resulting pigment. The pigments are brighter, and of higher tinting strength than heretofore produced.

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Krefeld, Germany

Wolfgang Rambold