Uop Lcc

Wolfgang A Spieker

Paolo Palmas

Gregory J Gajda

Andrea G Bozzano

Laura Elise Leonard

Gregory A Funk

David Nathan Myers

J W Adriaan Sachtler

Nicholas J Schoenfeldt

Thulasidas Chellppannair

Jaime G Moscoso

John Joseph Senetar

Lev Davydov

Daniel N Myers

Richard A Johnson, Ii

Christopher D DiGiulio

Adam D Ballard

Stanley Joseph Frey

Bipin Virpal Vora

Paula L Bogdan

James A Johnson

Patrick C Whitchurch

Avram Michael Buchbinder

Wei Pan

Mohammad-Reza Mostofi-Ashtiani

Kristoffer E Popp

A fluidized catalytic reactor system cycles from 0.05-5% of catalyst at a time through a rejuvenation unit to be heated in the presence of oxygen to maintain catalyst activity. The use of the rejuvenation unit that may be 2% of the size of the main catalyst regeneration unit allows for reduction in equipment size and in catalyst inventory. The catalyst that is sent to the rejuvenation unit may be spent catalyst but may be partially or fully regenerated catalyst. The rejuvenation unit may be heated by combusting fuel or by hot flue gas.

Regeneration of a dehydrogenation catalyst slip-stream

A process and reactor for contacting a feed stream with a catalyst stream comprises a reaction chamber comprising two spent catalyst inlets for delivering two spent catalyst streams to the reaction chamber and at least one regenerated catalyst inlet for delivering a regenerated catalyst stream to the reaction chamber. The reaction chamber may also include a second regenerated catalyst inlet for delivering a second regenerated catalyst stream to the reaction chamber. The second spent catalyst inlet enables thorough mixing of catalyst streams.

Process and apparatus for contacting feed and catalyst with improved catalyst mixing

A fluidized catalytic reactor utilizes an ascending temperature profile. The apparatus and process deliver cooler spent catalyst to a first catalyst distributor and a hotter regenerated catalyst to a second catalyst distributor that are spaced apart from each other. The reactant stream first encounters the first stream of catalyst and then encounters the second stream of catalyst. The process and apparatus stage the addition of hot catalyst to the reactant stream. The process and apparatus may be particularly advantageous in an endothermic reaction because the hotter catalyst will encounter reactants that have cooled due to the progression of endothermic reactions.

Process and apparatus for reacting feed with a fluidized catalyst over a temperature profile

A process is presented for the management of sulfur on a catalyst. The catalyst is a dehydrogenation catalyst, and sulfur accumulates during the dehydrogenation process. Sulfur compounds are stripped from the spent catalyst and the catalyst is cooled before the regeneration process. The process includes controlling the amount of sulfur that needs to be removed from the catalyst before regeneration.

Process for managing sulfur on catalyst in a light paraffin dehydrogenation process

A process is presented for the treatment of spent catalyst to manage sulfur-containing compounds on the catalyst. The catalyst may be a dehydrogenation catalyst, where sulfur accumulates during a dehydrogenation process. Sulfur compounds are stripped from the spent catalyst and the catalyst may be cooled before a regeneration step. The process includes controlling removal of sulfur compounds from the spent catalyst before regeneration.

Process for managing sulfur compounds on catalyst

A process is presented for the production of light olefins. The process utilizes a SAPO-18 catalyst and is operated at an elevated pressure. The process generates higher concentrations of heavier olefins which can then be processed to generate light olefins. The processing of the heavier olefins can include metathesis reactions and olefin cracking processes.

MTO process for enhanced production of propylene and high value products

A process is presented for generating light olefins with the methanol to olefins process from a combination of catalysts. The process controls the product distribution for ethylene, propylene and butylenes, to enable shifting of the product distribution. The process includes passing a second catalyst to a reactor while the process is on-going.

Use of catalyst to adjust product distributions in MTO process

This invention is drawn to a process for isomerizing a non-equilibrium mixture of xylenes and ethylbenzene which contain a substantial concentration of nonaromatics using a catalyst system which features the ability to both convert nonaromatics and to obtain an improved yield of para-xylene from the mixture relative to processes of the known art.

Aromatics isomerization using a dual-catalyst system

A process and apparatus for the dehydrogenation of paraffins is presented. The process utilizes a reactor that includes a slower flow of catalyst through the reactor, with a counter current flow of gas through the catalyst bed. The catalyst is regenerated and distributed over the top of the catalyst bed, and travels through the bed with the aid of reactor internals to limit backmixing of the catalyst.

Counter-current fluidized bed reactor for the dehydrogenation of olefins

A process is presented for quenching a process stream in a paraffin dehydrogenation process. The process comprises cooling a propane dehydrogenation stream during the hot residence time after the process stream leaves the catalytic bed reactor section. The process includes cooling and compressing the product stream, taking a portion of the product stream and passing the portion of the product stream to the mix with the process stream as it leaves the catalytic bed reactor section.

Method for quenching paraffin dehydrogenation reaction in counter-current reactor

An apparatus and process are presented for drying a catalyst in a reactor-regenerator system. The process includes a continuous operating system with catalyst circulating between a reactor and regenerator, and the catalyst is dried before returning the catalyst to the reactor. The process uses air that is split between the drying stage and the combustion stage without adding equipment outside of the regenerator, minimizing energy, capital cost, and space requirements.

Growing community of inventors

Glenview, IL, United States of America

Wolfgang A Spieker