Hoechst Aktiengesellschaft

Winfried Ehrl

Rolf Kleber

Alwin K Reng

Jochen M Quack

Karl Hintermeier

Siegfried Billenstein

Frank Wehowsky

Heinrich Bathelt

Werner Lotz

Manfred Muller

Siegfried Jung

Jan-Hilbert Mast

Hubert Herdt

Lothar Jackel

Wolfgang Glenz

The novel urethanes correspond to the formula I below ##STR1## in which a denotes a number from 5 to 17 and b denotes a number from 1 to 7. These urethanes are prepared by reacting the corresponding perfluoroalkylethanol/epichlorohydrin adducts with toluelene diisocyanates. The novel aqueous dispersions are essentially composed of the novel urethanes, cationic or betaine emulsifiers and non-ionic emulsifiers, water-insoluble carboxylic and/or dicarboxylic acid esters and alkanediols or polyalkanediols which can be etherified on one or both sides, in water. The novel urethanes and the novel aqueous dispersions are used to impart an oleophobic and hydrophobic finish to textiles, leather and furs. They are also suitable for the treatment of unpainted timber, for example unpainted furniture.

Urethanes containing perfluoroalkyl and epichlorohydrin groups

Hair shampoo and body cleansing agent having a content of alkyl-sulfatobetaine of the formula ##STR1## wherein R.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.22 alkenyl, preferably C.sub.12 -C.sub.18 alkyl, R.sub.2 is C.sub.1 -C.sub.4 alkyl, preferably methyl, R.sub.3 is C.sub.1 -C.sub.4 hydroxyalkyl or a group of the formula --(CH.sub.2 CH.sub.2 O).sub.n H and n is an integer of from 1 to 10.

Hair shampoos and body cleansing agents having a content of

Fluorine-containing alkylsulfobetaines of the general formula ##STR1## wherein R.sub.f denotes a perfluoroalkyl radical having 3 to 16 C atoms, R.sub.1 and R.sub.2, which can be identical or different, denote alkyl radicals or hydroxyalkyl radicals having 1 to 4 C atoms, a is zero or 1, b assumes the value 1 when a is equal to 1 and the values 1 to 4 when a is equal to 0, and c is 3 or 4, are described. These are prepared by reacting the corresponding fluorine-containing amines with propanesultone or butanesultone in organic solvents. The compounds are distinguished in particular by high interfacial activity at the interface of water with non-miscible organic liquids and by compatibility with other surfactants. They are suitable for use as aftertreatment agents (auxiliary dispersing agents) in dispersions of fluoropolymers and as components in fire-extinguishing agents.

Fluorine-containing alkylsulfobetaines, a process for their preparation

Fluorine-containing alkyl-sulfato-betaines of the formula ##STR1## in which R.sub.f is perfluoroalkyl with 3 to 16 C atoms, R.sup.1 is alkyl with 1 to 4 C atoms, R.sub.2 is alkyl with 1 to 4 C atoms, Q is --CH.sub.2 --CH.sub.2 -- or ##STR2##

Fluorine-containing alkyl-sulfato-betaines and processes for their

Fiber conditioning agent containing a reaction product of polyphosphoric acid and an oxalkylate of C.sub.8-18 alkyl- or alkenylcarboxylic acids with 1 to 22 ethylene oxide units and having a content of free polyethylene glycol of less than 2% by weight, the reaction product being present in acidic form or in the form of its alkali metal salts. These fiber conditioning agents are applied by conventional methods. They show good antistatic properties, are stable to heat and show good lubricating and sliding properties.

Liquid thermostable phosphoric acid esters for the fiber conditioning

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Neuotting, Germany

Winfried Ehrl