Colgate Palmolive Company

The Mennen Company

Other

Wilson Lee

Jairajh Mattai

Eric P Guenin

Xiaozhong Tang

Robert J Bianchini

Kathy J Potechin

Patricia Ann Hall-Puzio

Elizabeth Linn

Anne Elisabeth Gale

John J Afflitto

John Patrick Hogan

John Jonas

Rosemary Munsayac

Paul Joseph Vincenti

Peter Hilliard, Jr

Makarand Shevade

Peter R Hilliard

Radhakrishna B Kasat

Adriana Urrutia-Gutierrez

Kathy Potechin

Norayr G Telyan

Esther Avendano

David R McCarthy

A low residue antiperspirant and/or deodorant composition in the form of an anhydrous, surfactant-free and antiseptic alcohol-free suspension exhibiting a syneresis of less than 8% which is made by combining selected amounts of: (a) a cyclomethicone (and) dimethicone crosspolymer made with an &#x2261;Si&#x2014;H containing polysiloxane and an alpha, omega-diene of formula CH&#x2550;CH(CH)CH&#x2550;CHwhich crosspolymer has a viscosity in the range of 50,000&#x2013;3,000,000 centipoise, preferably with a nonvolatiles content of 10&#x2013;14% in cyclomethicone; (b) polyethylene beads having a density in the range of 0.91&#x2013;0.98 grams/cmand a particle size in the range of 5&#x2013;40 microns; (c) a volatile silicone; (d) an emollient (or a mixture of two or more emollients) which may include a non-volatile silicone and an additional amount of a volatile silicone; and (e) an effective amount of an antiperspirant active material in an amount sufficient to have an antiperspirant and/or a deodorant effect.

Effective soft solid personal care product

A low residue antiperspirant and/or deodorant composition in the form of an anhydrous, surfactant-free and antiseptic alcohol-free suspension exhibiting a syneresis of less than 8% is disclosed which comprises: (a) a dimethicone/vinyldimethicone crosspolymer composition made by reacting a polymethylhydrogensiloxane with an alpha, omega-divinylpolydimethyl siloxane for which the dimethicone/vinyldimethicone crosspolymer composition is used at a concentration of 0.5&#x2013;10% in cyclomethicone; (b) polyethylene beads having a density in the range of 0.91&#x2013;0.98 grams/cmand a particle size in the range of 5&#x2013;40 microns, wherein the polyethylene beads are used in an amount of at least 2% by weight based on the total weight of the composition; (c) a volatile silicone; (d) an emollient or mixture of two or more emollients; and (e) an effective amount of an antiperspirant active material.

Stable and efficacious soft solid product

This invention comprises low residue cosmetic compositions (especially underarm products) which are made by combining an active ingredient; a silicone gel material itself comprising an elastomer composition; and at least one selected surfactant having an HLB value in the range of 8-16. The compositions of this invention exhibit reduced or eliminated film formation when applied to the skin and increased availABILity of the active ingredient.

Low Residue cosmetic composition

A high efficacy antiperspirant/deodorant stearyl alcohol free stick product may be made by combining (a) 30-70% volatile cyclomethicone; (b) 10-25% of an antiperspirant active; (c) 1-15% of an emollient; (d) 1-14% of polyethylene comprising one or more members selected from the group consisting of homopolymers and copolymers of polyethylene wherein the polyethylene (i) is at least 90% linear; (ii) has a molecular weight in the range of 300-3000 (especially 300-1000 and more especially 300-500); (iii) has a melting point in the range of 50-129 degrees C.; and (iv) has a polymer backbone of CH CH &mdash;(CH &mdash;CH ) &mdash;H, where n is an average number and is selected to be in the range of 10-106; (e) 0.3-7% of a wax as a co-gellant with the polyethylene wherein the wax has a melting point in the range of 40-97 degrees C.; and (f) 1-40% of an elastomer in cyclomethicone composition; provided that the ratio of wax:polyethylene is in the range of 1:1-1:10.

High efficacy antiperspirant stick

A high efficacy antiperspirant/deodorant stick product may be made by combining (a) 30-70% volatile cyclomethicone; (b) 10-25% of an antiperspirant active; (c) 1-15% of an emollient; (d) 1-14% of polyethylene comprising one or more members selected from the group consisting of homopolymers and copolymers of polyethylene wherein the polyethylene (i) is at least 90% linear; (ii) has a molecular weight in the range of 300-3000 (especially 300-1000 and more especially 300-500); (iii) has a melting point in the range of 50-129 degrees C.; and (iv) has a polymer backbone of CH CH &mdash;(CH &mdash;CH ) &mdash;H, where n is an average number and is selected to be in the range of 10-106; (e) 0.3-7% of a wax as a co-gellant with the polyethylene wherein the wax has a melting point in the range of 40-97 degrees C.; and (f) 1-30% of an elastomer in cyclomethicone composition comprising a cyclomethicone (and) dimethicone crosspolymer made with an &boxH;Si&mdash;H containing polysiloxane and an alpha, omega-diene of formula CH &boxH;CH(CH ) CH&boxH;CH , where x&equals;1-20; provided that the ratio of wax:polyethylene is in the range of 1:1-1:10.

High efficacy antiperspirant stick with concentrated elastomer

A two-phase roll-on antiperspirant and/or deodorant is described which comprises: (a) a clear, translucent or opaque non-polar phase having a viscosity in the range of 20 cps-9,000 made by combining: a cross-linked or partially cross-linked non-emulsifying siloxane elastomer; 0.1-70 weight % of one or more low viscosity, lipophilic emollients; (b) a clear, translucent or opaque polar phase have a viscosity in the range of 20-9,000 cps made by combining: one or more members selected from the group consisting of water, glycols and polyhydric alcohols; and an antiperspirant active salt which is soluble or suspendible in the polar phase; wherein the polar phase comprises (i) a sufficient amount of water, glycols or polyhydric alcohols to dissolve or suspend the antiperspirant active, and (ii) optionally may comprise up to 30 weight % water; up to 16.00 weight % of ethyl alcohol; up to 16 weight % isopropyl alcohol; or mixtures of the foregoing; (iii) 0.1-2.5 weight % of a water soluble cationic derivative selected from the group consisting of hydroxyethyl cellulose and its copolymers provided that the viscosity of the polar phase does not exceed 9,000 cps.

Two-phase roll-on cosmetic product

A high efficacy antiperspirant/deodorant stick product may be made by combining (a) 30-70% volatile cyclomethicone; (b) 10-25% of an antiperspirant active; (c) 1-15% of an emollient; (d) 1-14% of polyethylene comprising one or more members selected from the group consisting of homopolymers and copolymers of polyethylene wherein the polyethylene (i) is at least 90% linear; (ii) has a molecular weight in the range of 300-3000 (especially 300-1000 and more especially 300-500); (iii) has a melting point in the range of 50-129 degrees C; and (iv) has a polymer backbone of CH CH &mdash;(CH &mdash;CH ) &mdash;H, where n is an average number and is selected to be in the range of 10-106; (e) 0.3-7% of a wax as a co-gellant with the polyethylene wherein the wax has a melting point in the range of 40-97 degrees C.; provided that the ratio of wax:polyethylene is in the range of 1:1-1:10.

Elastomer free, high efficacy antiperspirant stick

Disclosed is a clear cosmetic gel composition in the form of a water-in-oil emulsion, and methods of forming and of using the composition. The composition has a water-based phase containing water, a cosmetically active ingredient, and at least one coupling agent; and an oil-based phase containing a material having a refractive index in the range of 1.40-1.50, silicone fluids and an alkoxylated, alkyl substituted siloxane surface active agent (e.g., dimethicone copolyol). The composition has a refractive index in a range of 1.4026 to 1.4150. Where the cosmetically active ingredient is an antiperspirant active ingredient, the composition can be an antiperspirant gel (e.g., soft gel) composition. In the refractive index range of the present invention, increased amounts of, e.g., antiperspirant active ingredient, and other high-refractive-index materials providing cosmetic benefits, can be incorporated in the water and oil phases of the composition while still achieving a clear composition. The composition can also include polypropylene glycols (e.g., tripropylene glycol), as part of the water-based phase, to provide a composition having reduced tackiness and reduced whitening (decreased residue); this composition is also mild (reduced skin irritation potential) relative to comparable commercial products.

Clear cosmetic gel composition

Disclosed is a solid cosmetic composition (e.g., a cream composition) containing an active cosmetic material (e.g., a deodorant active, an antiperspirant active, a sunscreen, an insect repellent and/or an anti-fungal agent) and a silicone gel material. The silicone gel material includes (a) a volatile silicone material and (b) an organopolysiloxane material as a gelling agent, able to form a gel after being mixed with the volatile silicone material. The organopolysiloxane material can be a reaction product of a vinyl-terminated siloxane polymer and a hydride cross-linking agent. The composition can be formed by mixing the active cosmetic material and silicone gel material at ambient temperature. The compositions do not need particulate or clay thickeners or waxy gelling agents.

Cosmetic cream composition containing silicone gel material

Disclosed is a solid (e.g., cream, such as semi-solid or soft solid) cosmetic composition containing an active cosmetic material (e.g., a deodorant active, an antiperspirant active, a sunscreen, an insect repellent and/or an anti-fungal agent), volatile (e.g., cyclomethicone) and linear chain (e.g., dimethicone and/or phenyl trimethicone) silicone materials, and at least one gelling agent. The at least one gelling agent includes hexanediol-behenyl beeswax, and is included in the composition in an amount sufficient to provide the solid composition. By incorporating the hexanediol-behenyl beeswax as a gelling agent, conventional gelling agents such as fatty alcohols and hydrogenated castor oil need not be incorporated in the composition. When an antiperspirant active material is incorporated in the solid composition containing hexanediol-behenyl beeswax as a gelling agent, a solid antiperspirant composition that is efficacious and leaves no visible (white) residue, can be achieved.

Solid cosmetic composition containing hexanediol-behenyl beeswax as

Disclosed is a low residue antiperspirant solid stick composition containing, in addition to an antiperspirant active material, volatile and non-volatile silicone materials, dimethicone copolyol and high-melting-point and low-melting-point waxes. The composition not only has low visible (white) residue after application and after drying, but also has good cosmetic properties, superior antiperspirancy and is easy to manufacture.

Low residue antiperspirant solid stick composition

Disclosed is a clear, antiperspirant material-containing, gel stick composition, containing an acidic antiperspirant material (e.g., an aluminum salt) and gelled with dibenzylidene sorbitol, the composition including a guanidine compound (for example, guanidine carbonate or aminoguanidine bicarbonate) as a stabilizing agent to reduce degradation of the gel and of the dibenzylidene sorbitol gelling agent. Also disclosed are continuous processes for forming the gel stick composition, wherein degradation of the dibenzylidene sorbitol gelling agent in the presence of the antiperspirant material is reduced.

Growing community of inventors

Bloomfield, NJ, United States of America

Wilson Lee