General Electric Company

William R Becker

Richard I Larson

Steven J Babb

Michael R Chilton

Thomas J Flaherty, Iii

A process for reclaiming scrap UO.sub.2 materials yields a high-sinter-density pellet. The scrap is oxidized in a high-temperature furnace to produce U.sub.3 O.sub.8. The U.sub.3 O.sub.8 particles from the oxidation furnace are reacted with nitric acid to produce a solution of uranyl nitrate that meets the concentration and free acid requirements of the ADU precipitation process. A controlled two-stage ADU precipitation process is carried out to produce ADU particles with a size and morphology that leads to high-surface-area UO.sub.2 powder with excellent sintered pellet ceramic characteristics. After calcination and hydrogen reduction to UO.sub.2, the high-surface-area UO.sub.2 powder is passivated.

Process to reclaim UO.sub.2 scrap powder

The 'Purex' solvent extraction and separation process for recovering uranium from scrap material or spent fuel containing gadolinia is modified by treating uranium containing scrap or spent fuel with nitric acid to convert uranium oxide to soluble uranyl nitrate in an aqueous medium, separating the uranyl nitrate from the aqueous media with an organic medium containing tri-butyl phosphate, and then releasing the separated uranium from the organic medium with water. The improvement comprises monitoring the density of the organic medium and controlling the feed rate of the uranium in the aqueous medium in response to the density measurements.

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Wilmington, NC, United States of America

William R Becker