Exxon Research and Engineering Company

William L Schuette

William E Winter, Jr

Elroy M Gladrow

Terry A Reid

Tan-Jen Chen

Paul E Eberly

William A Wachter

Lloyd A Pine

Patrick J Maher

A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen and a 345.degree. C.+ products fraction is recycled to the cracking zone. The catalyst is an amorphous silica-alumina or a zeolitic material which is iso-structural to faujasite. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.

FCC for producing low emission fuels from high hydrogen and low nitrogen

A fluid catalytic cracking process for producing relatively low emissions fuels. The feedstock is exceptionally low in nitrogen and aromatics and relatively high in hydrogen. The catalyst is an amorphous silica-alumina or a zeolitic material having a relatively small unit cell size. The feedstock can be characterized as having less than about 50 wppm nitrogen; greater than about 13 wt. % hydrogen; less than about 7.5 wt. % 2+ring aromatic cores; and not more than about 15 wt. % aromatic cores overall.

Fluid cracking process for producing low emissions fuels

A catalyst is provided which comprises a phosphorus-treated ultrastable Y-type crystalline zeolite and a non-zeolitic inorganic oxide matrix. A catalytic cracking process utilizing the catalyst is also provided.

Hydrocarbon cracking catalysts and processes for utilizing the same

A catalyst, having a specified amount of rare earth metal content and a specified amount of alkali metal content, suitable for conversion of hydrocarbon oils to lower boiling products comprises a crystalline aluminosilicate zeolite, such as zeolite Y, an inorganic oxide matrix and, optionally discrete particles of alumina dispersed in the matrix. The zeolite prior to being composited with the matrix has a unit cell size above about 24.5 Angstroms. A cracking process utilizing the catalyst is also provided.

Hydrocarbon conversion catalysts and processes utilizing the same

Hydrocarbon conversion catalysts

A cracking catalyst comprising discrete particles of ultra-stable Y-type zeolite and discrete particles of alumina, which particles are dispersed in a porous oxide matrix to produce a catalyst containing 5-40 wt. % ultra-stable Y-type zeolite, 5-40 wt. % alumina and 40-90 wt. % of porous oxide matrix. The cracking catalyst has unusually high activity and selectivity for the production of high octane gasoline fractions from higher boiling point feedstocks.

Octane improvement cracking catalyst

An improved catalyst, and process utilizing said catalyst for catalytically cracking a sulfur-containing hydrocarbon feed, and for the fixation of sulfur by the catalyst and transfer thereof from the catalyst regeneration zone to the reaction zone of a catalytic cracking unit. The catalyst comprises an admixture of composite particles, one present in major concentration for providing principally cracking and combustion promoting functions, and the other present in minor concentration for providing principally sulfur fixation and transfer functions. The particle present in major concentration, on the one hand, is constituted essentially of one or more Group VIII noble metals, preferably platinum, composited with a support comprised of a crystalline alumino silicate component distributed in an active cracking catalyst matrix, suitably one constituted of silica-alumina. The minor component particle, on the other hand, is comprised of one or more Group II-A metals, preferably magnesium, composited with a support, suitably silica-magnesia or silica-alumina, which may also contain a crystalline aluminosilicate zeolite component dispersed within thesilica-magnesia or silica-alumina support matrix.

Sulfur transfer cracking catalyst

An improved catalyst, and process utilizing said catalyst for catalytically cracking a sulfur-containing hydrocarbon feed, and for the fixation of sulfur by the catalyst and transfer thereof from the catalyst regeneration zone to the reaction zone of a catalytic cracking unit. The catalyst comprises an admixture of composite particles, one present in major concentration for providing principally cracking and combustion promoting functions, and the other present in minor concentration for providing principally sulfur fixation and transfer functions. The particle present in major concentration, on the one hand, is constituted essentially of one of more Group VIII noble metals, preferably platinum, composited with a support comprised of a crystalline alumino silicate component distributed in an active cracking catalyst matrix, suitably one constituted of silica-alumina. The minor component particle, on the other hand, is comprised of one or more Group II-A metals, preferably magnesium, composited with a support, suitably silica-magnesia or silica-alumina, which may also contain a crystalline aluminosilicate zeolite component dispersed within the silica-magnesia or silica-alumina support matrix.

Sulfur transfer process in catalytic cracking

A process which comprises recracking a cracked naphtha feed containing up to about 60 percent, suitably from about 20 to about 40 percent olefins, over a crystalline aluminosilicate zeolite catalyst to further crack the naphtha and saturate at least about 50 percent of the olefins, preferably from about 90 percent to about 100 percent of the olefins, based on the weight of said cracked naphtha feed. In a preferred combination a gas oil is catalytically cracked in a first stage to produce a cat cracked naphtha product of high olefin content, and an intermediate boiling component thereof is recracked as a feed in a second stage over a zeolite catalyst to saturate the olefins, and hydrodenitrogenate and hydrodesulfurize said cat cracked naphtha. The recracked cat cracked naphtha is then hydrotreated at low to mild severities and then catalytically reformed (hydroformed) to produce high octane gasoline.

Catalytic cracking process

A fluid hydrocoking process is provided in which certain metal compounds are dispersed in the coker chargestock. Preferred compounds are molybdenum compounds, for example, molybdenum naphthenate.

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Baton Rouge, LA, United States of America

William L Schuette