Exxonmobil Research and Engineering Company

Exxonmobil Technology and Engineering Company

William Joseph Novak

Timothy Lee Hilbert

Stuart S Shih

Michel A Daage

Stephen John McCarthy

Patrick Loring Hanks

Xiaochun Xu

Christopher Gordon Oliveri

William J Tracy, Iii

Gary Paul Schleicher

Michael B Carroll

Richard Charles Dougherty

Zhiguo Hou

John P Greeley

Kathryn Younger Cole

Robert Allen Bradway

Wenyih Frank Lai

Thomas F Degnan

Jose G Santiesteban

Ramesh Gupta

Edward Stanley Ellis

Ajit Bhaskar Dandekar

Thomas R Halbert

Benjamin S Umansky

Ross Mabon

Kuangnan Qian

Roger Grant Gaughan

Eric D Joseck

Virginia M Roberts

Hyung Rae Kim

April D Ross

Carlos N Lopez

Krista Marie Prentice

Hans Georg Korsten

Teck-Mui Hoo

Nicole D Vaughn

John T Wyatt, Jr

Antonio O Ramos

Ramesh X Gandhi

José Guadalupe Santiesteban

Stuart H Shih

Meghan E Pierson

Rohit Garg

Kirsten E Schutt

William J Iii Tracy

Beatrice M Cooding

April Denise Ross

John Peter Greeley

Iii William J Tracy

Richard J Quann

Thomas Risher Halbert

Roger G Gaughan

Stephen J Mccarthy

William J Tracy

William E Riedinger

Darunee Meemongkolkiat

John T Wyatt

Systems and methods are provided for co-processing of biomass oil with mineral coker feeds in a coking environment. The coking can correspond to any convenient type of coking, such as delayed coking or fluidized coking. The biomass oil can correspond to biomass oil with a molar ratio of oxygen to carbon of 0.24 or less on a dry basis. Such types of biomass oil can be formed from pyrolysis methods such as hydrothermal pyrolysis, and are in contrast to biomass oils formed from pyrolysis methods such as fast pyrolysis. By using a biomass oil with a molar ratio of oxygen to carbon of 0.24 or less, improved yields of light coker gas oil can be achieved in conjunction with a reduction in the yield of heavy coker gas oil.

Co-processing of biomass oil in coker

Methods are provided for dewaxing a distillate fuel boiling range feed to improve one or more cold flow properties of the distillate fuel feed, such as cloud point, where the distillate fuel feed is fractionated to produce both a jet fuel product and an arctic diesel fuel product. The decrease of cloud point is achieved by using a feedstock having a concentration of nitrogen of less than about 50 wppm and a concentration of sulfur of less than about 15 wppm. Further, the dewaxing catalyst may have a reduced content of hydrogenation metals, such as a content of Pt or Pd of from about 0.05 wt % to about 0.35 wt %. A distillate fuel feed can be dewaxed to achieve a desired cloud point differential using a reduced metals content dewaxing catalyst under the same or similar conditions to those required for a dewaxing catalyst with higher metals content.

Production of low cloud point diesel fuels and low freeze point jet fuels

Methods are provided for dewaxing a distillate fuel boiling range feed to improve one or more cold flow properties of the distillate fuel feed, such as cloud point, with reduced consumption of hydrogen during the dewaxing process. The reduced hydrogen consumption is achieved by using a dewaxing catalyst with a reduced content of hydrogenation metals, such as a content of Pt or Pd of from about 0.03 wt % to about 0.35 wt %. A distillate fuel feed can be dewaxed to achieve a desired cloud point differential using a reduced metals content dewaxing catalyst under the same or similar conditions to those required for a dewaxing catalyst with higher metals content.

Production of low cloud point distillate fuels

This invention relates to a process involving hydrocracking and dewaxing of a feedstream in which a converted fraction can correspond to a majority of the product from the reaction system, while an unconverted fraction can exhibit improved properties. In this hydrocracking process, it can be advantageous for the yield of unconverted fraction for gasoline fuel application to be controlled to maintain desirable cold flow properties for the unconverted fraction. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

Fuels hydrocracking with dewaxing of fuel products

A method for producing diesel fuel from biocomponent feeds includes hydrotreating the feed followed by catalytic dewaxing with a 1-D, 10 member ring molecular sieve containing catalyst. The hydrotreated feed may be cascaded directly to the dewaxing step, or the hydrotreated feed can undergo intermediate separation. The diesel fuel resulting from processing of the biocomponent feed exhibits superior cetane values.

Hydroprocessing of biodiesel fuels and blends

Methods are provided for producing Group II/III lubricant base oil products where at least a portion of the feedstock for forming the lubricant base oil product is a solvent extract fraction from a Group I lubricant production facility. This can increase the overall volume of feedstock available for production of Group II/III lubricant base oils by using a lower value stream (Group I solvent extract) as a portion of the feedstock. The solvent extract fraction can be added to a full range lubricant feedstock or to a portion of a lubricant feedstock, such as adding an extract fraction to a higher viscosity portion (such as a heavy neutral portion) of a feedstock for lubricant production, while a lower viscosity portion (such as a light neutral portion) is processed without addition of an extract fraction.

Basestock production from feeds containing solvent extracts

A catalytic naphtha hydrodesulfurization process is operated in a process unit having a surge drum with equipped for gas blanketing with a blanketing gas containing controlled levels of CO and CO. If the gas selected for blanketing normally contains more than the acceptable level of these inhibitors, they should be reduced to the levels appropriate for retention of catalyst functionality.

Hydroprocessing with drum blanketing gas compositional control

Methods are provided for processing a gas oil boiling range feedstock, such as a vacuum gas oil, in a single reaction stage and/or without performing intermediate separations. The methods are suitable for forming lubricants and distillate fuels while reducing or minimizing the production of lower boiling products such as naphtha and light ends. The methods can provide desirable yields of distillate fuels and lubricant base oils without requiring separate catalyst beds or stages for dewaxing and hydrocracking. The methods are based in part on use of a dewaxing catalyst that is tolerant of sour processing environments while still providing desirable levels of activity for both feed conversion and feed isomerization.

Co-production of lubricants and distillate fuels

This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

Hydrocracking process selective for improved distillate and improved lube yield and properties

A method for producing diesel fuel from biocomponent feeds includes hydrotreating the feed followed by catalytic dewaxing with a ZSM-48 containing catalyst. The hydrotreated feed may be cascaded directly to the dewaxing step, or the hydrotreated feed can undergo intermediate separation. The diesel fuel resulting from processing of the biocomponent feed exhibits superior cetane values.

Methods are provided for hydrotreating high nitrogen feeds with improved results for nitrogen removal, aromatic saturation, and/or sulfur removal. The method includes hydrotreating the feed with a supported hydrotreating catalyst followed by a bulk metal catalyst, the hydrotreated effluent of which can be suitable for use as a feed to an FCC reactor.

Hydroprocessing of high nitrogen feed using bulk catalyst

The invention includes a hydrotreating method for increased CO content comprising: contacting an olefinic naphtha feedstream with a hydrogen-containing treat gas stream and a hydrotreating catalyst in a reactor under hydrotreating conditions sufficient to at least partially hydrodesulfurize and/or hydrodenitrogenate the feedstream, wherein the feedstream and the hydrogen-containing treat gas stream collectively have greater than 10 vppm CO content and/or wherein the reactor inlet sees an average CO concentration of greater than 10 vppm, wherein the hydrotreating catalyst comprises a catalyst having cobalt and molybdenum disposed on a silica-based support, and wherein the hydrotreating conditions are selected such that the catalyst has a relative HDS activity at least 10% greater than an identical catalyst under identical conditions except for a collective CO content of the feedstream and/or hydrogen-containing treat gas being &#x3c;10 vppm and/or a reactor inlet CO content &#x3c;10 vppm.

Hydroprocessing methods utilizing carbon oxide-tolerant catalysts

This invention provides methods for multi-stage hydroprocessing treatment of FCC naphthas for improving the overall production quantity of naphtha boiling-range materials during naphtha production for low sulfur gasolines. Of particular benefit of the present processes is the selective treating of cat naphthas to remove gums instead of undercutting the overall naphtha pool by lowering the end cutpoints of the cat naphtha fraction. This maximizes the amount of refinery cat naphtha that can be directed to the gasoline blending pool while eliminating existing processing problems in hydrodesulfurization units. The processes disclosed herein have the additional benefit of minimizing octane losses in the increased naphtha pool volume.

Pretreatment of FCC naphthas and selective hydrotreating

Non-hydrotreated biocomponent feeds can be mixed with mineral feeds and processed under catalytic isomerization/dewaxing conditions. The catalytic isomerization/dewaxing conditions can be selected to advantageously also substantially deoxygenate the mixed feed. Diesel fuel products with improved cold flow properties can be produced.

Hydroprocessing of diesel range biomolecules

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Bedminster, NJ, United States of America

William Joseph Novak