Exxon Research and Engineering Company

William J Murphy

Alberto Ravella

Lyle Edwin Moran

Joseph P Boyle

David H Shaw

Ashok Uppal

Lawrence J Lawlor

Edmund M Mackert

Gary L Archambeault

Biddanda V Achia

Heavy metals contaminants in soils are fixed and rendered non-leachable by the process of heating the metal contaminated soil containing a hydrocarbon liquid, at an elevated temperature sufficient to convert at least a part of the liquid hydrocarbon into solid carbon or coke deposited on the surface of the soil and subjecting the thus heated soil to sufficient microwave radiation to sustain at least a partial fusion or melting process that results in a fixing of the heavy metals in the soil.

Metal fixation in oily waste contaminated soil using microwave radiation

An alkylation process which utilizes a solid alkylation catalyst is disclosed. The catalyst, which has carbonaceous material adsorbed thereto, is regenerated by reacting the adsorbed carbonaceous material. The reaction step is accomplished by heating the catalyst in the presence of ozone to form an ozonated hydrocarbon, wherein the ozonated hydrocarbon includes carbonyl carbons. The ozonated hydrocarbon is removed by desorbing the carbonyl carbons from the solid alkylation catalyst. The carbonaceous material is preferably reacted at a temperature ranging from about 20.degree. C. to 200.degree. C. The ozone is preferably in a gaseous stream at a concentration ranging from about 1 to 50 volume percent. The carbonyl components are preferably desorbed from the heated alkylation catalyst by sweeping the catalyst with a desorption fluid.

Heterogeneous alkylation and regeneration of alkylation catalysts

Low value hydrocarbons can be upgraded by contact with the products formed during irradiation of a hydrogen donor and water using microwave energy in the presence of at least one plasma initiator.

Upgrading of low value hydrocarbons using a hydrogen donor and microwave

This invention relates to a method of producing a softer asphalt product with improved low temperature properties and reduced solids buildup from an asphalt feed which comprises measuring the penetration and Penetration Index of the asphalt feed and heat soaking the asphalt feed in the presence of at least one C.sub.1 to C.sub.5 halogenated aliphatic hydrocarbon as dehydrogenation agent wherein from about 0.05 to about 10 wt. % of the dehydrogenation agent, based on weight of the asphalt, is present during heat soaking, at a temperature ranging between about 300.degree. C. and about 400.degree. C., said temperature being sufficient to increase the penetration and Penetration Index over that of the asphalt feed provided that the temperature should not exceed the temperature at which onset of coking occurs and further provided that the asphalt product has a trichloroethylene solubles content of at least about 99.5 wt. %, based on asphalt.

Method of producing asphalt having an increased penetration and

C.sub.1+ hydrocarbons can be effectively converted to primarily unsaturated hydrocarbon and hydrogen by subjecting the C.sub.1+ hydrocarbon to microwave radiation in the presence of water and at least one plasma initiator that is capable of initiating an electric discharge in an electromagnetic field.

Conversion of hydrocarbons using microwave radiation

Plasma initiators that have become deactivated due to the accumulation of carbonaceous deposits, sulfur deposits, or both thereon can be regenerated by contact with a gas containing molecular hydrogen in the presence of microwave radiation.

Regenerating a plasma initiator using molecular hydrogen in the presence

Plasma initiators that have become deactivated due to the accumulation of carbonaceous deposits, sulfur deposits, or both thereon can be regenerated by contact with an oxygen-containing gas in the presence of microwave radiation.

Regenerating a plasma initiator using oxygen-containing gas in the

A mixture of methane, water and carbon dioxide can be effectively converted to carbon monoxide and hydrogen by subjecting the mixture to microwave radiation in the presence of at least one plasma initiator that is capable of initiating an electric discharge in an electromagnetic field.

Conversion of methane, carbon dioxide and water using microwave radiation

This invention relates to a method for producing asphalt that has improved low temperature properties. More specifically, the penetration and Penetration Index of an asphalt can be increased if the asphalt is heat soaked in the presence of a dehydrogenation agent at a temperature above the temperature at which oxidation of the asphalt occurs and below the temperature at which coking is initiated. Polyvinyl chloride and a chlorinated wax are preferred dehydrogenation agents.

Methane can be effectively converted to acetylene, ethylene, and hydrogen by subjecting the methane to continuous microwave radiation in the presence of at least one plasma initiator that is capable of initiating an electric discharge in an electromagnetic field.

Conversion of methane using continuous microwave radiation (OP-3690)

Methane can be effectively converted to acetylene, ethylene, and hydrogen by subjecting the methane to pulsed microwave radiation in the presence of at least one plasma initiator that is capable of initiating an electric discharge in an electromagnetic field.

Conversion of methane using pulsed microwave radiation

The activity maintenance of the plasma initiators used during the upgrading of a hydrocarbon feedstock in a reaction zone using microwave radiation can be improved if molecular hydrogen is added to the reaction zone such that the weight ratio of carbon (in the molecules in contact with the plasma initiators) to hydrogen is maintained at less than 6:1 during upgrading.

Method for improving the activity maintenance of a plasma initiator

Low value hydrocarbons can be upgraded by contact with the products formed during irradiation of a hydrogen donor using microwave energy in the presence of at least one plasma initiator.

C.sub.2 + hydrocarbons can be effectively converted to primarily unsaturated hydrocarbons and hydrogen using microwave radiation in the presence of at least one plasma initiator that is capable of initiating an electric discharge in an electromagnetic field.

Conversion of C.sub.2 + hydrocarbons using microwave radiation (OP-3515)

This invention relates to a novel transition metal crystalline alumino-silicate, a method for its preparation and its use, and to a transition metal extracted crystalline alumino-silicate, a method for its preparation from the aforesaid transition metal crystalline alumino-silicate and its use as a catalyst, especially for selective dewaxing of hydrocarbon oils. The transition metal crystalline alumino-silicate and the transition metal extracted crystalline alumino-silicate are characterized by XRD patterns set forth in Table I.

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Brights Grove, Canada

William J Murphy