The Standard Oil Company

William J Miloscia

Brandford E Giddings

Robert W Lee

Louis R Trott

Christopher L Bodolus

Frederick W Haas

John A Turnbaugh

A process for the impact modification of a plastic with a rubber polymer to form a thermoplastic resin in a reactor extruder is provided. The process includes the steps of dissolving a rubber polymer in a solvent selected from the group consisting of ethylenically unsaturated monomers and non-polymerizable organic compounds to form a feed solution, introducing the feed solution into the feed section of a twin screw reactor extruder, introducing a separate feed stream containing a material in sufficient amount to precipitate the rubber polymer, heating the feed solution and feed stream under pressure to a temperature sufficient for polymerization to begin, polymerizing the monomers with the rubber polymer in the reactor extruder to form a thermoplastic resin and extruding the thermoplastic resin through a die. A novel ABS thermoplastic resin is also provided having a uniform distribution of rubber particles dispersed within the plastic phase of the resin, the rubber particles ranging in size of from about 0.01 to 0.25 microns. The thermoplastic portion of resin has an acrylonitrile content of more than about 26 weight percent and can have as much as 60 weight percent.

Process for the preparation of rubber-modified thermoplastic resins

A process for the impact modification of a plastic with a rubbery polymer to form a thermoplastic resin in a reactor extruder is provided. The process includes the steps of dissolving a rubbery polymer in at least one ethylenically unsaturated monomer to form a feed solution, introducing the feed solution into the feed section of a twin screw reactor extruder, heating the feed solution under pressure to a temperature sufficient for polymerization to begin, shearing the feed solution until the solids content formed is equal to at least about twice the rubber content in the feed solution so as to produce a phase inversion product wherein discrete particles of rubber become encapsulated in a continuous phase of plastic polymer formed from the ethylenically unsaturated monomer, thereafter reacting the phase inversion product until at least about 70 weight percent of the feed solution has been converted to a thermoplastic resin, and extruding the said thermoplastic resin through a die. A novel thermoplastic resin is also provided having a uniform distribution of rubber particles dispersed within the plastic phase of the resin, the rubber particles ranging in size of from about 0.01 to 0.50 microns. The process is particularly useful for the preparation of high nitrile and ABS type resins.

Manufacture of rubber modified copolymers in an extruder type reactor

The invention herein is directed toward a method for forming a coating on the surface of a catalyst and includes the steps of dissolving a membrane forming compound in a hdyrocarbon solvent, adding the catalyst to the solvent and agitating to form a mixture and finally drying the mixture to form particles of the catalyst having a coating of the membrane forming compound. Particularly suitable for the polymerization of monoolefins are Ziegler-Natta catalyts which can be coated according to the foregoing method. The compounds forming the coating include the silicone greases obtained by mixing a filler material with a dimethylpolysiloxane fluid.

Monoolefin catalysts and method for the preparation thereof

Impact-resistant polymers having excellent color, clarity and low permeability to gases and vapors are prepared by polymerizing in a specified manner an olefinically unsaturated nitrile such as acrylonitrile, an ester of an olefinic acid such as methyl acrylate, or a vinyl ester such as vinyl acetate, and a vinyl aromatic monomer such as styrene optionally in the presence of a diene rubber.

Nitrile barrier resins and process for their manufacture

Nitrile polymer solids having good stability against loss of impact strength and resin yellowing are recovered from latex with minimal or no use of stabilizers in a screw extruder.

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Shaker Heights, OH, United States of America

William J Miloscia