Battelle Development Corporation

William J Huffman

Edgel P Stambaugh

Herman Nack

Melville E Hillman

Edward S Lipinsky

Billy R Allen

Continuous chemical and biological reactions may be carried out in a liquid fluidized reactor (1). Improved mixing and mass transport between gas/liquid/solid phases is provided by fluidizing large particles (2) with a liquid in a dense bed in the bottom of the reactor (1) while recirculating small entrained particles (3) and the liquid through the reactor (1), particle separator (9), external regenerator (10) and conduits (7) and (8) back through the dense bed of large particles (2).

Liquid multisolid fluidized bed processing

Disclosed is a method for thermochemically converting a carbohydrate material into ethanol wherein the carbohydrate material and a metal salt are reacted at elevated temperature to form an intermediate carbohydrate complex salt and/or a lactate metal salt which then is pyrolyzed in the presence of water into ethanol. Preferred carbohydrate materials for the process are various sugars and the metal salt preferably is a metal oxide, hydroxide, or carbonate. The intermediate complex and/or lactate salt may be separated from its aqueous reaction mixture prior to its pyrolysis to reduce the ultimate separation of ethanol from water. Alternatively, the metal of the metal salt may be one whose carbonate decomposes to metal oxide and carbon dioxide during the pyrolysis step of the process to generate said metal salt in situ.

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Worthington, OH, United States of America

William J Huffman