The Dow Chemical Company

William J Fairchok

Bruce P Thill

Mark J McKinley

Frederick W Stanley, Jr

Ralph E Friedrich

Thomas T Chiu

Thomas O Ginter

A thermoplastic laminate structure consisting of a plurality of layers wherein at least one of the layers is the adhesive polymeric blend. The adhesive polymeric blend comprises a dispersed phase of poly-2-oxazoline and a glycol and a continuous phase of grafted polypropylene. The preferred poly-2-oxazoline is poly-2-ethyl-2-oxazoline and the preferred glycols are polyalkylene glycols. The grafted polypropylene comprises from about 50 to 80 percent by weight of the total polymeric blend. The grafted polypropylene contains from about 0.1 to about 5 percent by weight total polymer of a graft portion derived from an .alpha.,.beta.-ethylenically unsaturated carboxylic acid or an unsaturated cyclic anhydride wherein said glycol is in slight excess to the graft, i.e., molar ratio of glycol to graft is 1.1 to about 1.5:1.

Thermoplastic laminate tie layer using a polymeric blend adhesive

A process for absorbing polar materials using a crosslinked polymeric composition such as poly-2-ethyloxazoline and ethyleneamine tetracetic acid. The crosslinked polymeric composition swells into a gel-like mass in the presence of polar materials to entrap them.

Process for absorbing polar materials using transamidated

A polymeric composition comprising a poly-2-oxazoline reacted by transamidation with a carboxylic acid, anhydride, salts of a carboxylic acid or combination thereof which can be blended with another polymeric composition to form a water wettable blend. In another aspect, the poly-2-oxazoline is crosslinked with a polybasic carboxylic acid by transamidation. The crosslinked polymeric composition is useful as an absorbent for polar materials.

Transamidated poly-2-oxazoline compositions useful as wetting agents for

Quaternary carboxamide polymers such as N-(triethylammonium ethyl)acrylamide chloride are prepared by simultaneously contacting a carboxamide polymer with an aldehyde such as formaldehyde, a secondary amine such as dimethylamine and a quaternizing agent such as methyl chloride. By such method, quaternary carboxamide polymers useful in a variety of applications such as emulsion breaking and water clarification are readily prepared.

Method for the preparation of quaternary carboxamide polymers

Water-miscible monomers such as acrylamide are polymerized continuously to produce a concentrated solution of a high molecular weight polymer by passing a mixture of a water-immiscible organic liquid and an aqueous solution of at least 20 weight percent of the monomer through a tubular reactor, e.g., a polyethylene tube, having internal surfaces that are readily wetted by the hydrocarbon liquid and polymerizing the monomer in the reactor. The polymerized product is recovered as a water-in-oil emulsion wherein the polymer resides in the dispersed aqueous phase or as a solid strand which is a high solids aqueous solution containing at least 20 weight percent of the water-soluble polymer of the water-miscible monomer.

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Saginaw, MI, United States of America

William J Fairchok