E.i. Dupont De Nemours and Company

William J Chambers

Robert P Foss

Christina N Lazaridis

Louis Plambeck, Jr

A photosensitive composition, a photosensitive element employing said composition, and an improved photoimaging method that utilizes the disclosed composition. The improved method concerns a photosensitive element, formed from a photosensitive composition having a substrate layered with silver halide particles in operative association with a polymeric coupler, latently imaged, developed to render the imaged area insoluble, and washed to remove the undeveloped portion of the layer, wherein the improvement comprises addition of selected dispersed pigments to the polymeric coupler so that the optical density of the final image is neutral black.

Photosensitive composition and method for forming a neutral black image

A method for producing a photopolymer image comprising (a) exposing, imagewise, a photosensitive element to actinic radiation, said element comprising a substrate coated with a photosensitive layer containing dispersed silver halide particles in operative association with a continuous film-forming phase of polymeric coupler, said coupler having (i) a number average molecular weight of about 2,000 to 100,000, (ii) a content of about 10 to 100 milliequivalents per 100 g of polymeric coupler of acidic methylene coupler groups and about 15 to 175 milliequivalents per 100 g of polymeric coupler of at least one of carboxylic, sulfonic and phosphonic acid groups, and (iii) the ability to couple with a monofunctional developing agent thus becoming water-insoluble; (b) developing (insolubilizing) the latent image; and (c) removing the undeveloped, soluble portion of the photosensitive element by washing with aqueous solvent.

Photoimaging process

A photopolymerizable element, preferably a lithographic plate, is provided. This element comprises a substrate bearing a photopolymerizable layer having a weight of about 1 to about 90 mg/dm.sup.2, said layer comprising:

Methods of imaging photopolymerizable materials containing diester

Photopolymerizable compositions containing

Elements and method which use photopolymerizable compositions based on

Radiation sensitive element having a thin photopolymerizable layer

Photopolymerizable compositions based on salt-forming polymers and

Photosensitive polyaldehydes are provided which have the formula: ##STR1## wherein R is a photosensitive end group selected from ##STR2## R.sup.1 is H or n-alkyl of 1-5 carbon atoms, preferably H, R.sup.2 is (a) n-alkanoyl of 1-4 carbon atoms or (b) n-alkanoyl of 1-4 carbon atoms or ##STR3## when R.sup.1 is H, and N IS A POSITIVE INTEGER OF ABOUT 10-4000. The polyaldehydes are prepared by the anionic polymerization of the appropriate aldehyde with an initiating amount of an alkali metal or tetraalkylammonium alkoxide of RO in the above formula. The polyaldehydes are useful in articles and methods of relief imaging and in lithographic plates.

Photosensitive article having polyaldehydes and its use in photoimaging

Photosensitive polyaldehydes are provided which have the formula: ##STR1## WHEREIN R is a photosensitive end group selected from ##STR2## R.sup.1 is H or n-alkyl of 1-5 carbon atoms, preferably H, R.sup.2 is (a) n-alkanoyl of 1-4 carbon atoms or (b) n-alkanoyl of 1-4 carbon atoms or ##STR3## when R.sup.1 is H, and n is a positive integer of about 10-4000. The polyaldehydes are prepared by the anionic polymerization of the appropriate aldehyde with an initiating amount of an alkali metal or tetraalkylammonium alkoxide of RO in the above formula. The polyaldehydes are useful in articles and methods of relief imaging and in lithographic plates.

Photosensitive polyaldehydes and use in photoimaging

Aqueous dispersions are disclosed containing up to 50% of particulate solids having a particle size less than 1.mu. and consisting essentially of

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Wilmington, DE, United States of America

William J Chambers