The Dow Chemical Company

Dow Global Technolgoies LLC

Rohm and Haas Company

Stevens Institute of Technology

William I Harris

David J Moll

Chan Han

Robert L Sammler

Daryl John Gisch

George P Korfiatis

Harlan Robert Goltz

Fredrick W Vance

Xiaoguang Meng

Christos Christodoulatos

David C McDonald

Mazakhir Dadachov

Geofrey Paul Onifer

Daniel B Rice

Robert E Reim

Dennis A Keeley

William J Harris

David H West

Robert M Strom

Alfred Karl Schultz

Rex R Stevens

Thomas Caldwell Young

H Robert Goltz

Charles R Marston

Suresh Subramonian

Philip J Carlberg

William G Worley

Gregoire Cardoen

Jose Antonio Trejo-O'Reilly

Bruce S Holden

James R Stahlbush

James A Jagodzinski

Marvin H Tegen

Robert J Olsen

Leming Gu

Antonio Dorta

Robert E Gaidos

Natalie N Westphal

Marvin K Tegen

Doreen C Keptner

A catalyst prepared by polymerizing 0-98 weight % butylstyrene; 0-80 weight % vinyl toluene; 1.5-25 weight % divinyl benzene having 1-98 weight % of ethyl vinyl benzene; and 0-80 weight % styrene. Copolymer beads are made, sulfonated, and used as a catalyst.

Strong acid catalyst composition

A water-insoluble copolymer including an epoxide containing structural unit represented by Formula (I), wherein: the epoxide containing group is positioned meta, ortho or para on the ring relative to the bond linkage with the polymer backbone; L is an optional linking group; and R, Rand Rare independently selected from: hydrogen, or a substituted or unsubstituted hydrocarbyl group. 

Water insoluble copolymer including pendant aryl epoxide groups

Use a modified, amine-functionalized anion exchange resin as a catalyst to produce a bishalohydrin ether and then dehydrohalogenate the bishalohydrin ether with an aqueous inorganic hydroxide mixture to yield a liquid epoxy resin.

Production of epoxy resins using improved ion exchange resin catalysts

The present invention relates to a method for the production of improved shell functionalized ion exchange resins from core/shell copolymer having a highly crosslinked core.

Shell functionalized ion exchange resins

The invention generally relates to amination reactions and amination reaction products, and particularly to methods for aminating vinyl aromatic polymers utilizing tertiary amines. In one embodiment, the invention includes conducting an amination reaction by combining a tertiary amine and a vinyl aromatic polymer comprising benzyl chloride groups to form a reaction mixture and maintaining the pH of the reaction mixture within a designated range. In another embodiment, the invention includes an aminated vinyl aromatic polymer. In yet another embodiment, the invention includes an ion exchange resin including quaternary ammonium functionality. The invention is useful in preparing ion exchange resins suitable for a variety of applications such as the removal of perchlorate ions from water sources and recovery of gold cyanide from mining leach solutions.

Amination of vinyl aromatic polymers with tertiary amines

A method for processing effluent from a chloromethylation of a vinyl aromatic polymer wherein the effluent includes catalyst and volatile organics, and wherein the method includes the steps of:

Method for processing effluent from chloromethylation of vinyl aromatic polymers

A method for removing dissolved contaminants from solution using a surface-activated crystalline titanium oxide product having a high adsorptive capacity and a high rate of adsorption with respect to dissolved contaminants, in particular, arsenate and arsenite. Preferably, the titanium oxide product includes crystalline anatase having primary crystallite diameters in the range of 1-30 nm. The surface-activated titanium oxide is combined with other filter media to further improve the removal of dissolved contaminants.

Methods of preparing a surface-activated titanium oxide product and of using same in water treatment processes

An improved process for conducting an etherification reaction has been discovered. The process employs a macroporous strong-acid, cation-exchange resin catalyst prepared at a temperature of about 120.degree. C. or higher with a reduced amount of divinylbenzene crosslinker. The etherification catalysts produced in the invention display equivalent or superior catalytic activity than conventional catalysts and are less expensive to produce than conventional catalysts due to reduced amounts of crosslinker.

Process for conducting etherification reactions using as catalysts

Seeded cation-exchange resin beads are particularly susceptible to oxidative degradation which results in the leaching of organic carbon fragments. The leachability of organic carbon fragments of molecular weights greater than 1000 g/mol is reduced to less than 800 ppm by effectively crosslinking the copolymers that comprise the seeded cation-exchange resin beads. Crosslinking can be achieved either during sulfonation by increasing sulfone bridge formation or before sulfonation by either alkylene bridge formation or by incorporation and subsequent activation of a crosslinkable functionality in the copolymer that forms the seed in the seeded polymer bead process.

Crosslinked seeded copolymer beads and process of manufacture

Seeded cation-exchange resin beads are particularly susceptible to oxidative degradation which results in the leaching of organic carbon fragments. The leachability of organic carbon fragments of molecular weights greater than 1000 g/mol is reduced to less than 800 ppm by effectively crosslinking the copolymers that comprise the seeded cation-exchange in beads Crosslinking can be achieved either during sulfonation by increasing sulfone bridge formation or before sulfonation by either alkylene bridge formation or by incorporation and subsequent activation of a crosslinkable functionality in the copolymer that forms the seed in the seeded polymer bead process.

A process for preparing crosslinked copolymer beads suitable for making polymeric adsorbents and ion-exchange resins comprising the substantially adiabatic suspension copolymerization of at least one monoethylenically unsaturated monomer with at least one polyethylenically unsaturated monomer in the presence of an effective amount of free-radical polymerization initiators.

Preparation of ion exchange and adsorbent copolymers

The invention concerns preparation of porous copolymer beads by a seeded polymerization process employing gel copolymer seed particles. The process comprises initially providing a plurality of gel-type copolymer seed particles prepared by polymerization of at least one first monovinylidene monomer and a first cross-linking monomer. A second monomer mixture comprising at least one second monovinylidene monomer, a second cross-linking monomer, and a phase-separating diluent is thereafter imbibed by the seed particles and polymerized therein. The process is characterized by selecting the first monovinylidene monomers such that the phase-separating diluent and second monovinylidene monomers are capable of being imbibed by the seed particles in an amount sufficient to form a porous copolymer. The porous copolymer beads produced have stable polymeric structures and good physical properties that render them useful in preparing ion-exchange resins and polymeric adsorbents.

Seeded porous copolymers and ion-exchange resins prepared therefrom

A process is provided for preparing ion-exchange resin particles of relatively uniform size by partial functionalization of non-uniform copolymer beads with ion-exchange groups. The non-uniform copolymer beads are preferably functionalized in a manner such that the ion-exchange groups are substituted at available sites which are most accessible to diffusion by functionalizing agents. Due to the size difference between individual copolymer particles, a greater proportion of available sites is functionalized in a small particle when compared to that of a large particle. Due to the greater proportion of ion-exchange groups present in a small particle, the small particle swells relatively more than a larger particle. The result is effectively a narrowing of the size distribution for the partially functionalized resin particles. The relatively uniform resin particles obtained by the process have performance advantages, such as reduced pressure drops, improved exchange kinetics, rinse efficiencies, and separation efficiencies when compared to fully functionalize ion-exchange resins that are non-uniform in particle size.

Method of preparing uniform size ion exchange resin particles by partial

A process for preparing copolymer beads suitable for conversion to ion exchange resins, comprising forming a polymeric matrix containing a plurality of free radicals, and continuously adding to said matrix, under conditions suitable for polymerizing a monomer feed which is imbibed by and polymerized within the matrices. Ion exchange resins prepared from beads made by such process exhibit improved osmotic and mechanical properties.

Ion exchange resins prepared by sequential monomer addition

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Midland, MI, United States of America

William I Harris