Bell Telephone Laboratories

William H Grodkiewicz

Shobha Singh

Legrand G Van Uitert

LeGrand G Van Uitert

Stuart H Wemple

A fabrication technique is described for making various devices in which a certain type of glass is used as a surface protection layer. The glass layers are formed by particle bombardment (generally sputtering or E-beam) of a glass target. Devices with such surface layers are also described. Such glass layers are highly advantageous as encapsulating layers, diffusion barrier layers, etc., particularly for optical type devices and certain semiconductor devices. Particularly important is the preparation procedure for the glass target used in the bombardment process. The glass layers are moisture stable, act as excellent barriers against diffusion, and are usable up to quite high temperatures (i.e., in diffusion doping procedures) without cracking or peeling. The glass layers also provide long-term protection against atmosphere components including water vapor, oxygen, atmosphere pollution contaminants, etc., and can be removed by standard etching techniques.

Fabrication procedure using arsenate glasses

ZnCl.sub.2 optical fibers are advantageously used for transmission of radiation in the infrared portion of the spectrum. Losses as low as 10.sup.-3 dB/km may be obtained when radiation of wavelength between 3.0 and 4.5 microns is transmitted in such fibers. Fabrication techniques allow for the formation of graded fibers to further improve transmission characteristics.

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Murray Hill, NJ, United States of America

William H Grodkiewicz