Avery Dennison Corporation

William F Scholz

Norman A Conti

Robert H Van Ham

Eric Chen-nan Su

Dong-Tsai Hseih

Frederick N Miekka

Christopher D Meader

Ronald Ugolick

Luigi Sartor

Edward I Sun

Johannes Schut

Wen-Chen Su

David J Scanlan

Steven J Vargas

Jose Luis Mendez

Karl Josephy

Rick J Verhines

Richard P Randall

Richard P Randall, Legal Representative

Louis C Van Ham, Legal Representative

Robert H Van Ham, Deceased

Wan-Chen Su

Overlaminated faceless PSA label constructions of this invention comprise a low material cost, thin prelaminate PSA construction having a layer of pressure-sensitive material disposed on a release surface of a removable substrate, and a nonblocking continuous film disposed over a surface of the layer of pressure-sensitive adhesive to render the pressure-sensitive adhesive tack free. An optically transparent overlaminate film layer is disposed over the nonblocking continuous film, and a printed indicia is interposed between the overlaminate film layer and nonblocking continuous film. The prelaminate PSA construction does not include a conventional facestock formed from paper, cardboard or plastic, and is highly conformable.

Overlaminated pressure-sensitive adhesive construction

Ink-imprintable release coating compositions are described which comprise a polymer comprising a polyurethane, a fluoroacrylate polymer or copolymer, or an addition cured or a condensation cured silicone polymer containing dispersed and/or emulsified resin particles, resin particle domains, or both, and, optionally, inorganic particles. The resin particles comprise resins which are different from the polymers and the resins comprise polyurethanes, polyamides, and polyureas. Ink-imprintable label, tape and stamp constructions also are described which comprise a plurality of contiguous labels, tapes or stamps in a roll or stacked sheet configuration without an independent release liner wherein the labels, tapes and stamps have a pressure-sensitive adhesive on the back surface and a cured ink-imprintable release coating on the face surface.

Ink-imprintable release coatings, and pressure sensitive adhesive constructions

Faceless PSA label constructions of this invention comprise a flexible substrate having a release surface, and a layer of pressure-sensitive adhesive disposed on the release surface. A nonblocking continuous film that, in combination with the pressure-sensitive adhesive is sufficiently self supporting, is disposed over a surface of the layer of pressure-sensitive adhesive to render the pressure-sensitive adhesive tack free. The continuous film is selected from the group of film-forming polymers consisting of polyamide resins, polyester resins, polyurethane resins, polyacrylate resins, vinyl acetate resins and mixtures thereof having a tensile strength of at least 200 psi, and a percent elongation of at least 50. The continuous film can be applied sequentially or simultaneously with the PSA. For purposes of simultaneous application it is desired that the continuous film be formed from a material having a hot melt viscosity that is within a factor of about two times a hot melt viscosity for the PSA. The completed faceless PSA label construction is adapted to receive and retain printing or marking indicia directly onto a surface of the continuous film.

Faceless pressure-sensitive adhesive construction

Prelaminate pressure-sensitive adhesive (PSA) constructions comprise, a first substrate, a coating or release material on a surface of the first substrate, a PSA layer disposed on the coating of release material, and a detackified layer (DL) disposed on a surface of the PSA layer to form a continuous film covering the PSA layer. In first and second embodiments of the construction the DL is activatable to form a tacky layer on top of the PSA layer for lamination with a second substrate. In a third embodiment, the DL includes constituents that when activated migrate into the PSA layer to expose the PSA layer tacky surface for lamination with a second substrate. The prelaminate PSA constructions are completely nonblocking to a minimum 24 hour blocking temperature of about 50&deg; C. at pressure of about 40 kilopascals, thereby allowing such prelaminate PSA construction to be collected, stored, and or transported before being laminated without adhesive interference occurring between continuous layers. The DL in each embodiment is activatable in less than five seconds to provide a tacky layer having a sufficient open tack time to permit lamination at less than about 100&deg; C.

Prelaminate pressure-sensitive adhesive constructions

Faceless PSA label constructions of this invention comprise a flexible substrate having a release surface, and a layer of pressure-sensitive adhesive disposed on the release surface. A nonblocking continuous film that, in combination with the pressure-sensitive adhesive is sufficiently self supporting, is disposed over a surface of the layer of pressure-sensitive adhesive to render the pressure-sensitive adhesive tack free. The continuous film is selected from the group of film-forming polymers consisting of polyamide resins, polyester resins, polyurethane resins, polyacrylate resins, vinyl acetate resins and mixtures thereof having a tensile strength of at least 200 psi, and a percent elongation of at least 50. The continuous film can be applied sequentially or simultaneously with the PSA. For purposes of simultaneous application it is desired that the continuous film be formed from a material having a hot melt viscosity that within a factor of about two times a hot melt viscosity for the PSA. The completed faceless PSA label construction is adapted to receive and retain printing or marking indicia directly onto a surface of the continuous film.

Overlaminated faceless PSA label constructions of this invention comprise a low material cost, thin prelaminate PSA construction having a layer of pressure-sensitive material disposed on a release surface of a removable substrate, and a nonblocking continuous film disposed over a surface of the layer of pressure-sensitive adhesive to render the pressure-sensitive adhesive tack free. An optically transparent overlaminate film layer is disposed over the nonblocking continuous film, and a printed indicia is interposed between the overlaminate film layer and nonblocking continuous film. The prelaminate PSA construction does not include a conventional facestock formed from paper, cardboard or plastic, and is highly conformable. The overlaminated film layer can be applied to the prelaminate faceless PSA construction by pressure lamination, via a further PSA layer interposed between continuous film and the overlaminate film layer, or by heat and pressure by forming one of the continuous film or overlaminate film layers from a heat-activatable material that itself forms a laminating adhesive surface. Alternatively, the overlaminate film layer can be applied to the prelaminate PSA construction as a film-forming material. The overlaminated PSA construction has a sufficient Gurley stiffness to permit high-speed converting and dispensing by peel plate equipment without sacrificing the high degree of conformity provided by the underlying prelaminate PSA construction.

A pressure-sensitive adhesive construction repulpable in paper recycling operations, comprising a facestock which is repulpable; a dispersible pressure-sensitive adhesive comprising tacky emulsion polymers dispersible in water; and a nondispersible pressure-sensitive adhesive comprising tacky emulsion polymers not dispersible in water, wherein, on the facestock, the dispersible pressure-sensitive adhesive is closer to the facestock than the nondispersible pressure-sensitive adhesive, thereby improving both adhesive performance and recyclability.

Method for producing repulpable pressure-sensitive adhesive

Ink-imprintable release coatings, and pressure sensitive adhesive

A tackified, mixed rubber, hot melt PSA deinking composition and an improved process for removing inks and other contaminants from printed wastepaper are provided. A preferred deinking composition contains a mixture of SB and SIS rubbers, tackified with at least one hydrocarbon resin tackifier and at least one rosin-based tackifier. In an improved deinking or recycling process, the novel composition is added to a paper slurry, either directly or as PSA-coated paper or label stock, and significantly reduces the number of contaminants that remain after screening and forward cleaning.

Process for removing contaminants from paper pulp using a deinking

Repulpable pressure-sensitive adhesive constructions having multiple

A splicing tape adhesive comprising 97% to 45% by weight of an emulsion polymer formed of from about 80% to 90% by weight of monomers comprising a major portion of at least alkyl acrylate containing from 4 to about 8 carbon atoms in the alkyl group and from about 20% to 10% by weight of a least one carboxylic acid, said emulsion polymer formed in the presence of anionic and nonionic surfactants to provide a polymer having a glass transition temperature of -15.degree. to -50.degree. C. in the presence of a chain transfer agent, from about 25% by weight of an acrylic polymer having a glass transition of less than -50.degree. C. and about 3% to about 20% by weight plasticizer.

Repulpable splicing tape

A water-dispersible, inherently tacky pressure-sensitive adhesive comprising a tacky emulsion polymer formed of from about 80% to 90% by weight of monomers comprising a major portion of at least alkyl acrylate containing from 4 to about 8 carbon atoms in the alkyl group and from about 20% to 10% by weight of a mixture of acrylic acid with at least an oleophilic unsaturated carboxylic acid, said emulsion polymer formed in the presence of anionic and nonionic surfactants to provide a polymer having a glass transition temperature of -15.degree. to -50.degree. C. A sufficient amount of chain transfer agent is employed to provide an emulsion polymer which when coated on a repulpable paper substrate enables recovery of paper fibers substantially free of adhesive under conditions of TAPPI Useful Method 213 and/or 204, and resistant to loss of adhesive properties on exposure to high humidity.

Growing community of inventors

Altadena, CA, United States of America

William F Scholz