Trw Limited

William D English

Charles W Clendening, Jr

Martin H Mach

Joseph A Neff

Trecil D Dreiling

William M Chew

A system for preparing excited molecular oxygen in the excited singlet-delta electronic state for use in a chemical laser that minimizes salt formation utilizing the common ion effect. In one version, basic hydrogen peroxide is formed by combining H.sub.2 O.sub.2 and at least two bases. In another version of the invention, the basic hydrogen peroxide is reacted with a gas containing at least two halogen species.

Gas generating system for chemical lasers

A mixture of at least two particulate metals capable of undergoing an exothermic reaction to form an intermetallic compound is provided to sustain decomposition of borane reactants to yield hydrogen or deuterium.

Solid propellant hydrogen generator

A liquid mixture of tetrafluorammonium bifluoride in anhydrous liquid hydrogen fluoride in the liquid and/or gaseous decomposed state serves as an oxidizer for fuels. Tetrafluorammonium bifluoride is present in the liquid in an amount up to about 50 mole percent.

Method of oxidation of fuels with tetrafluorammonium bifluoride

Tris-tetrafluorammonium hexafluoraluminate, (NF.sub.4).sub.3 AlF.sub.6, a new compound, is synthesized by forming a mixture of solid aluminum trichloride in a solution of a molar excess tetrafluorammonium bifluoride in anhydrous hydrogen fluoride, at a temperature of about -78.degree. C. or less. The mix is then rapidly heated to a temperature of about 40.degree. C. to the decomposition temperature of the product until all the solids dissolve. The solution containing the dissolved aluminum trichloride is evaporated under vacuum conditions to cause crystallization of (NF.sub.4).sub.3 AlF.sub.6.

Tris-tetrafluorammonium hexafluoraluminate and its method of preparation

The compound NF.sub.4 MF.sub.6 where M is a Group V metalloid is reacted with a fluoride of sodium to yield tetrafluorammonium bifluoride in solution with hydrogen fluoride and a precipitate of the formula NaMF.sub.6. The preferred metaloid is antimony. The formed tetrafluorammonium bifluoride may be converted to NF.sub.4 BF.sub.4 by reaction with BF.sub.3.

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Orange, CA, United States of America

William D English