Dynamit Nobel Aktiengesellschaft

Werner Schmidt

Egon N Petersen

Herbert Klinkenberg

Norbert Vollkommer

Hermann Richtzenhain

Klaus-Dieter Steffen

Gerhard Schade

Gerhard Bier

Rudeger Minke

Werner Pohl

Ernst Schainberg

Gunter Tappe

Rudiger Minke

The invention relates to solutions of silanols prepared by hydrolysis of alkyltrialkoxysilanes whose alkoxy groups are partially or completely hydrolyzed. Preferred hydrolyzed alkyltrialkoxysilanes are of the formula CH.sub.3 --CH.sub.2 .dbd.CH.sub.2 --Si(OH).sub.n (OH').sub.3-n.

Stable aqueous impregnating solutions prepared from hydrolyzed alkyl

This invention relates to solutions of silanols prepared by hydrolysis of alkyltrialkoxysilanes whose alkoxy groups are partially or completely hydrolyzed. Preferred hydrolyzed alkyltrialkoxysilanes are of the formula CH.sub.3 --CH.sub.2 --CH.sub.2 --Si(OH).sub.n (OH').sub.3-n.

Stable aqueous impregnating solutions prepared from hydrolyzed

Agent for impregnating materials that contain cellulose, mainly paper and wood. The active ingredient is a mixture of alkali aluminate and alkyl silanols that exhibits an intense hydrophobing effect at low concentrations. The agent can be employed in aqueous solution, e.g. in an enclosed space without the special exhaust devices required with volatile solvents. The solution is storage-stable. It contains preferably between 0.1 and 2.0% by weight of alkyl silanol and between 0.03 and 0.1% by weight of alkali aluminate.

Impregnating compositions for cellulose containing materials

A composition comprising a polyester, a brominated flameproofing agent for said polyester and 0.5-20 weight percent, preferably 1-8 weight percent, of an epoxy resin; a process for improving the decomposition behavior of a polyester composition containing a brominated flameproofing agent which comprises adding to said composition an epoxy resin an amount of 0.5 to 20 weight percent.

Flameproofed polyesters of improved viscosity

A polymer having as a component thereof a moiety corresponding to a monomer having the following formula ##STR1## wherein n=0 or 1, X is bromine, chlorine or a mixture thereof and R represents hydrogen or methyl, a method of preparing the same and the use of such a polymer, including a copolymer thereof in a plastic composition containing a normally flammable plastic.

Acrylate-based polymers and copolymers and their use as flameproofing

An improvement in a process for preparing an antimony oxide stabilized polymethylene terephthalate polymeric composition wherein polymethylene terepthalate is produced by polycondensing a polymethylene terephthalate precondensate, the improvement residing in compounding said precondensate with said antimony oxide and thereafter subjecting the resultant composition to solid phase polycondensation. In particular is described a process for the stabilization of high molecular weight (high viscosity) polymethylene terephthalate wherein together with the antimony oxide there is added a stabilizer or other additive to the precondensate and the resultant composition is subjected to solid phase polycondensation. Also described are the resultant products of such processes.

Preparation of high-viscosity mixtures containing thermoplastic

A process for preparing a filler-fortified polyalkyleneterphthalate molding composition which comprises mixing a filler with a precondensate of poly-(1,4-butylene)-terephthalate and/or poly-(1,3-propylene)-terephthalate, forming the resultant mixture into a shape and thereafter polymerizing the precondensate by solid-phase condensation under solid-phase condensation conditions; a molding composition prepared by such a process comprising poly-(1,4-butylene)-terephthalate and/or poly-(1,3-propylene)-terephthalate in an amount of 20 to 98 weight percent and 2 to 80 weight percent of a fortifying filler, the amounts based upon the combined amount of polyester and fortifying filler; a shaped object prepared from molding such a molding composition and the process for molding such a molding composition into a molded shaped article.

Filler-fortified polyalkyleneterephthalate molding compositions

A polymer having as a component thereof a moiety corresponding to a monomer having the following formula ##STR1## WHEREIN N = 0 OR 1, X is bromine, chlorine or a mixture thereof and R represents hyrogen or methyl, a method of preparing the same and the use of such a polymer, including a copolymer thereof in a plastic composition containing a normally flammable plastic.

Acrylate-based polymers and their use as flameproofing agents

A polymeric formal having the general formula ##STR1## wherein p is 0 or 1, n is a positive integer from 2 to 200 and R represents optionally halogen-substituted straight-chained or branched-chained alkyl radicals having 3 to 8 carbon atoms, an aryl radical or an aralkyl radical which can be substituted on one or both sides with alkyl or hydroxyalkyl ether groups; improved methods for the preparation of such formals, tetrabromoxylylene-bis-(.beta.-hydroxyethylether) compounds employed in the preparation of such formals and the use of such polymeric and oligomeric formals as flame retardant agents in plastic compositions especially thermoplastic and polycondensation plastic compositions.

Polymeric and oligomeric formals

A flame stabilized molding composition comprising: 1. A polyester which is the condensation product of an aromatic dicarboxylic acid, acid halide or ester and an aliphatic diol having more than 2 atoms in the chain, and 2. 1,4-bis-(.beta.,.gamma.,.gamma.-trichloroallyl)-2,3,5,6-tetrachlorobenzene of the formula ##STR1## SAID 1,4-BIS-(.beta.,.gamma.,.gamma.-TRICHLOROALLYL)-2,3,5,6-TETRACHLOROBENZENE PRESENT IN SAID MOLDING COMPOSITION IN AN AMOUNT OF 5-30 WEIGHT PERCENT, PREFERABLY 10-25%, BASED UPON THE WEIGHT OF SAID POLYESTER.

Difficultly inflammable polyester molding compositions

Process for the preparation of tris-(halophenoxy) -1,3,5-triazine of formula I ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 is each a phenoxy substituent having a 0-2 alkyl groups, and 0-2 halo alkyl groups, and has 1-5 halogen atoms which comprises contacting cyanuric acid chloride with alkali phenolate of the formulae R.sub.1 Me, R.sub.2 Me and R.sub.3 Me, wherein Me is alkali metal, and wherein said formulae can be identical or different, in the presence of alkylene diol monoalkyl ether, e.g. methyl or ethyl cellosolve. The ethers are good solvents for the phenolates. The products are used as flame-proofing agents for plastics.

Preparation of tris-(halophenoxy)-sym.-triazines

A process for preparing a bis-(bromomethyl)-tetrachlorobenzene which comprises contacting a bis-(chloromethyl)-tetrachlorobenzene with a bromide of an element of the first to the third group of the Periodic Table, preferably in a solvent of the bis-(chloromethyl)-tetrachlorobenzene which solvent is a non-solvent for the bis-(bromomethyl)-tetrachlorobenzene being prepared; a stabilized polymeric composition comprising a polymer and a bis-(bromomethyl)-tetrachlorobenzene, preferably containing additionally a compound of antimony or boron.

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St. Augustin, Germany

Werner Schmidt