Bergwerksverband Gmbh

Metallgesellschaft Aktiengesellschaft

Rheinstahl Huttenwerke Ag

Werner Peters

Harald Juntgen

Karl K Knoblauch

Heinrich Heimbach

Werner Korbacher

Dieter Zundorf

Heinrich Munzner

Karl H Van Heek

Roland Rammler

Josef Langhoff

Paul Schmalfeld

Hans-Dieter Schilling

Erwin Ahland

Joachim Lehmann

Heinrich Wagener

Reinhold Kirchhoff

Burkhard Bock

Klaus D Haverkamp

Siegfried Henkel

Hugo Horbel

Klaus Janssen

Fuels, particularly caking fuels, are supplied in a fluidized bed reactor by conveying a fuel through an injection pipe with an end provided with an injection nozzle in a fluidized bed reactor, conveying a fluid through a jacket pipe surrounding the injection pipe and having an end provided with a jacket nozzle, wherein the jacket pipe is interrupted prior to the jacket nozzle, as considered in the flow direction, and at a predetermined location, and bypassing by a heat exchanger at this location at which the jacket pipe is interrupted.

Arrangement for and method of dosing fuel in fluidized bed reactor

Product gas is produced by partial gasification of coke or coal. The coke or coal is admitted in particulate form into a gasification zone where it undergoes partial gasification. The residue of coke or coal is then forwarded into a combustion zone where it is combusted to liberate heat. A gaseous heat carrier is first passed through the combustion zone to become heated therein, is then passed through the gasification zone to sustain the partial gasification process, and is then recirculated into the combustion zone to be reheated.

Production of H.sub.2 and CO-containing gases

Fine grained coal is fed into a first chamber of a generally horizontally extending fluidizing bed reactor while a stream of hot solid heat exchange material is passed through the chamber. The coal is then subjected to a fluidizing action with a low nitrogen and low oxygen content so as to degas the coal particles and obtain the combustible gases and liquid byproducts. The coke particles thus formed are then passed into an adjoining second chamber which acts as the combustion chamber and are subjected therein to fluidization with air and burning. Steam is generated in water-filled conduits passing through said second chamber. The heat exchanger particles are simultaneously heated up and are continuously fed back into the first zone of the reactor to contact fresh coal introduced thereinto.

Process for generating combustible gases, liquid coal byproducts and

A method of manufacturing a briquetted coke from fine coal comprises carbonizing the coal at a temperature of from around 600.degree. to 900.degree. C., mixing the carbonized coal with approximately 10 to 80% and preferably from 20 to 40% of fine coal well caking coal, and thereafter hot briquetting the mixture at temperatures of from around 300.degree. to 500.degree. C. A fuel for shaft furnaces preferably includes the use of the hot briquettes as the only solid fuel in the shaft furnace, and it is particularly applicable for blast furnaces.

Method of manufacturing green hot briquettes from fine coal for use in

An initial gaseous mixture of at least two components is passed through an adsorber which preferentially adsorbs one of the components. This initially loads the adsorber. Subsequently, another gaseous mixture, having a greater proportion of the preferentially adsorbed component than the initial gaseous mixture, is passed through the adsorber so as to additionally load the adsorber. Part of the gas in the adsorber is then removed. This initially unloads the adsorber and yields a first fraction containing both components, with the proportion of the preferentially adsorbed component being greater than that in the initial gaseous mixture. The remainder of the gas in the adsorber is removed next so as to completely unload the adsorber. This results in a second fraction including both components and wherein the proportion of the preferentially adsorbed component is greater than that in both the second gaseous mixture to be passed through the adsorber and the first fraction removed from the adsorber. The first fraction may be used for additionally loading the adsorber during a subsequent cycle. An advantageous arrangement for carrying out the process is also disclosed.

Process and arrangement for the enrichment of gases

An initial gaseous mixture of at least two components is passed through an adsorber which preferentially adsorbs one of the components. This initially loads the adsorber. Subsequently, another gaseous mixture, having a greater concentration of the preferentially adsorbed component than the initial gaseous mixture, is passed through the adsorber so as to additionally load the adsorber. Part of the gas in the adsorber is then removed. This initially unloads the adsorber and yields a first fraction containing both components with the concentration of the preferentially adsorbed component being greater than that in the initial gaseous mixture. Subsequently, part of the gas still remaining in the adsorber is removed so as to further unload the adsorber. This results in a second fraction including both components and wherein the concentration of the preferentially adsorbed component is greater than that in both the second gaseous mixture to be passed through the adsorber and the first fraction removed from the adsorber. Finally, the remainder of the gas in the adsorber is removed so as to completely unload the adsorber. This yields a third fraction including both components with the concentration of the preferentially adsorbed component being lower than that in the second fraction removed from the adsorber but greater than that in the initial gaseous mixture passed into the adsorber. The first and third fractions may be used for additionally loading the adsorber in a subsequent cycle. A preferred application is the enrichment of oxygen-containing gases, particularly air, which include a component of greater molecular size than oxygen. A preferred adsorber is molecular sieve coke which preferentially adsorbs the oxygen. The process permits air to be enriched to such an extent that the product fraction, namely, the second fraction, removed from the adsorber contains between 70 and 95 volume percent of oxygen.

Process for the enrichment of gases

Process for preparing carbon containing molecular sieves adapted for separating small molecular gases in particular oxygen from nitrogen which comprises treating coke having a content of volatile components of up to 5% at 600.degree.-900.degree.C with a hydrocarbon splitting off carbon whereby the split-off carbon is deposited in the carbon framework of the coke under narrowing of the existing pores.

Carbon containing molecular sieves

Porous coke is impregnated with an organic compound which remains in the pores thereby causing a reduction in the effective size of the same. This results in molecular sieve coke capable of separating different gases, particularly oxygen and nitrogen, and capable of adsorbing smaller gas molecules more rapidly than larger gas molecules. The organic compound has a boiling point of at least 200.degree.C as measured at atmospheric pressure and of no more than 450.degree.C as measured in vacuum.

Impregnation of coke with an organic compound to produce a molecular

Fine-grained coke is produced by the degasification of fine-grained coal by a process which includes the following steps:

Process for producing fine-grained coke by degasification of coal

Process for preparing carbon-containing molecular sieves adapted for separating small molecular gases, in particular oxygen, from nitrogen, which comprises treating coke having a content of volatile components of up to 5% at 600.degree. - 900.degree. C with a hydrocarbon which splits off carbon whereby the split-off carbon is deposited in the carbon framework of the coke thereby narrowing the existing pores.

Carbon-containing molecular sieves

Process for preparing carbon-containing molecular sieves adapted for separating small molecular gases, in particular oxygen, from nitrogen, which comprises treating coke having a content of volatile components of up to 5% at 600.degree. - 900.degree.C with a hydrocabon which splits off carbon whereby the split-off carbon is deposited in the carbon framework of the coke thereby narrowing the existing pores.

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Wattenscheid, Germany

Werner Peters