Hille & Mueller Gmbh

Hille & Müller Gmbh

Werner Olberding

Ferdinand Schmidt

Karlfried Pfeifenbring

Beate Monscheuer

Nikolaus Ferenczy

Hans-Güenter Steinmann

Claudia Dahmen

Marcel Sebastian Rubart

Dagmar Petrick

Anette Schenck

Helmut Kossler

Annette Borisch

A method for heat treatment of a cold rolled strip with a surface coating of Ni and/or Co and incorporated non-metallic elements C and/or S, if need be with the addition of Fe, In, Pd, Au and/or Bi, whereby the cold rolled strip has a low carbon content. Since the compounds of C, S, N and P deposited on the grain boundaries bring about the most micro-cracks with the surface coating metal if no recrystallization takes place, the temperature of the heat treatment should be selected lower than the recrystallization temperature and higher than the precipitation temperature. With a recrystallization, the grain sizes would easily attain the thickness of the coating so that the embrittled compounds would migrate with the grain boundaries out of the coating. Due to the choice of temperature of the heat treatment of the surface coating of the invention, in contrast, an optimal embrittlement of the grain boundaries is guaranteed, which is especially advantageous in the manufacture of battery cans. Furthermore the sheet metal which can be manufactured in accordance with the invention and the corresponding battery can are described.

Heat treatment method for a cold-rolled strip with an Ni and/or Co surface coating, sheet metal producible by said method and battery can producible by said method

The invention relates to a method for producing improved cold-rolled band that is capable of being deep-drawn or ironed and that has a carbon content of less than 0.5 weight %. The invention also relates to a cold-rolled band that can be produced by such a method, and preferably used for producing cylindrical containers and, in particular, battery containers by deep-drawing or ironing. The band that is cold-rolled with a cold-rolling ratio ranging from 30 to 95% is subjected to a thermal treatment in an annealing furnace and to a&#x2014;preferably galvanic&#x2014;coating of at least one of the two band surfaces. In order to obtain an isotropic steel band that has a low level of texturing and that has a low tendency to form earing, the coating produced with one or multiple layers contains the elements of nickel/cobalt/iron/bismuth/indium/palladium/gold/tin, or alloys thereof, where the thermal treatment is effected by annealing, which is carried out&#x2014;before or after the coating process&#x2014;in a continuously running band-annealing furnace at a temperature greater than the limit temperature of the austenite range (&#x3b3; range).

Method for producing improved cold-rolled strip that is capable of being deep-drawn or ironed, and cold-rolled strip, preferably used for producing cylindrical containers and, in particular, battery containers

The invention relates to a method for producing an electrolytically coated cold rolled strip, preferably for use in the production of battery sheaths. The cold rolled strip is provided with a cobalt or a cobalt alloy layer by an electrolytic method. The aim of the invention is to provide a battery sheath with low values for the electric contact resistance between the cathode substance of the battery and the inner surface of the battery sheath. To this end, organic substances m added to the electrolyte during coating that produce decomposition products, said decomposition produces and/or reaction products of said decomposition products with other components of the electrolytic bath being deposited on the strip material as a brittle layer along with the cobalt or the cobalt alloy.

Method for producing electrolytically coated cold rolled strip, preferably for use in the production of battery sheaths, and battery sheath produced according to this method

A battery sheath made of formed and cold-rolled sheet metal as well as a process for manufacturing the battery sheath are proposed. In the process, cold-rolled strip stock is provided on at least one side with a coating of Ni, Co, Fe, Sn, In, Pd, Bi or their alloys in an electroplating bath, e.g., a Watts-type bath. As an additional component, the electroplating bath contains electrically conductive particles such as carbon, carbon black, graphite, TiS, TaS, MoSi. These particles are deposited on the base material during electroplating together with Ni, Co, Fe, Sn, In, Pd, Bi or their alloys. The sheet metal side with, for example, the carbon-containing electroplated coating faces preferably inwardly when the sheet is formed into a battery sheath. Batteries with battery sheaths produced in this manner exhibit reduced increase in internal resistance, even with prolonged storage, as compared to known batteries.

Battery sheath made of a formed cold-rolled sheet and method for producing battery sheaths

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Velbert, Germany

Werner Olberding