Ernst Leitz Wetzlar Gmbh

Wild Leitz Gmbh

Werner Huber

Norbert Meinert

Heinz Broemer

Henning Franek

Rainer Dreuth

Optical fluorophosphate glass which is based on Mg(PO.sub.3).sub.2, Ca(PO.sub.3).sub.2, Ba(PO.sub.3).sub.2, Al(PO.sub.3).sub.3, MgF.sub.2, CaF.sub.2, SrF.sub.2, AlF.sub.3, BaO and SrO and has a refractive index n.sub.e between 1.515 and 1.546, an Abbe value .nu..sub.e between 75.8 and 77.4 and a positive anomalous partial dispersion value .DELTA..nu..sub.e between 14.85 and 15.15. The glass comprises (in weight-%) 2.4-2.7 Mg; 4.5-4.9 Ca; 15.9-17.6 Sr; 20.2-22.3 Ba; 5.6-6.2 Al; 8.8-9.7 P; 22.0-24.3 F and 15.7-17.4 O. The improved physico-chemical parameters, such as linear expansion coefficient, glass transition temperature T.sub.g, density .zeta., Knoop-hardness HK, etc., are stated. Finally, a production process for this optical glass is described.

Process for producing an optical fluorophosphate glass having anomalous

Optical fluorophosphate glasses based on Ba(PO.sub.3).sub.2, Al(PO.sub.3).sub.3, alkaline earth metal fluorides and AlF.sub.3 are described which have a refractive index n.sub.e between 1.47 and 1.50, an Abbe-value .nu..sub.e between 85 and 80 and a positive anomalous partial dispersion value .DELTA..nu..sub.e between +17 and +22. They comprise (in wt.-%) 0.5-3 Mg, 8-10 Ca, 12-20 Sr, 9-12 Ba, 7-9 Al, 5-9 P, 8-12 O and 35-38 F. Ti, Na, K and H may additionally be present. The improved physico-chemical parameters (expansion coefficient, glass transition temperature, density, Knoop-hardness) and the transmission characteristics are given, and a process for producing these optical glasses is described.

Process for preparation of fluorophosphate optical glass

Optical fluorophosphate glass having anomalous positive partial

Optical fluorophosphate glasses based on Ba(PO.sub.3).sub.2, Al(PO.sub.3).sub.3, alkaline earth metal fluorides and AlF.sub.3 are described which have a refactive index n.sub.e between 1.47 and 1.50, an Abbe-value .nu..sub.e between 85 and 80 and a positive anomalous partial dispersion value .DELTA..nu..sub.e between +17 and +22. They comprise (in wt.-%) 0.5-3 Mg, 8-10 Ca, 12-20 Sr, 9-12 Ba, 7-9 Al, 5-9 P, 8-12 O and 35-38 F. Ti, Na, K and H may additionally be present. The improved physico-chemical parameters (expansion coefficient, glass transition temperature, density, Knoop-hardness) and the transmission characteristics are given, and a process for producing these optical glasses is described.

Optical fluorophosphate glasses possessing positive anomalous partial

Disclosed are zirconium-containing borosilicate glass compositions having a refractive index n.sub.e between 1.55 and 1.72, and Abbe number .nu..sub.e between 50 and 34 and a negative anomalous partial dispersion value .DELTA..nu..sub.e between -3.0 and -7.7. Also disclosed is a process for the production of such glass compositions.

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Solms-Albshausen, Germany

Werner Huber