Peroxid-Chemie Gmbh

Solvay Interox Gmbh

Solvay Chemicals Gmbh

Kali-Chemie Aktiengesellschaft

Werner Doetsch

Rudolf Siegel

Manfred Mathes

Richard Roesler

Helmut Honig

Gerd Hecken

Gabriele Wasem

Werner Zeiss

Helmut Dillenburg

Otto Caspar

Paul-Wilhelm Fuchs

Klaus-Guenter Gerling

Otmar Woost

Ernst Buchholz

Hans-Ludwig Pfeifer

Alfred Soentgerath

A highly stabilized hydrogen peroxide useful for chemical sterilization of packaging materials in high-speed aseptic packaging plants.

Stabilized hydrogen peroxide

Dust-free alkaline earth peroxides are obtained by mixing alkaline earth peroxides with a compacting aid and dry-compacted in a compactor, for example, a roller press. Examples of suitably useful compacting aids include sodium bicarbonate, cellulose, magnesium montanate and cross-linked silicone compounds.

Method for producing dust-free alkaline earth peroxides

Homogeneous, boron-doped alkaline earth peroxides and mixed alkaline earth peroxides, methods for the production thereof, and use thereof as oxygenating agents for agricultural purposes.

Homogeneous, boron-doped alkaline earth peroxides

Coated metal peroxides, their preparation and use, in which metal peroxides are coated with silicone compounds from selected from the group siliconates, hydrogen-polysiloxanes, siloxanes, silicone resin emulsions, silane/siloxane emulsions, silane/siloxane mixtures, silicone microemulsion concentrates, and silicic acid ester mixtures.

Coated metal peroxides

A homogeneous calcium/magnesium peroxide, its manufacture and use are described. The new calcium/magnesium peroxide is suitable in particular as an additive used as source of oxygen and acid buffer, e.g. in the application, processing, treatment and/or disposal of various biomaterials.

Alkaline earth metal peroxide product

A method for the &ldquo;dry&rdquo; production of sodium percarbonate (dry process), in which monohydrate crystals of sodium carbonate are reacted with a quasi-stoichiometric quantity of concentrated aqueous hydrogen peroxide solution, relative to the quantity of active oxygen required in the sodium percarbonate to be produced. This method can be combined to great advantage with subsequent compaction of the sodium percarbonate obtained. Sodium percarbonate products containing varying concentrations of active oxygen of at least 10 weight percent, particularly high active oxygen concentrations of above 14.5 weight percent, can be produced. The resulting sodium percarbonate products are distinguished in that they have remarkably advantageous dissolution rates, stabilities and compatibility with detergent bases, and are superior to conventional sodium percarbonates obtained, for example, by a crystallization process. The invention also relates to the sodium percarbonate products obtained and to detergent compositions containing such sodium percarbonate products.

Method for producing sodium percarbonate

A flexible process for production of homogeneous sodium precarbonate particles or granules according to which a reaction slurry with an average to high solids content is prepared initially from an aqueous hydrogen peroxide solution of up to maximum 50% by weight and solid soda, this reaction slurry, which optionally may be finely ground by wet comminution, being subsequently subjected immediately to short-term drying, preferably spray drying, and, optionally, granulation. The process enables production, in an efficient manner, of essentially homogeneous sodium percarbonate particles or granules with variable active oxygen contents of 10 to 14.5% by weight and grain sizes and bulk densities which are variable within wide ranges.

Process for the production of sodium percarbonate

Coated alkali metal peroxy salts and process for their preparation

Particulate alkali metal peroxy salts are stabilized by coating with a crystallized mineral salt mixture of alkali metal sulfate and alkali metal chloride which optionally may additionally contain alkali metal silicate. Particularly suitable alkali metal peroxy salts include peroxypyrophosphate, peroxytripolyphosphate, peroxymonosulfate and peroxycarbonate. The coated peroxy salts are incorporated in bleaching and detergent compositions.

Detergent composition containing alkali metal peroxysalt stabilized with

A process is described for preparing peroxyborate agglomerates having an active oxygen content of at least 14% by weight in which amorphous primary particles composed of peroxyborate prepared by a spray drying process are subjected to compacting pressing-agglomeration. Briquettes, compressed strips and tablets can be obtained which can be comminuted, if desired, to peroxyborate granules of desired particle size and bulk density. Advantageous, optionally colored, peroxyborate agglomerates, particularly peroxyborate granules are prepared. Preferred agglomerates and granules are composed of sodium peroxyborates.

Process for preparing peroxyborate agglomerates

Sodium percarbonate particles stabilized by being coated with a solid coating material which contains a mixture of sodium carbonate and sodium chloride, optionally together with one or more auxiliary agents used in the manufacture of sodium percarbonate.

Sodium percarbonate stabilized by coating

A process for preparing microcrystalline perborate hydrate products and highly concentrated, storage stable aqueous solutions used for this purpose which have a stable active oxygen content and a boron content of 3 to 8% by wt. based on the total weight of the solution. The products of the invention are suitable for numerous uses in the field of bleaching agent, disinfectant and liquid detergent formulations, and other fields of use.

Process for preparing microcrystalline perborate products

A process for producing an alkali metal carbonate peroxyhydrate having improved storage stability by mixing particles of an alkali metal carbonate peroxyhydrate with an effective storage stability improving amount of a powdered fatty acid metal salt.

Process for improving the storage stability of percarbonate and

A process for producing sodium perborate monohydrate agglomerates or granules in which primary particles of sodium perborate monohydrate produced from sodium perborate tetrahydrate by a dehydration process are subjected to compacting pressing agglomeration, and the resulting agglomerates are subsequently comminuted to granules.

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Linz a. Rhein, Germany

Werner Doetsch