Chartered Semiconductor Manufacturing Ltd (corporation)

Globalfoundries Singapore Pte. Ltd.

International Business Machines Corporation

Wenhe Lin

Simon Yew-Meng Chooi

Kin Leong Pey

Young Way Teh

Mei-Sheng Zhou

Khee Yong Lim

Yong Meng Lee

Chung Woh Lai

Jia Zhen Zheng

John Leonard Sudijono

Liang Choo Hsia

Hui Peng Koh

Wee Leng Tan

Chew Hoe Ang

Eng Hua Lim

Juan Boon Tan

Mei Sheng Zhou

Victor Chan

Fan Zhang

Bei Chao Zhang

Yong Kong Siew

Chew-Hoe Ang

Haifeng Sheng

Vincent Ho

Zhong Dong

Jamin F Fen

Kern Rim

Brian Joseph Greene

Siddhartha Panda

Alan Lek

Jeffrey Chee Wei-Lun

A first example embodiment provides a method of removing first spacers from gates and incorporating a low-k material into the ILD layer to increase device performance. A second example embodiment comprises replacing the first spacers after silicidation with low-k spacers. This serves to reduce the parasitic capacitances. Also, by implementing the low-k spacers only after silicidation, the embodiments' low-k spacers are not compromised by multiple high dose ion implantations and resist strip steps. The example embodiments can improve device performance, such as the performance of a rim oscillator.

Spacer-less low-K dielectric processes

The present invention provides a method of inducing stress in a semiconductor device substrate by applying an ion implantation to a gate region before a source/drain annealing process. The source/drain region may then be annealed along with the gate which will cause the gate to expand in certain areas due to said ion implantation. As a result, stress caused by said expansion of the gate is transferred to the channel region in the semiconductor substrate.

Poly profile engineering to modulate spacer induced stress for device enhancement

A method for forming a device with both PFET and NFET transistors using a PFET compressive etch stop liner and a NFET tensile etch stop liner and two anneals in a deuterium containing atmosphere. The method comprises: providing a NFET transistor in a NFET region and a PFET transistor in a PFET region. We form a NFET tensile contact etch-stop liner over the NFET region. Then we perform a first deuterium anneal. We form a PFET compressive etch stop liner over the PFET region. We form a (ILD) dielectric layer with contact openings over the substrate. We perform a second deuterium anneal. The temperature of the second deuterium anneal is less than the temperature of the first deuterium anneal.

Double anneal with improved reliability for dual contact etch stop liner scheme

An example process to remove spacers from the gate of a NMOS transistor. A stress creating layer is formed over the NMOS and PMOS transistors and the substrate. In an embodiment, the spacers on gate are removed so that stress layer is closer to the channel of the device. The stress creating layer is preferably a tensile nitride layer. The stress creating layer is preferably a contact etch stop liner layer. In an embodiment, the gates, source and drain region have a silicide layer thereover before the stress creating layer is formed. The embodiment improves the performance of the NMOS transistors.

Method to remove spacer after salicidation to enhance contact etch stop liner stress on MOS

A method (and apparatus) of post silicide spacer removal includes preventing damage to the silicide spacer through the use of at least one of an oxide layer and a nitride layer.

Method and apparatus for post silicide spacer removal

Spacer-less low-k dielectric processes

An example process to remove spacers from the gate of a NMOS transistor. A stress creating layer is formed over the NMOS and PMOS transistors and the substrate. In an embodiment, the spacers on gate are removed so that stress layer is closer to the channel of the device. The stress creating layer is preferably a tensile nitride layer. The stress creating layer is preferably a contact etch stop liner layer. In an embodiment, the gates, source and drain region have an silicide layer thereover before the stress creating layer is formed. The embodiment improves the performance of the NMOS transistors.

An example method embodiment forms spacers that create tensile stress on the substrate on both the PFET and NFET regions. We form PFET and NFET gates and form tensile spacers on the PFET and NFET gates. We implant first ions into the tensile PFET spacers to form neutralized stress PFET spacers. The neutralized stress PFET spacers relieve the tensile stress created by the tensile stress spacers on the substrate. This improves device performance.

Composite stress spacer

A method of forming a silicon nitride-silicon dioxide, composite gate dielectric layer, offering reduced risk of boron penetration from an overlying boron doped polysilicon gate structure, has been developed. A porous, silicon rich silicon nitride layer is first deposited on a semiconductor substrate, allowing a subsequent thermal oxidation procedure to grow a thin silicon dioxide layer on the semiconductor substrate, underlying the porous, silicon rich silicon nitride layer. A two step anneal procedure is then employed with a first step performed in a nitrogen containing ambient to densify the porous, silicon rich silicon nitride layer, while a second step of the anneal procedure, performed in an inert ambient at a high temperature, reduces the foxed charge at the silicon dioxide-semiconductor interface.

Method of fabricating a gate dielectric layer with reduced gate tunnelling current and reduced boron penetration

Methods for forming dual-metal gate CMOS transistors are described. An NMOS and a PMOS active area of a semiconductor substrate are separated by isolation regions. A metal layer is deposited over a gate dielectric layer in each active area. Silicon ions are implanted into the metal layer in one active area to form an implanted metal layer which is silicided to form a metal silicide layer. Thereafter, the metal layer and the metal silicide layer are patterned to form a metal gate in one active area and a metal silicide gate in the other active area wherein the active area having the gate with the higher work function is the PMOS active area. Alternatively, both gates may be metal silicide gates wherein the silicon concentrations of the two gates differ. Alternatively, a dummy gate may be formed in each of the active areas and covered with a dielectric layer. The dielectric layer is planarized thereby exposing the dummy gates. The dummy gates are removed leaving gate openings to the semiconductor substrate. A metal layer is deposited over a gate dielectric layer within the gate openings to form metal gates. One or both of the gates are silicon implanted and silicided. The PMOS gate has the higher work function.

Dual metal gate process: metals and their silicides

Methods for forming dual-metal gate CMOS transistors are described. An NMOS and a PMOS active area of a semiconductor substrate are separated by isolation regions. A metal layer is deposited over a gate dielectric layer in each active area. Oxygen ions are implanted into the metal layer in one active area to form an implanted metal layer which is oxidized to form a metal oxide layer. Thereafter, the metal layer and the metal oxide layer are patterned to form a metal gate in one active area and a metal oxide gate in the other active area wherein the active area having the gate with the higher work function is the PMOS active area. Alternatively, both gates may be metal oxide gates wherein the oxide concentrations of the two gates differ. Alternatively, a dummy gate may be formed in each of the active areas and covered with a dielectric layer. The dielectric layer is planarized thereby exposing the dummy gates. The dummy gates are removed leaving gate openings to the semiconductor substrate. A metal layer is deposited over a gate dielectric layer within the gate openings to form metal gates. One or both of the gates are oxygen implanted and oxidized. The PMOS gate has the higher work function.

Methods to form dual metal gates by incorporating metals and their conductive oxides

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Wenhe Lin