3M Innovative Properties Company

Wendi J Winkler

Audrey A Sherman

Mieczyslaw H Mazurek

Kevin R Schaffer

Albert I Everaerts

Charles M Leir

Richard G Hansen

Karl E Benson

David J Kinning

Mark D Purgett

Scott Melvyn Tapio

John E Potts

James P DiZio

Haiyan Zhang

Robert K Galkiewicz

Larry A Meixner

Jeffrey J Schwab

James R Starkey

Erica J Draheim

Patrick S Seleski

Jeffrey M Olofson

Michael Alan Meis

Wayne K Dunshee

Raymond Patrick Johnston

Robert L Brott

Marc Dudley Radcliffe

Zhiming Zhou

William J Bryan

Craig E Hamer

Marie A Boulos

Yufeng Liu

Robert J Reuter

Gregory D Kostuch

Stephen A Johnson

Jayshree Seth

Jiaying Ma

Thu-Van T Tran

Donald H Lucast

Ellen O Aeling

James Patrick DiZio

Soemantri Widagdo

Thomas E Augustine

Maureen C Nelson

Patrick J Yeshe

Marvin Jeffrey Case

Henri Garcia

Daniel Toro

A shape memory polymer article is disclosed. The article may include a surface having a microstructure and it may include a shape memory polymer. The shape memory polymer may include a copolymer network. The copolymer network may be formed from the reaction product of a free radically polymerizable siloxane having greater than one functional free radically polymerizable group and at least one (meth)acrylate monomer.

Shape memory polymer articles with a microstructured surface

Disclosed herein is an optical device having a light source and a viscoelastic lightguide. Light from the light source enters the viscoelastic lightguide and is transported within the lightguide by total internal reflection. The viscoelastic lightguide may comprise a pressure sensitive adhesive. The optical device may be used in a variety of constructions wherein the device emits light being transported within the viscoelastic lightguide. Constructions include those used for signs, markings, illumination devices, display devices, keypad assemblies and tail light assemblies for vehicles.

Light source and optical article including viscoelastic lightguide disposed on a substrate

Non-silicone urea-based adhesives are disclosed which are prepared by the polymerization of reactive oligomers with the general formula X&#x2014;B&#x2014;X, where X is an ethylenically unsaturated group and B is a unit free of silicone and containing urea groups. The reactive oligomers can be prepared from polyamines through chain extension reactions using diaryl carbonates followed by capping reactions. Adhesive articles, including optical adhesive articles may be prepared using the disclosed non-silicone urea-based adhesives.

Urea-based pressure sensitive adhesives

A method of making a microstructured adhesive article that includes (a) providing an article comprising a crosslinked pressure sensitive adhesive layer disposed on a backing; and (b) embossing the surface of the crosslinked pressure sensitive adhesive layer to form a crosslinked pressure sensitive adhesive layer having a microstructured adhesive surface.

Method for preparing microstructured laminating adhesive articles

Methods of making cut adhesive articles are described. The methods involve: providing a crosslinked pressure sensitive adhesive layer disposed on a substrate, embossing a surface of the crosslinked pressure sensitive adhesive layer to form a microstructured crosslinked pressure sensitive adhesive layer having a microstructured adhesive surface, and die cutting the microstructured crosslinked pressure sensitive adhesive layer.

Method of making adhesive article

Temporarily repositionable pressure sensitive adhesive compositions which are blends of a silicone-modified pressure sensitive adhesive component, a high Tg polymer component and a crosslinker are presented. The silicone-modified pressure sensitive adhesive includes a copolymer that is the reaction product of an acidic or basic monomer, a (meth)acrylic or vinyl monomer, and a silicone macromer. The high Tg polymer component contains acid or base functionality such that when mixed, the silicone-modified pressure sensitive adhesive component and the high Tg polymer component form an acid-base interaction.

Temporarily repositionable pressure sensitive adhesive blends

Disclosed herein is an optical device including a light source and an optical article. The optical article includes a lightguide and a viscoelastic layer disposed on the lightguide. Light emitted by the light source enters the lightguide and is transported within the lightguide by total internal reflection. The viscoelastic layer manages light, for example, at least about 50%, or less than about 10%, of light that enters the lightguide may be extracted. The optical device can be used in a variety of constructions for signs, markings, display devices, keypad assemblies, tail light assemblies and illumination devices.

Lightguide having a viscoelastic layer for managing light

Urea-based pressure-sensitive adhesives

Optically clear stretch releasing pressure sensitive adhesive films containing a silicone pressure sensitive adhesive composition and a tacky tab are provided. The pressure sensitive adhesive compositions are formed from elastomeric silicone polymer selected from the group consisting of urea-based silicone copolymers, oxamide-based silicone copolymers, amide-based silicone copolymers, urethane-based silicone copolymers, polydiorganosiloxane polymers, or mixtures of these copolymers. The pressure sensitive adhesive compositions may also contain an MQ tackifying resin. The pressure sensitive adhesive compositions may be used to form adhesive articles.

Stretch releasing optically clear pressure sensitive adhesive

Polydiorganosiloxane polyoxamide, linear, block copolymers and methods of making the copolymers are provided. The method of making the copolymers involves reacting a diamine with a polydiorganosiloxane precursor having oxalylamino groups. The polydioroganosiloxane polyoxamide block copolymers are of the (AB)type.

Adhesive compositions

A method of forming an image having multiple phases is disclosed herein. The method includes forming exposed and unexposed areas, the exposed areas comprising a first polymer network exhibiting first and second phases that are chemically connected and have different refractive indices, the first phase being continuous, and the second phase comprising a plurality of structures dispersed within the first phase, and the unexposed areas comprising a second polymer network comprising third and fourth phases that are chemically connected and have different refractive indices, the third phase being continuous, and the fourth phase comprising a plurality of structures dispersed within the third phase. The first and second polymer networks are chemically connected, and morphology formed by the first and second phases is different than that formed by the third and fourth phases.

Method of forming an image having multiple phases

A method of modifying light is disclosed and includes: providing an optical element having an oriented polymer network of a silicone(meth)acrylate copolymer and exhibiting a first phase and a second phase, the first phase and the second phase being chemically connected and having different refractive indices, the first phase being continuous, and the second phase comprising a plurality of structures dispersed within the first phase; illuminating the optical element with light from a light source; and detecting polarized or directionally diffused light transmitted by the optical element. Optical elements including the polymer network and a variety of additional layers are also disclosed, as are optical devices such as prisms, display panels, lenses, and the like.

Method of modifying light with silicone (meth) acrylate copolymers

Methods for changing the shape of a surface of an article are disclosed. The methods may include providing a liquid polymer precursor, casting the precursor against a first tool assembly, curing the precursor to form a shape memory polymer substrate, deforming one or more surfaces of the substrate, and mobilizing the shape memory polymer to shift the deformed surface of the substrate from a deformed shape to a pre-set shape.

Methods for changing the shape of a surface of a shape memory polymer article

Growing community of inventors

Minneapolis, MN, United States of America

Wendi J Winkler