Basf Se Corporation

Tokyo Institute of Technology

Basf Corporation

Weiping Zhang

Dirk De Vos

Feng-Shou Xiao

Hermann Gies

Xinhe Bao

Bilge Yilmaz

Ulrich Mueller

Ulrich Müller

Takashi Tatsumi

Toshiyuki Yokoi

Mathias Feyen

Xiangju Meng

Bernd Marler

Ute Kolb

Hiroyuki Imai

Andrei-Nicolae Parvulescu

Stefan Maurer

Robert McGuire

Bart Tijsebaert

Trees De Baerdemaeker

Xiulian Pan

Faruk Özkirim

Chuan Shi

Yong Wang

Yu Dai

Bin Xie

Meike Pfaff

Haiyan Zhang

Ryoichi Otomo

Chengguan Yang

Limin Ren

Yokoi Toshiyuki

A process for the production of an aromatic compound which comprise reacting a mixture comprising ethylene and a furan compound over a zeolitic material having a BEA-type framework structure is described, wherein the zeolitic material having a BEA-type framework structure comprised in the catalyst is obtainable and/or obtained according to an organotemplate-free synthetic process.

Process for the preparation of an aromatic compound from biomass

The present invention relates to a process for the preparation of a zeolitic material SiOand XOin its framework structure, wherein X stands for a trivalent element, wherein said process comprises interzeolitic conversion of a first zeolitic material comprising SiOand XOin its framework structure, wherein the first zeolitic material has an FER-, TON-, MTT-, BEA-, MEL-, MWW-, MFS-, and/or MFI-type framework structure to a second zeolitic material comprising SiOand XOin its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material. Furthermore, the present invention relates to a zeolitic material per se as obtainable and/or obtained according to the inventive process and to its use, in particular as a molecular sieve, as an adsorbent, for ion-exchange, or as a catalyst and/or as a catalyst support.

Process for the production of a zeolitic material via interzeolitic conversion

The present invention relates to a rare earth element containing zeolitic material having a framework structure selected from the group consisting of AEI, AFT, AFV, AFX, AVL, CHA, EMT, GME, KFI, LEV, LTN, and SFW, including mixtures of two or more thereof, the framework structure of the zeolitic material comprising SiOand XO, wherein X stands for a trivalent element, wherein the zeolitic material displays an SiO:XO molar ratio in the range of from 2 to 20, and wherein the zeolitic material contains one or more rare earth elements as counter-ions at the ion exchange sites of the framework structure. Furthermore, the present invention relates to a process for the production of the inventive rare earth element containing zeolitic material as well as to the use of the inventive rare earth element containing zeolitic material.

Rare earth element containing aluminum-rich zeolitic material

A zeolitic material having framework type CHA, comprising a transition metal M and an alkali metal A, and having a framework structure comprising a tetravalent element Y, a trivalent element X and O, wherein the transition metal M is a transition I metal of groups 7 to 12 of the periodic table, A is one or more of K and Cs, Y is one or more of Si, Ge, Ti, Sn and Zr, and X is one or more of Al, B, Ga and In. A process for preparing such a zeolitic material. Use of such a zeolitic material.

Zeolitic material having framework type CHA and comprising a transition metal and one or more of potassium and cesium

A process for preparing a zeolitic material containing YOand XO, where Y and X represent a tetravalent element and a trivalent element, respectively, is described. The process includes (1) a step of preparing a mixture containing one or more structure directing agents, seed crystals, and a first zeolitic material containing YOand XOand having FAU-, GIS-, MOR-, and/or LTA-type framework structures; and (2) a step of heating the mixture for obtaining a second zeolitic material containing YOand XOand having a different framework structure than the first zeolitic material. The mixture prepared in (1) and heated in (2) contains 1000 wt % or less of HO based on 100 wt % of YOin the framework structure of the first zeolitic material. A zeolitic material obtainable and/or obtained by the process and its use are also described.

Process for the production of a zeolitic material via solvent-free interzeolitic conversion

The present invention relates to a process for the production of a zeolitic material having a BEA-type framework structure comprising YOand XO, wherein said process comprises the steps of (1) preparing a mixture comprising one or more sources for YOand one or more sources for XO; (2) crystallizing the mixture obtained in step (1); (3) subjecting the zeolitic material having a BEA-type framework structure obtained in step (2) to an ion-exchange procedure with Cu; and (4) subjecting the Cu ion-exchanged zeolitic material obtained in step (3) to an ion-exchange procedure with Fe; wherein Y is a tetravalent element, and X is a trivalent element, wherein the mixture provided in step (1) and crystallized in step (2) further comprises seed crystals comprising one or more zeolitic materials having a BEA-type framework structure, and wherein the mixture provided in step (1) and crystallized in step (2) does not contain an organotemplate as a structure-directing agent, as well as to the zeolitic material having a BEA framework structure per se, and to its use, in particular in a method for the treatment of NOby selective catalytic reduction (SCR).

Bimetal-exchanged zeolite beta from organotemplate-free synthesis and use thereof in the selective catalytic reduction of NO

The present invention relates to a method for the preparation of a treated zeolitic material having a BEA framework structure including the steps of:

Process for the preparation of a dealuminated zeolitic material having the BEA framework structure

A process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X203, wherein said process comprises preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, and wherein the crystallized mixture contains 0.1 wt.-% or less, more preferably 0.01 wt.-% or less of one or more metals M based on 100 wt.-% of YO2, wherein even more preferably the crystallized mixture contains no metal M, wherein M stands for sodium and/or potassium, wherein preferably M stands for the group of alkali and alkaline earth metals.

Alkali-free synthesis of zeolitic materials of the LEV-type structure

The present invention relates to a process for the preparation of a zeolitic material having a CHA framework structure, said zeolitic material comprising zeolite crystals having a core-shell structure, wherein said process comprises the steps of

Process for the production of a core/shell zeolitic material having a CHA framework structure

The present invention relates to a process for the preparation of a silicate compound, comprising (1) providing at least one layered silicate; and (2) mixing said layered silicate with water and at least one silicon containing compound according to formula RSi[&#x2014;(SiR)&#x2014;R]wherein at least one residue R is a leaving group and none of the residues R contains Si; m is 0, 1, 2, 3, or 4; and n is an integer greater than or equal to 0.

Process for the preparation of pillared silicates

The present invention relates to a process for the alkylation of an organic compound comprising: (a) providing a catalyst comprising one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YOand optionally comprises XO, wherein Y is a tetravalent element, and X is a trivalent element, (b) contacting the catalyst with one or more alkylatable organic compounds in the presence of one or more alkylating agents in one or more reactors for obtaining one or more alkylated organic compounds, wherein the one or more zeolitic materials is obtainable from a synthetic process which does not employ an organotemplate as structure directing agent.

Process for the alkylation of organic compounds

The present invention relates to a process for the preparation of a zeolitic material having a BEA framework structure comprising the steps of: (i) providing one or more zeolitic materials having a BEA framework structure, wherein the BEA framework structure comprises YOand XO, wherein Y is a tetravalent element, and X is a trivalent element; (ii) subjecting the one or more zeolitic materials provided in step (i) to a procedure for removing at least a portion of X, preferably tetrahedrally coordinated X, from the BEA framework structure; wherein the Y:X molar ratios of the one or more zeolitic materials provided in step (i) are respectively comprised in the range of from 1 to 50.

Process for the production of an acylation catalyst

The present invention relates to a pillared silicate compound comprising a layered silicate structure, and bridging metal atoms located between adjacent silicate layers of the silicate structure, wherein said bridging metal atoms form at least one covalent bond to each of the adjacent silicate layers, as well as a process for the preparation of a pillared silicate compound, and further includes a pillared silicate compound obtainable and or obtained according to said process, as well as a method of catalyzing a chemical reaction comprising the step of contacting one or more chemical compounds with the any of the aforementioned pillared silicate compounds.

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Dalian, China

Weiping Zhang