Imperial Chemical Industries Limited

Warren T Smith

Richard A Hann

Barry Pack

Kazuhiko Sakata

A dyesheet is provided for thermal transfer printing, comprising a base sheet having a thermal transfer dye layer on one surface, and on the other a heat resistant backcoat comprising a crosslinked reaction product of radically polymerising a compound having a plurality of polymerisable unsaturated groups per molecule, wherein the backcoat is formulated to minimise scratching of the print during printing. The formulation comprises a) a compound having a single radically polymerisable unsaturated group which is copolymerised with the compound having a plurality of polymerisable unsaturated groups per molecule, and b) a multivalent metal salt of a long chain alkyl or alkylphenyl phosphate ester as slip agent. These two factors (a & b) work together, and if either is omitted, relief from scratching does not generally occur.

Thermal transfer dyesheet

A dyesheet is provided for thermal transfer printing, comprising a base sheet having a dyecoat containing a thermal transfer dye layer on one surface, and on the other a croselinked heat resistant backcoat formulated to minimize dye migration from the dyecoat to the backcoat during storage. The backcoat comprises the reaction product of radically copolymerising in a layer of coating composition, a) at least one organic compound having a plurality of radically polymerisable unsaturated groups per molecule, and b) at least one organic compound having per molecule a single unsaturated group radically copolymerisable with constituent a, and having at least one alicyclic group per molecule. Preferred additional constituents include slip agents, especially a multivalent metal salt of a long chain alkyl or alkylphenyl phosphate ester.

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Sydney, Australia

Warren T Smith