Lg Chem, Ltd

Wang Rae Joe

Ji Yeon Kim

Joo Young Cheon

Jun Seon Choi

Yong Yeon Hwang

Bong Keun Ahn

Jang Won Park

Min Soo Kim

Kyung Soo Kim

Ji Yoon Jeon

Hye Jeong Ok

Chun Ho Park

Yong Hee An

Jeong Min Jang

Tae Hoon Kim

Min Jung Kim

Ho Hoon Kim

Da Eun Sung

Eung Seob Yeom

Won Kyun Lee

Provided is a thermoplastic resin composition which includes: a first graft copolymer including a first acrylic rubber polymer; a second graft copolymer including a second acrylic rubber polymer; and a first styrene-based copolymer including an alkyl-substituted styrene-based monomer unit and an acrylonitrile-based monomer unit, wherein the first acrylic rubber polymer has an average particle diameter larger than that of the second acrylic rubber polymer, the first graft copolymer is included in a larger amount than the second graft copolymer, and the sum of the first graft copolymer and the second graft copolymer is 22 parts by weight or less with respect to 100 parts by weight of the sum of the first graft copolymer, the second graft copolymer, and the first styrene-based copolymer.

Thermoplastic resin composition

The present invention relates to a method of preparing a graft copolymer powder, which includes: preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer and a vinyl cyan-based monomer to a reactor and carrying out polymerization; preparing a core in the presence of the seed by adding an alkyl (meth)acrylate-based monomer and carrying out polymerization; and preparing a graft copolymer latex in the presence of the core by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and carrying out polymerization; adding an alkyl methacrylate-based polymer to the graft copolymer latex and carrying out coagulation, and more particularly, to a method of preparing a graft copolymer powder that is excellent in weather resistance, fluidity, mechanical properties, surface gloss and appearance quality.

Method of preparing graft copolymer powder

The present invention provides a graft copolymer comprising (A) a seed comprising units derived from an alkyl methacrylate monomer; (B) a core formed on the seed and comprising units derived from an alkyl acrylate monomer; and (C) a shell formed on the core and comprising units derived from one or more one or more selected from the group consisting of an aromatic vinyl-based monomer, a vinyl cyanide-based monomer and an alkyl methacrylate monomer, wherein an average particle diameter of the core is 40 to 90 nm, and a graft ratio of the shell is 10 to 30%, and a thermoplastic resin composition and a thermoplastic resin molded article including the same.

Graft copolymer, and thermoplastic resin composition and thermoplastic resin molded article comprising the same

A method for preparing a graft copolymer includes the steps of: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and carrying out polymerization; 2) preparing a core in the presence of the seed by adding an alkyl (meth)acrylate-based monomer and carrying out polymerization; and 3) preparing a shell in the presence of the core by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and carrying out polymerization, wherein an activator including a compound represented by Chemical Formula 1 is added in the step 3).  In Chemical Formula 1, Rand Rare each independently hydrogen, a C-Calkyl group, or *-(C=O)OM, provided that Rand Rare not both hydrogen, and Mand Mare each independently an alkali metal.

Method for preparing graft copolymer and graft copolymer

Provided are a method of preparing a graft copolymer, a graft copolymer, and a thermoplastic resin molded article including the graft copolymer, the method including: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and performing polymerization; 2) in the presence of the seed, preparing a core by adding an alkyl (meth)acrylate-based monomer and performing polymerization; and 3) in the presence of the core, preparing a shell by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and performing polymerization, wherein the method further includes adding an alkyl acrylate-based polymer. When the alkyl acrylate-based polymer is included in a graft copolymer, a graft copolymer and a thermoplastic resin molded article excellent in weather resistance, fluidity, mechanical properties, and appearance quality can be provided.

Method of preparing graft copolymer, graft copolymer, and thermoplastic resin molded article including graft copolymer

Provided is a thermoplastic resin composition including: a first copolymer including an acrylic rubber-based graft copolymer and an emulsifier including an acid salt; a second copolymer including a unit derived from an alkyl acrylate-based monomer and a unit derived from an alkyl methacrylate-based monomer; and a third copolymer including a unit derived from an aromatic vinyl-based monomer and a unit derived from a vinyl cyan-based monomer.

Thermoplastic resin composition of copolymers and method of preparing the same

The present invention provides a method of preparing a graft copolymer, which comprises: emulsion-polymerizing one or more selected from the group consisting of an aromatic vinyl-based monomer to prepare a seed, a vinylcyano-based monomer and an alkyl (meth)acrylate-based monomer; emulsion-polymerizing the seed and an alkyl (meth)acrylate-based monomer to prepare a core; and emulsion-polymerizing the core, an aromatic vinyl-based monomer and a vinylcyano-based monomer to prepare a shell, wherein one or more steps selected from the group consisting of the steps of preparing the seed, the core and the shell comprises adding an emulsifier comprising a compound represented by Formula 1 below.

Method of preparing graft copolymer

The present disclosure relates to a catalyst for dehydration of glycerin, a preparation method thereof, and a production method of acrolein using the catalyst. Particularly, the catalyst according to an embodiment of the present disclosure is used in a dehydration reaction of glycerin to exhibit high catalytic activity, a high yield, and high selectivity to acrolein and acrylic acid, and has a longer lifetime compared to the conventional catalysts due to a characteristic that coke carbon cannot be easily deposited on the surface of the catalyst.

Catalyst for dehydration of glycerin, preparation method thereof, and production method of acrolein using the catalyst

The present invention relates to a synthesis method of N-substituted maleimides using a non-homogeneous solid acid catalyst, and particularly, a synthesis method of N-substituted maleimides with high synthesis yield by using a zirconium(IV) hydrogen phosphate as a catalyst, by which, the loss of the catalyst is minimized, the separation and recovering processes of the catalyst are simplified, in case when the activity of the separated and recovered catalyst is decreased, the complete regeneration of the catalyst is possible via washing or firing, and solvents that could be used during a washing process of the catalyst are not limited.

Synthesis method of N-substituted maleimide using solid acid catalysts

A dehydration catalyst for preparing N-substituted maleimide, which may minimize formation of by-products, is reusable because its activity is not reduced significantly even after being reused several times, and may maintain its reaction activity for a long time, a preparation method thereof, and a method of preparing N-substituted maleimide, are provided.

Dehydration catalyst for preparing N-substituted maleimide, preparation method thereof, and method of preparing N-substituted maleimide

The present invention relates to a method for preparing acrylic acid from glycerin. More specifically, the present invention provides a method which can improve the selectivity of acrolein by applying a specific catalyst composition and process conditions to minimize the generation of coke carbon of the catalyst, and can prepare acrylic acid with higher productivity for a longer duration of time because a dehydration reaction can be performed for a longer working period while maintaining catalyst activity at a high level during the reaction.

Method for preparing acrylic acid from glycerin

The present invention relates to: a catalyst for glycerin dehydration; a preparation method therefor; and an acrolein preparation method using the catalyst. According to one embodiment of the present invention, the catalyst is used in glycerin dehydration so as to exhibit high catalytic activity, a high yield and high acrolein selectivity, and has a characteristic in which carbon is not readily deposited, thereby having a long lifetime compared with that of a conventional catalyst.

Catalyst for glycerin dehydration, preparation method therefor, and acrolein preparation method using catalyst

The present invention relates to a catalyst for glycerin dehydration, a preparation method thereof, and a preparation method of acrolein. The catalyst for glycerin dehydration exhibits a high glycerin conversion ratio, minimizes by-product formation to improve acrolein selectivity, and also maintains high catalytic activity during reaction.

Catalyst for glycerin dehydration, preparation method thereof, and preparation method of acrolein

The present invention relates to a catalyst for glycerin dehydration, a preparation method thereof, and a preparation method of acrolein, and more particularly, to a catalyst for glycerin dehydration which minimizes by-product formation during glycerin dehydration to improve acrolein selectivity and maintains high catalytic activity during reaction.

The present invention relates to a catalyst for glycerin dehydration, a preparation method thereof, and a preparation method of acrolein, and more particularly, to a catalyst for glycerin dehydration which minimizes by-product formation to improve acrolein selectivity and maintains high catalytic activity during reaction.

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Daejeon, South Korea

Wang Rae Joe