Allied Chemical Corporation

Walter R Buckman

Samuel L Bean

A concentrated calcium fluoride ore, having a decreased foam value which is particularly adapted for the manufacture of hydrogen fluoride is provided by a process which comprises: (a) grinding calcium fluoride ore containing calcite and quartzite particles to form calcium fluoride particles and to liberate at least a portion of said calcite and quartzite particles; (b) admixing the ground ore with aqueous medium and an effective amount of a suitable flotation agent to form a first aqueous slurry containing said flotation agent and calcium fluoride, calcite and quartzite particles; (c) contacting said first aqueous slurry with a gas under conditions sufficient to produce (i) a foam containing a major portion of said flotation agent and foamed particles comprising calcium fluoride particles together with a minor portion of the calcite and quartzite particles in said first slurry, and (ii) separated solids containing a major portion of the calcite and quartzite particles in said first slurry; (d) recovering at least a portion of said foam containing said foamed particles and said flotation agent portion as a second aqueous slurry; (e) removing from said second slurry a major portion of said foamed particles having a particle size of less than about 10 microns, thereby producing a thickened aqueous slurry containing calcium fluoride particles; and (f) recovering calcium fluoride particles from said thickened aqueous slurry as product.

Growing community of inventors

Syracuse, NY, United States of America

Walter R Buckman