Akzo N.v.

Akzo Nobel N.v.

Walter Loffelmann

Heinz-Dieter Sluma

Jurgen Passlack

Harald Schmitt

Joachim Behnke

Karl Henke

Michael Schmitt

Polysulfone membrane and method for its manufacture

An asymmetric semipermeable membrane for dialysis and/or ultrafiltration is composed of a copolymer of acrylonitrile and acrylic ester and an ionic or ionizable monomer in the form of a hollow fiber. The copolymer is composed of 90.50 to 95.00 wt. % acrylonitrile, 4.99 to 8.60 wt. % acrylic ester, and 0.01 to 0.90 wt. % of the ionic or ionizable monomer. Also provided is a process for its manufacture.

Polyacrylonitrile membrane

A method for production of polycarbonate-polyether-blockcopolymers is provided. One or more solutions comprising bisphenol A and polyalkyleneglycol and a phosgene solution are added to a cooled initial reaction medium in a cooled reaction chamber in such a way that the phosgene contacts substantially the reaction partners from the one or more cooled solutions after they have spread in the reaction medium. Preferably the phosgene solution and the one or more solutions are added through tubes ending above the liquid level of the reaction medium such that the solutions added contact only within the stirred reaction mixture the reaction partner. The phosgene is employed in an excess of less than about 10 weight percent of the stochiometrically required weight amount relative to bisphenol A and polyalkyleneglycol. The polymer is useful in the production of membranes for dialysis, ultrafiltration and reverse osmosis.

Process for preparing polycarbonate-polyether-blockcopolymers

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Erlenbach, Germany

Walter Loffelmann