E.i. Dupont De Nemours and Company

Vinodkumar Mehra

Pallatheri M Subramanian

Edmund Arthur Flexman

James Dean Katsaros

Robert B Fish, Jr

This invention relates to a process for making laminar articles by blending multicomponent pellets of a heterogeneous blend of a barrier resin, typically a condensation polymer, and a compatibilizer with a polyolefin. The pellets advantageously prevent segregation of the barrier resin and the compatibilizer during processing. This provides uniform, reproducible laminar articles with improved barrier properties and mechanical properties. The articles exhibit good fluid barrier and mechanical properties.

Process for making laminar articles

Laminar articles are disclosed comprising a heterogeneous melt of (a) a polyolefin, (b) a barrier resin comprising a blend of a condensation polymer incompatible with the polyolefin such as a polyamide and a phenol-formaldehyde resin, and (c) a compatibilizer. A process for making such laminar articles is also disclosed. Multilayer structures incorporating this barrier resin are also disclosed.

Articles incorporating barrier resins

Multilayer laminates formed from at least two layers. The first layer being a flexible blow moldable thermoplastic polyamide composition and the second layer being a vinyl alcohol composition. These laminates can withstand high temperatures for extended periods of time, possess low temperature impact strength, and have resistance to permeation of fuel compositions. These laminates are especially suited for fuel tanks for motor vehicles.

Multilayer laminates from blow moldable thermoplastic polyamide and

Polyethylene terephthalate scrap material containing on its surface a chlorine-containing polymer such as, for example, polyvinylidene chloride or polyvinyl chloride, can be recovered and reused by melt-blending it with a polymer from a defined class of ethylene copolymers containing an epoxy group, and melt processing the blend in the same manner as virgin polyethylene terephthalate. The recovered and reprocessed polymer material has good physical properties and barrier properties.

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Wilmington, DE, United States of America

Vinodkumar Mehra