Other

Viktor Alexandrovich Kabanov

Vladimir Ivanovich Smetanjuk

Marina Alexandrovna Martynova

Stanislav Konstantinovich Pluzhnov

Jury N Bocharov

Viktor V Fedorov

Valery G Popov

Andrei Alexandrovich Antonov

Nikolai S Nametkin

A method and composition for dimerization of olefins containing 2 to 4 carbon atoms, wherein at least one of said olefins is mixed, in a medium of hydrocarbon or halogenated hydrocarbon solvents at a temperature ranging from 0.degree. to 100.degree. C. under a pressure of from 1 to 40 atm with a two-component catalyst consisting of:

Catalyst for the dimerization of olefins

A catalyst for the (co)polymerization of ethylene, .alpha.-olefines, conjugated and non-conjugated dienes, a method of preparation, and a mode of using same. The catalyst contains from 0.1 to 50 wt.% of a compound of a transition metal of the IV-VIII Groups chemically combined and distributed over the surface and within the volume of a rubber-like polymeric carrier containing from 1 to 50 wt.% of electron-donor and/or electron-acceptor groups and is in the form of a gel which is swellable, but insoluble in the reaction medium. A co-catalyst comprising an organic compound of a metal of Groups I-III is employed chemically combined and/or non-combined with the catalyst. The catalyst is prepared by mixing the metal compound with said carrier swollen or dissolved in a solvent, and by extracting the resulting compound with a solvent. (Co)polymerization is effected in a solvent such as a hydrocarbon or a hologenated hydrocarbon derivative at a temperature not exceeding 200.degree. C. under a pressure ranging from 0 to 100 atm by separating the catalyst from the (co)polymer during or after the reaction and recycling it back to the (co)polymerization.

Polymeric gel catalyst for polymerization of .alpha.-olefines,

A catalyst for the (co)polymerization of ethylene, .alpha.-olefines, conjugated and non-conjugated dienes, a method of preparation and a mode of using same. The catalyst contains from 0.1 to 50 wt.% of a compound of a transition metal of the IV-VIII Groups chemically combined and distributed over the surface and within the volume of a rubber-like polymeric carrier containing from 1 to 50 wt.% of electron donor and/or electron-acceptor groups and is in the form of a gel which is swellable, but insoluble in the reaction medium. A co-catalyst comprising an organic compound of a metal of Groups I-III is employed chemically combined and/or non-combined with the catalyst. The catalyst is prepared by mixing the metal compound with said carrier swollen or dissolved in a solvent, and by extracting the resulting compound with a solvent. (Co)polymerization is effected in a solvent such as a hydrocarbon or a hologenatedhydrocarbon derivative at a temperature not exceeding 200.degree. C. under a pressure ranging from 0 to 100 atm by separating the catalyst from the (co)polymer during or after the reaction and recycling it back to the (co)polymerization.

Catalyst for (co) polymerization of ethylene, aplha-olefines, conjugated

A method for dimerization of olefins containing 2 to 4 carbon atoms, wherein at least one of said olefins is mixed, in a medium of hydrocarbon or halogenated hydrocarbon solvents at a temperature ranging from 0.degree. to 100.degree. C under a pressure of from 1 to 40 atm with a two-component catalyst consisting of:

Method for dimerization of olefins

A method for dimerization of olefins with a number of carbon atoms of at most 10 which comprises intermixing, in a medium of solvents selected from the group consisting of hydrocarbon solvents and halogenated hydrocarbon solvents at a temperature ranging from -20.degree. to +100.degree. C under a pressure of from 1 to 45 atm, of at least one of said olefines with a two-component catalyst consisting of an organoaluminum compound of the formula R.sub.n AlX.sub.3-n, wherein R is an alkyl with a number of carbon atoms of at most 8, X is a halogen, n = 1 or 2, and a graft-copolymer, swellable in said solvents, of a rubber selected from the group consisting of natural, synthetic carbo-chain and vinyl-containing siloxane rubbers, with vinylpyridine; said copolymer containing 0.5 to 40% by weight of polyvinylpyridine fragments complexed with a nickel salt; molar ratio between said organoaluminum compound and said nickel salt ranging from 1:1 to 100:1. In the method according to the present invention use is made of a catalyst with a maximal number of working active centers thus making it possible to substantially increase the process rate (for example, the rate of dimerization of propylene is about 9 kg of the product per gram of Ni per hour). The method can be performed under both batch and continuous operation conditions.

The method of dimerization of olefins having from 2 to 4 carbon atoms consists in that at least one said olefin is mixed, in a medium of hydrocarbon or halogenated hydrocarbon solvents at a temperature of from 0.degree. to 100.degree. C and a pressure from 1 to 40 atmospheres, with a catalyst, which is a graft copolymer of a natural or a synthetic carbon-chain rubber with vinylpyridine; said copolymer swells in said solvents and contains from 0.5 to 40 per cent of fragments of polyvinylpyridine that are complexed with a nickel salt, and contains also from 2 to 50 mole per cent of -AIRX- units, where R is an alkyl having not more than 8 carbon atoms, and X is a halogen, the aluminum atom being bound with the main chain of the copolymer through the carbon atom. The atom ratio of Al/Ni is from 1 to 20. Said catalyst is characterized by high stability and preserves it initial activity for a long period of time. It is not crushed in the process and is easy to recover. The catalyst is characterized also by high selectivity: the butene-1 content of a mixture of butenes, obtained by dimerization of ethylene, is 92 to 96 per cent. The methyl-pentene content of the dimerizate, obtained by dimerization of propylene, is 90 to 95 per cent.

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Moscow, Russia

Viktor Alexandrovich Kabanov