Dow Silicones Corporation

Dow Corning Corporation

Victor Baily

Frederic Gubbels

Gregory Chambard

Tatiana Dimitrova

Francois De Buyl

Davide Bianchi

Martijn A Beukema

Thierry Cooremans

Stephanie Lobry

Guy Beaucarne

Julien Renaud

Martin Beukema

There is provided silicone based materials with enhanced tackiness upon cure. These may be used for cured self-adhering silicone-based products such as pressure sensitive adhesives, self-adhering materials and/or self-sealing materials, made from condensation curable silicone-based compositions, the compositions therefor and to applications for which said self-adhesive products may be used. In one particular application the cured silicone based material may be utilised as a self-sealing layer in an inflatable article such as a pneumatic tire.

Silicone-based products and their applications

A lamination process is disclosed. The process is useful for silicone based lamination adhesive compositions, in particular those which cure at or around room temperature.

Lamination process

Two part silicone lamination adhesive compositions which cure via a condensation cure chemistry using titanium and/or zirconium based catalysts at room temperature are disclosed. The compositions comprise: (i) at least one condensation curable silyl terminated polymer having at least one hydrolysable and/or hydroxyl functional group(s) per molecule; (ii) a cross-linker; and (iii) a condensation catalyst selected from the group of titanates and zirconates. Polymer (i) is not stored in the same part as cross-linker (ii) and catalyst (iii). Catalyst (iii) is present in a molar amount which is at least 50% of the moisture present cumulatively in the parts of the composition. The molar ratio of silicon bonded hydroxyl groups in polymer (i) to hydrolysable groups in cross-linker (ii) is above 0.15. The molar ratio of the silicon bonded hydroxyl groups in polymer (i) to M-OR functions is greater than 10, where M is titanium or zirconium.

Lamination adhesive compositions and their applications

Improvements in or relating to transparent units (such as glazing units, which may also be referred to as insulating glass units) and their methods of manufacture are disclosed. Each transparent unit comprises first and second panes of transparent material each having an outwardly facing side and an inwardly facing side. Each inwardly facing side is at least partially coated with a reactive interlayer made by the application of a reactive interlayer coating composition. The inwardly facing side of the first and second panes of transparent material are spaced apart partially or totally by a transparent spacer made of a pre-cured condensation curable material or a substantially pre-cured condensation curable material adhered to the inwardly facing side of the first and second panes of transparent material by way of the reactive interlayers. In various embodiments, the pre-cured condensation curable material is a silicone based material.

Transparent unit

The present disclosure relates to self-sealing silicone sealant and/or gel compositions cured via a condensation cure chemistry and to their use subsequent to cure as puncture-resistant layers in any type of 'inflatable' article, i.e. articles which take their functional shape after inflation with a suitable gas such as air. The present disclosure also relates to silicone materials, e.g. elastomers and/or gels obtained subsequent to curing said compositions designed to function as self-sealing tire puncture material, i.e. to seal puncture holes in the tread region of tires if/when punctured by a foreign body.

Elastomeric compositions and their applications

A room temperature curable composition is disclosed. The composition can be used as an encapsulation/potting material. The composition comprises: (i) at least one condensation curable silyl terminated polymer having at least one silicon bonded hydroxyl functional group per molecule; (ii) a cross-linker having at least two hydrolysable groups and selected from certain silanes and/or silyl functional molecules; and (iii) a condensation catalyst selected from the group of titanates and/or zirconates. The molar ratio of the sum of moisture present in the composition and total silicon bonded hydroxyl groups:the catalyst ('the molar ratio') is &#x3e;7:1. When the molar ratio is from &#x3e;7:1 to 10:1, the molar ratio of total silicon bonded hydroxyl groups:total hydrolysable groups is between 0.1:1 to 0.3:1. When the molar ratio is &#x3e;10:1, the molar ratio of total silicon bonded hydroxyl groups:total hydrolysable groups is between 0.1:1 to 0.5:1.

A curable phenylorganosiloxane polymer composition comprising: (a) 100 parts by weight of a phenylorganosiloxane having a viscosity of at least 10000 mPa&#xb7;s at 25&#xb0; C. and at least two reactive groups per molecule selected from (i) &#x2014;OH or hydrolysable groups and (ii) unsaturated groups; (c) 0 to 500 parts by weight of fillers per 100 parts by weight of (a); (d) a suitable cure package comprising a cross-linker and a catalyst the suitable cure package being selected from a silane or polyorganosiloxane and a condensation catalyst when (a) is (a) (i) or a hydrosilylation catalyst when (a) is (a) (ii); and (b) 0.1 to 300 parts by weight of at least one phenyl siloxane resin per 100 parts by weight of (a). The compositions are especially useful in sealants (particularly in sealants for insulating glass units (IGUs), due to their low gas permeability), in conformal coatings and for corrosion protection.

Growing community of inventors

Seneffe, Belgium

Victor Baily