Ifp Energies Nouvelles

Centre National De La Recherche Scientifique

Cnrs

Cpe Lyon Fcr

Veronique Dufaud

Alexandra Chaumonnot

Audrey Bonduelle

Karin Marchand

Manuela Bader

Frederic Lefebvre

Susana Lopes Silva

Jean-Marie Basset

Magalie Roy-Auberger

Elodie Devers

A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HXMO), wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.

Process for hydrodesulphuration of gasoline cuts using a catalyst based on heteropolyanions trapped in a mesostructured silica support

The invention relates to a process of hydrodesulphuration of at least one gasoil cut implementing a catalyst containing, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HXMO), said polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size within the range 1.5 to 50 nm and having amorphous walls of thickness within the range 1 to 30 nm, the said catalyst being sulphured before being implemented in the said process.

Process for Hydrodesulphuration of gasoil cuts using a catalyst based on heteropolyanions trapped in a mesostructured silica support

A process for the hydrocracking a hydrocarbon-containing feedstock in which at least 50% by weight of the compounds have an initial boiling point above 340&#xb0; C. and a final boiling point below 540&#xb0; C., using a catalyst having, in its oxide form, at least one metal selected from the metals of groups VIB, VIII and VB, said metals being present in the form of at least one polyoxometallate of formula (HXMO), said polyoxometallates being present within a mesostructured matrix based on oxide of at least one element Y, said matrix having a pore size between 1.5 and 50 nm and having amorphous walls of thickness between 1 and 30 nm, said catalyst being sulphurized before used in said process.

Process for the hydrocracking of hydrocarbon cuts using a catalyst based on heteropolyanions trapped in a mesostructured oxide support

A method for converting a polymer or oligomer derived from an ethylenically unsaturated monomer into alkanes or into a hydrocarbon fraction or a lower oligomer fraction by controlled hydrocracking, wherein the polymer or oligomer is exposed to a catalyst based on a metal hydride or an organometallic complex supported on a mineral carrier, the complex having at least one hydrocarbon ligand and optionally at least one hydride ligand, and the resulting mixture is reacted with hydrogen to cause catalytic hydrocracking of the polymer or oligomer. The polymer or oligomer is broken down into reclaimable products with a lower molecular weight for use, e.g., in the field of polymers, particularly controlled molecular weight polymers, fuels or lubricants.

Process for controlled degradation of hydrocarbon polymers

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Villeurbanne, France

Veronique Dufaud