Ford Global Technolgoies, LLC

Venkataramani Anandan

Andrew Robert Drews

Daniel Murray

Chanyeop Yu

John Matthew Ginder

Theodore James Miller

Bryan William Boudouris

Mohan Karulkar

Zijie Lu

William Arthur Paxton

Andy Robert Drews

Matthew Denlinger

Siddhartha Akkiraju

Jung-Hyun Kim

Jung-Hyung Kim

A solid-state battery includes an anode, a cathode, and a solid electrolyte between the anode and cathode. The anode or cathode includes bonded active material particles having thereon a mixed ionic and electronic conducting conformal interface layer that provides a transport path for ions and electrons during operation of the solid-state battery, and lacks solid electrolyte particles.

Electrodes with active material particles having mixed ionic and electronic conducting layers thereon

A battery electrode material includes a composition of (A) a charge-conducting radical polymer, (B) poly[poly(ethylene oxide) methyl ether methacrylate] (PPEGMA); and (A) a lithium salt, the composition being a mixed ionic and electronic conductor with ionic conductivity at room temperature of at least about 10S/cm and electronic conductivity of at least about 10S/cm.

Polymer blends having mixed electronic and ionic conductive properties

According to one or more embodiments, a lithium-ion battery includes an anode including titanium niobium oxide (TNO) particles and solid electrolyte particles configured to form an interphase layer therebetween, a cathode including an active material, electronic conductor, and a non-solid electrolyte; and an ionically conductive and liquid-impermeable solid electrolyte separator. The solid electrolyte separator is in direct contact with and between the anode and cathode, and is configured to prevent reduction of the non-solid electrolyte by isolating the non-solid electrolyte from the TNO particles.

Hybrid electrolyte design for titanium niobium oxide based lithium battery

A solid-state battery comprises an anode in electrical contact with an anode current collector, including a first ionically conductive solid electrolyte material having a susceptibility to reduction in a presence of lithium metal such that, upon contact with lithium, the ionically conductive material partially reduces to a mixed ionic and electronic conductor including a partially reduced species, a cathode, and a separator positioned between and in ionic contact with the anode and cathode. The separator is formed of a second ionically conductive solid electrolyte material which is in contact with the first ionically conductive material but not susceptible to reduction in a presence of lithium metal and not soluble for the partially reduced species such that the separator has a susceptibility for migration of lithium ions from the mixed ionic and electronic conductor and impedes propagation or exchange of the partially reduced species from the mixed ionic and electronic conductor.

Solid state battery design with mixed ionic and electronic conductor

A solid-state battery includes a positive electrode, a negative electrode, and a separator between the positive and negative electrodes. The negative electrode includes reduced lithium titanate (LTO) particles and solid electrolyte particles. The negative electrode lacks electronically conductive additives.

Lithium titanate anode and fabrication method for solid state batteries

A Li-ion battery includes a cathode; an anode having a primary active material, conductive carbon, binder, and reserve material; and a separator between the cathode and anode. The reserve material has a reaction potential between a lithium reaction potential and a primary active material reaction potential. The reserve material is configured to intercalate with lithium at the reaction potential responsive to the primary active material being fully intercalated to inhibit lithium plating on the anode.

Electrode design for L-ion battery

According to one or more embodiments, a lithium-ion battery includes an anode including lithium titanate (LTO) particles and solid electrolyte particles configured to form an interphase layer therebetween, a cathode including an active material, electronic conductor, and a non-solid electrolyte; and an ionically conductive and liquid-impermeable solid electrolyte separator. The solid electrolyte separator is in direct contact with and between the anode and cathode, and is configured to prevent reduction of the non-solid electrolyte by isolating the non-solid electrolyte from the LTO particles.

Hybrid electrolyte design for lithium titanate based lithium ion battery

According to an embodiment, a lithium-ion battery includes a cathode, an anode, a separator between the cathode and anode, a current collector on the anode, and a layer of electronically conducting material between the anode and current collector. The layer of electronically conducting material is configured to, responsive to a potential of the battery crossing a phase-transition potential of the electronically conducting material, phase-transition from a conductor to an insulator to prevent dissolution of metal ions from the current collector into the anode.

Cell design to prevent over-discharge in li-ion batteries

A pre-sintered all-solid-state battery comprises a powdered lithium titanate (LTO), a powdered lithium lanthanum titanium oxide (LLTO), and a solid lithium compound configured to suppress formation of inactive phases during sintering. The solid lithium compound is about 0.5% to 10% by weight of the pre-sintered all-solid-state battery.

Composition for sintered lithium titanate-lithium lanthanum titanium oxide composite

A method of making a solid state battery may include heating a flux sandwiched between a solid ceramic electrolyte and a group one metal. The flux may be heated such that it roughens a surface of the solid ceramic electrolyte and the group one metal melts and adheres to the surface of the solid ceramic electrolyte.

Methods of manufacturing a solid state battery

A method of forming a solid state battery is disclosed. In a moisture-free inert atmosphere, the method includes combining unreacted solid electrolyte precursors to form a green sheet, stacking the green sheet in between porous electrodes to form a solid state battery, and heating the battery to a melting point temperature of the precursors such that the precursors form a liquid phase penetrating pores in the electrodes to form ion conducting channels in the battery.

Solid state battery

A method of producing a solid state battery includes pre-coating a solid electrolyte surface with a metal to form a sacrificial layer and contacting a metal alloy with the sacrificial layer such that the sacrificial layer and the metal alloy react to form a eutectic liquid metal interface layer, at room temperature and between the electrolyte and a lithium anode, configured to alloy with the liquid metal interface layer at operating potential.

A solid state battery includes a flexible polymer sheet, and an array of solid state pillars supported by and extending through the sheet. Each of the pillars has an anode layer, a cathode layer adjacent, and an inorganic solid electrolyte (ISE) layer interposed between the anode and cathode layers.

Flexible composite solid state battery

Rechargeable batteries (e.g., Li-ion) including hybrid liquid and solid electrolytes are disclosed. One embodiment of a battery may include an anode; a cathode; an ionically-conductive separator between the anode and cathode; and an electrolyte suspension including a plurality of solid electrolyte particles dispersed in a liquid electrolyte solution. The solid electrolyte particles may have an average size of up to 1 &#x3bc;m or 100 nm and the particles may comprise 5 to 95% by volume of the electrolyte suspension. In another embodiment, a plurality of solid electrolyte particles may be dispersed and embedded within a bulk of at least one of the anode, cathode or separator. In some embodiments, there may be a plurality of solid electrolyte particles in both suspension and embedded in the battery component(s). Replacing some of the liquid electrolyte with solid electrolyte may reduce the flammability of the electrolyte.

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Farmington Hills, MI, United States of America

Venkataramani Anandan