American Air Liquide, Inc.

L'air Liquide, Soci&#xe9;t&#xe9; Anonyme Pour L'etude Et L'exploitation Des Proc&#xe9;d&#xe9;s Georges Claude

Air Liquide Industrial U.S. LP

The United States of America, As Represented by the Secretary, Department of Health and Human Services

Air Liquide Canada, Inc.

Vasuhi Rasanayagam

Meenakshi V Sundaram

David C Braithwaite

Jan Mante

Midhun Joy

Rovshan Mahmudov

Siavash Isazadeh

Joerg Schwerdt

Meenakshi Sundaram

Stephen M Hewitt

Joon-Yong Chung

Michel Epiney

Timothy Lawrence Murray

Maicon Renan Neryz

Ivan Pajolli

Fabrice Laberge

Chunqiong Shi

Sagar D Joshi

Milson Carvalho

Camille Lanctot-Downs

Disclosed are decoupled systems and methods for producing an oxidized liquid. The method comprises the steps of generating an ozone strong water in a mass transfer unit, mixing the ozone strong water with a process liquid in a mixing unit to form a homogeneous and gas-free mixture of the ozone strong water and the process liquid, forwarding the homogeneous and gas-free mixture to a reaction unit, and producing the oxidized liquid in the reaction unit. The method utilizes the acidic feed liquid to generate ozone dissolved in water having a higher concentration at a saturated or nearly saturated concentration compared to prior art processes at atmospheric pressure and neutral or alkaline pH.

Separation of ozone oxidation in liquid media into three unit operations for process optimization

Disclosed are systems and methods for mixing a gas-free liquid oxidant with a process liquid to form a homogeneous and gas-free mixture with minimized degassing. The mixing system comprises an injection device, integrating with a pipe through which a process liquid flows, configured and adapted to inject a gas-free liquid oxidant into the process liquid, and a mixer, fluidly connected to the pipe and the injection device, configured and adapted to mix the process liquid and the gas-free liquid oxidant therein to form a homogeneous and gas-free mixture of the process liquid and the gas-free liquid oxidant with minimal degassing. The method comprises the steps of a). injecting the gas-free liquid oxidant into the process liquid, and b). mixing the gas-free liquid oxidant and the process liquid to form the homogeneous and gas-free mixture. The gas-free liquid oxidant is ozone strong water.

Method for mixing gas-free liquid oxidant with process liquid

Disclosed are methods for continuous production of ozone strong water, the methods comprising the steps of injecting an acidification agent into a pressurized feed water to maintain a pH value of the pressurized feed water below 7, diffusing a two-phase mixture of O-Ogas and recirculated water into a body of acidic pressurized water to dissolve ozone into the acidic pressurized water. The disclosed methods include simultaneously maintaining a start-up mode in an upper portion of the dissolution column that favors high efficiency of ozone mass transfer into the acidic pressurized water and a steady state mode in a lower portion of the dissolution column that favors a high concentration of dissolved ozone in the acidic pressurized water coexistent in the body of the acidic pressurized water, wherein an ozone concentration gradient is formed along a height of the body of the acidic pressurized water.

Methods for producing high-concentration of dissolved ozone in liquid media

Disclosed are systems for continuous production of ozone strong water, the systems comprising an injection device that injects an acidification agent into a pressurized feed liquid, a diffuser device that injects ozone into a body of the acidic pressurized feed water, and injection nozzles each controlled by a valve that adjust a flow rate of the ozone strong water discharged from a dissolution column to match a flow rate of the acidic pressurized feed water fed to the dissolution column, thereby maintaining a start-up mode in an upper portion of the dissolution column that favors a high efficiency of ozone mass transfer and a steady-state mode in a lower portion of the dissolution column that favors a high dissolved ozone concentration coexistent in the body of the acidic pressurized liquid, wherein a concentration gradient of dissolved ozone is formed along a height of the body of the acidic pressurized liquid.

Systems for producing high-concentration of dissolved ozone in liquid media

A device and method for injection of oxygen-rich gas into a body of liquid with oxygen recycling are disclosed. The device comprises a rotary hollow shaft vertically passing through a float partially immersed in the liquid, an impeller attached to the lower end of the rotary hollow shaft, a columnar structure, surrounding the rotary hollow shaft, mounted on the bottom side of the float and vertically extending into the liquid, a gas diffusion chamber formed by the columnar structure, the float and the liquid surface under the float, and a gas injection conduit passing through the float for delivering the oxygen gas into the gas diffusion chamber, wherein a vacuum is generated in the body of the liquid around the impeller when the impeller is driven to rotate, so that the oxygen-rich gas in the gas diffusion chamber is sucked into the body of the liquid and mixed therein.

Gas injection and recycling apparatus and methods

The invention may be broadly defined as the addition of Argon to FFPE procedures as an RNA stabilizing agent. Argon is an inert gas from the Noble gas group with low saturation concentrations in water. It is therefore highly surprising that Argon would have any effect on RNA stability in the presence of Formalin, or any other chemical. This property of Argon appears to be specific in that other inert gases fail to show any RNA stabilizing effect.

Use of argon as a tissue fixation preservative

The present invention is a cryogenic subterranean fracturing fluid, comprising a liquefied industrial gas and a viscosity increasing additive. The liquefied industrial gas may be liquefied carbon dioxide, liquefied nitrogen, or a blend of the two. The liquefied industrial gas mixture should be substantially free of water. In this context, substantially free of water means less than 10% water by volume, or preferably less than 5% water by volume. In addition to the viscosity increasing additive, a proppant may be added to the fracturing fluid. In addition to the viscosity increasing additive and/or proppant additional additives may be added to the liquefied industrial gas as required.

Hydraulic fracturing with improved viscosity liquefied industrial gas based solution

Embodiments of the invention generally provide methods and systems that distribute an additive in solid carbon dioxide in an interior of food processing equipment. The additive may be injected into a flow of liquid carbon dioxide upstream of an expander at or adjacent to the interior. Injection of the additive into the interior may be alternated with directing a flow of expanded carbon dioxide into the interior. In some embodiments, the freezing point of the additive with or without a diluent composition and/or additive(s) is lower than a temperature of the liquid carbon dioxide.

Method and system for treating food items with an additive and solid carbon dioxide

An improved process for peeling hard boiled eggs includes contacting the cooked egg with a cold inert gas before peeling.

Shelling of cooked eggs

A CO-containing modified atmosphere packaging (MAP) gas is generated from a processing gas including COand an optional inert gas by applying an electric field under conditions sufficient to generate non-thermal plasma. The fresh appearance of meat or seafood is maintained for a longer time by storing them in a container with the MAP gas.

Plasma generation of CO for modified atmosphere packaging

A liquid additive is sprayed over liquid nitrogen to form discrete solid particles of the additive in liquid nitrogen. The mixture of additive particles and liquid nitrogen is mixed with a flow of liquid nitrogen at an eductor pump to provide a food treatment composition comprising additive particles. The food treatment composition flows into an interior of food processing equipment to come into contact with food items contained therein.

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Newark, DE, United States of America

Vasuhi Rasanayagam