Alliedsignal Inc.

Celanese Engineering Resins, Inc.

Allied Corporation

Hoechst Celanese Corporation

Gaf Corporation

Varkki P Chacko

Gerald A Baum

Donald F Stewart

Mocherla K Rao

Paul DeStio

Michael F Tubridy

George M Johns

Timothy J Kraft

Arie A Hochberg

Nylon compositions useful for molding and film applications with film properties and impact strength are made of a polyamide resin and a block copolymer of poly(amide-ether) of the formula ##STR1## where R is an alkyl or substituted alkyl group with from one to 12 carbons, n is an integer from 2 to 20, m is an integer from 2 to 6, and x and y are numbers from about 50 to about 30,000. In one embodiment, a nonpolymeric amide is added to the composition. Articles made from the claimed compositions have improved impact strength; films made from the compositions have improved drapeability over the unmodified resin, both at room temperature and after heat-aging. Reinforced compositions are obtained by including mineral and other reinforcing fillers, including glass fibers, in the extrusion process. The reinforced compositions exhibit improved impact characteristics.

Glass fiber reinforced nylon compositions comprising poly(amide-ether)

Nylon compositions useful for molding and film applications with film properties and impact strength are made of a polyamide resin and a block copolymer of poly(amide-ether) of the formula ##STR1## where R is an alkyl or substituted alkyl group with from one to 12 carbons, n is an integer from 2 to 20, m is an integer from 1 to 6, and x and y are numbers from about 50 to about 30,000. In one embodiment, a non-polymeric amide is added to the composition. Articles made from the claimed compositions have improved impact strength; films made from the compositions have improved drapeability over the unmodified resin, both at room temperature and after heat-aging. Reinforced compositions are obtained by including mineral and other reinforcing fillers, including glass fibers, in the extrusion process. The reinforced compositions exhibit improved impact characteristics.

Polyamide compositions comprising poly(amide-ether) block copolymers

Nylon compositions useful for molding and film applications with film properties and impact strength are made of a polyamide resin and a block copolymer of poly(amide-ether) of the formula ##STR1## where R is an alkyl or substituted alkyl group with from one to 12 carbons, n is an integer from 2 to 20, m is an integer from 2 to 6, and x and y are numbers from about 50 to about 30,000. In one embodiment, a non-polymeric amide is added to the composition. Articles made from the claimed compositions have improved impact strength; films made from the compositions have improved drapeability over the unmodified resin, both at room temperature and after heat-aging. Reinforced compositions are obtained by including mineral and other reinforcing fillers, including glass fibers, in the extrusion process. The reinforced compositions exhibit improved impact characteristics.

Nylon compositions with superior film properties and impact strength

A thermoplastic molding composition comprising a polyester blend of polybutylene terephthalate and a copolyester derived from condensing ethylene glycol, cyclohexanedimethanol and terephthalic acid wherein the ethylene glycol units of the copolyester comprises at least 25 mole % based on the total glycol content. The polyester blend can also include an impact modifier. The blend is useful in the formation of molded keycaps.

Polyester molding composition

Polyester molding composition containing polybutylene terephthalate, nucleated polyethylene terephthalate or mixtures thereof as well as thermally stable reinforcing fibers and polyphenylene sulfide having a melt flow rate of less than about 1,000.

High temperature resistant polyester compositions

Poly(C.sub.2 -C.sub.4 alkylene terephthalate) molding composition containing aromatic polyester carbonate and impact modifier. The aromatic polyester carbonate is derived from a dihydric phenol, a carbonate precursor and dicarboxylic acid or ester forming derivative thereof. The impact modifier may be a core-shell polymer polymerized from monomers comprising butadiene or may be a core-shell polymer having a first elastomeric phase polymerized from a monomer system including C.sub.1 -C.sub.6 alkylacrylate as well as crosslinking and graftlinking monomers and having a final rigid thermoplastic phase polymerized in the presence of the elastomeric phase.

Modified polyester compositions

Poly(C.sub.2 -C.sub.4 alkylene terephthalate) molding composition containing aromatic polyester and impact modifier. The aromatic polyester is a linear aromatic polyester consisting essentially of bisphenol and dicarboxylic acid monomer components. The impact modifier may be a core-shell polymer polymerized from monomers comprising butadiene or may be a core-shell polymer having a first elastomeric phase polymerized from a monomer system including C.sub.1 -C.sub.6 alkylacrylate as well as crosslinking and graftlinking monomers and having a final rigid thermoplastic phase polymerized in the presence of the elastomeric phase.

Polyester compostions

A composition comprising a polyamide, a reinforcing amount of glass fiber, and 1 to 25, preferably 5 to 25, and more preferably 10 to 20 percent by weight based on the weight of the polyamide of a core/shell polymer. The core/shell polymer comprises 40 to 90 and preferably 50 to 90 parts by weight of an elastomer core and 10 to 60 and preferably 10 to 50 parts by weight of a rigid thermoplastic polymer shell. The shell comprises an interpolymer of 20 to 100 parts by weight of an methyacrylic ester, 0 to 80 parts by weight styrene, and from 0 to 50 parts by weight of acylonitrile. The shell can also contain alkyl acrylates, allyl methacrylates, diallyl methacrylates, and the like. The methacrylic ester is preferably a lower alkyl methacrylate/such as methyl methacrylate. The core is an elastomer and can be a diene elastomer, an ethylene-propylene-diene rubber, an acrylic elastomer, or a polyurethane elastomer.

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Summit, NJ, United States of America

Varkki P Chacko