Korea Institute of Science and Technology

Van Dung Do

Won Il Cho

Mun Sek Kim

In Wook Nah

In Hwan Oh

Min Seop Kim

Seung Hun Lee

An artificial solid electrolyte interphase (ASEI) of an anode for a secondary battery includes a first film composed of amino-functionalized, reduced graphene oxide (rGO) that is amino-functionalized by binding with polyethyleneimine present in an amount of from 1 to 50% by weight, based on total weight of the amino-functionalized, reduced graphene oxide (rGO) and that is disposed in contact with an anode material to protect the anode material; and a second film comprised of amino-functionalized, multi-walled carbon nanotubes that is amino-functionalized by binding with polyethyleneimine and that is stacked on the first film. An anode of a secondary battery including the ASEI enables rapid diffusion and stable deposition of lithium to inhibit the formation of dendrites. In a secondary battery including the anode, the ASEI prevents side reactions between a lithium metal anode and the electrolyte, achieving good electrochemical stability and high Coulombic efficiency.

Artificial solid electrolyte interphase of a metallic anode for a secondary battery including amino-functionalized carbon structures to protect the anode material, a method for producing the anode and a lithium metal secondary battery including the anode produced by the method

The present disclosure relates to an aqueous binder for a lithium-sulfur secondary battery, a method for preparing the same, and a lithium-sulfur secondary battery including the same. More particularly, it is possible to obtain an aqueous binder (PEI/PVP/CA, PPC) by adding citric acid to a mixed solution of polyethylene imine with polyvinyl pyrrolidone, and to apply the aqueous binder to a lithium-sulfur secondary battery having high discharge capacity, Coulombic efficiency and stable life characteristics through the improvement of adhesion capability even at a sulfur cathode with high energy density, inhibition of a shuttle reaction and inhibition of metal current collector corrosion.

Aqueous binder for lithium-sulfur secondary battery, preparation method thereof and lithium-sulfur secondary battery comprising the same

An anode includes a thin film of an anode material; and a protective layer that is formed on the thin film of the anode material, that is composed of functionalized metal oxide nanoparticles, which are lithium-terminated sulfonated metal oxide nanoparticles, and that has a thickness of 300-5000 nm. A method for manufacturing the anode includes dispersing the functionalized metal oxide nanoparticles into a dispersion medium to form a dispersion; dipping a substrate into water, and introducing the dispersion thereto so that the functionalized metal oxide nanoparticles form a self-assembled molecular film on the water surface; lifting the substrate over the water surface to transfer the self-assembled molecular film onto the substrate, thereby providing a substrate coated with a functionalized metal oxide film; and transferring the functionalized metal oxide film onto the thin film of the anode material to provide an anode coated with the functionalized metal oxide film.

Anode including functionalized metal oxide nanoparticles, a method for manufacturing the anode, a secondary battery including the anode, and a device including the secondary battery

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Van Dung Do