Basf Corporation

Valeri L Valoppi

Elizabeth S Bredeson

Joe C Wilson

Donald L Christman

Richard P Harrison

Oscar M Grace

It has been found that non-chlorinated pentafluoropropane blowing agents may be used alone or in combination with water in flexible integral skin foams. For example, foams prepared from a resin blend incorporating 1,1,1,3,3-pentafluoropropane (HFA-245fa) alone or in combination with water exhibit physical characteristics such as resistance to abrasion and cracking on flex comparable to conventional chlorinated fluorocarbon blown foams. Such foams made using the resin blend of the present invention are suitable for use in many applications including, for example, shoe soles.

Pentafluoropropane blowing agent-containing resin blend for use in making integral skin foams

It has been found that non-chlorinated pentafluoropropane blowing agents may be used alone or in combination with water in a method of making flexible integral skin foams. For example, foams prepared using 1,1,1,3,3-pentafluoropropane (HFA-245fa) alone or in combination with water exhibit physical characteristics such as resistance to abrasion and cracking on flex comparable to conventional chlorinated fluorocarbon blown foams. The method of the the present invention produce foams which are suitable for use in many applications including, for example, shoe soles.

Method of making a low density, molded integral skin polyurethane foam

It has been found that non-chlorinated pentafluoropropane blowing agents may be used alone or in combination with water in flexible integral skin foams. For example, foams prepared using 1,1,1,3,3-pentafluoropropane (HFA-245fa) alone or in combination with water exhibit physical characteristics such as resistance to abrasion and cracking on flex comparable to conventional chlorinated fluorocarbon blown foams. The foams of the present invention are suitable for use in many applications including, for example, shoe soles.

Integral skin foams employing pentafluoropropane blowing agents

It has been found that 1,1,1,2-tetrafluoroethane (HFC-134a) may be used alone or in combination with water as blowing agents in flexible integral skin foams. Foams prepared using HFC-134a alone or in combination with water exhibit physical characteristics such as resistance to abrasion and cracking on flex comparable to conventional chlorinated fluorocarbon blown foams. The foams of the present invention are suitable for use in shoe sole applications.

1,1,1,2-tetrafluoroethane as a blowing agent in integral skin

The invention pertains to polyol compositions containing a lithium salt of an aliphatic or cycloaliphatic, saturated or unsaturated carboxylic acid having 2 to 7 carbon atoms and to flexible polyurethane foams having an open cell structure produced thereby.

Lithium-based salts in flexible foams

It was found that a combination of thermoplastic microspheres containing a volatile hydrocarbon and water could be used as effective co-blowing/density reducing agents in low density, integral skin polyurethane foams.

Low density flexible integral skin polyurethane systems using

The present invention relates to integral skin foams prepared without using halogenated hydrocarbons as blowing agents. The foams of the present invention are prepared using water and volatile silicone fluids as co-blowing agents. Useful silicone agents have boiling points at on below 100.degree. C.

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Riverview, MI, United States of America

Valeri L Valoppi