Dow Global Technolgoies LLC

Arkema France

Rohm and Haas Company

Tuoqi Li

Wenwen Li

Thorsten Schmidt

Joseph James Zupancic

Yinzhong Guo

Jie Wu

Matthew Martin Yonkey

Paul G Clark

Stephen W King

Xue Chen

Ken Kawamoto

Kalyan Sehanobish

Rui Xie

Daniele Vinci

Elodie Hablot

Sudhanwa D Dewasthale

Marco Frasconi

Jian Wang

Kristy Brown

An epoxy terminated polyester; an adhesive formulation including the epoxy terminated polyester and a curative composition; a laminating adhesive prepared from the above adhesive formulation; a process of making a laminate; a laminate made by the above process; and a flexible package prepared from the above laminate.

Isocyanate-free laminating adhesive

Two-component solventless polyurethane adhesive compositions are disclosed comprising an isocyanate component comprising an isocyanate, and a polyol component comprising an amine-initiated polyol comprising two or more primary hydroxyl groups and a backbone incorporating tertiary amines, wherein the amine-initiated polyol comprises a functionality of from 2 to 12, a hydroxyl number of from 5 to 1,830, and a viscosity at 40° C. of from 500 to 20,000 mPa-s, and a silicone-based additive (e.g., an anti-foaming agent and/or a wetting agent). The adhesive compositions are formulated such that the isocyanate and polyol components can be applied to separate substrates prior to mixing. Laminate structures comprising the disclosed adhesive compositions and further comprising a metal or metallized substrate are also disclosed.

Two-component solventless adhesive compositions for adhesion to metal and/or metallized substrates

Water-based compositions that include a reaction product formed by reacting a polyol and an aminopolycarboxylic compound are discussed herein. The water-based compositions can include an isocyanate.

Water-based compositions

A polyolefin-based laminating adhesive composition for use in producing a mechanical recyclable material, the adhesive composition including a mixture of: (a) at least one saturated polyolefin polyol; and (b) at least one aliphatic multi-functional isocyanate compound; a process for producing the above adhesive composition; a mechanically recyclable multi-layer laminate including: (A) at least one first film substrate layer; (B) at least one second film substrate layer; and (C) at least one layer of the above polyolefin-based laminating adhesive composition; wherein the at least one first film substrate layer is bonded to the at least one second film substrate layer via the adhesive composition layer; a process for producing the above mechanically recyclable multi-layer laminate; and a packaging article made from the above mechanically recyclable multi-layer laminate.

Recyclable laminate

Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.

Epoxy phosphate ester

The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component; and (B) a polyol component containing (i) a polyester-polycarbonate polyol and (ii) a phosphate-terminated polyol. The present disclosure also provides a method of forming the two-component solvent-less adhesive composition.

Two-component solvent-less adhesive composition

The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component and (B) a polyol component containing a poly-ester-amide polycarbonate polyol. The present disclosure also provides a method of forming a two-component solvent-less adhesive composition.

Embodiments of the present disclosure are directed towards solvent-based compositions that include a reaction product formed by reacting a polyol and an aminopolycarboxylic compound.

Solvent-based compositions

The present disclosure provides a two-component solvent-based adhesive composition. The two-component solvent-based adhesive composition contains the reaction product of (A) an isocyanate component; (B) a polyol component containing a polyester-amide polycarbonate polyol; and (C) a solvent. The present disclosure also provides a method of forming the two-component solvent-based adhesive composition.

Two-component solvent-based adhesive composition

The disclosed adhesive compositions comprise (A) an isocyanate component comprising an isocyanate-terminated prepolymer that is the reaction product of a polyisocyanate and an isocyanate-reactive mixture comprising a phosphate ester polyol. The disclosed adhesive compositions further comprise (B) an isocyanate-reactive component polyol component comprising a polyol. In some embodiments, methods for preparing two-component adhesives formulations are disclosed comprising preparing an isocyanate component comprising an isocyanate-terminated prepolymer by reacting a polyisocyanate with an isocyanate-reactive mixture comprising a phosphate ester polyol and preparing an isocyanate-reactive component comprising a polyol. The methods further comprise mixing the isocyanate component and the isocyanate-reactive component at a stoichiometric ratio (NCO/OH) of from about 1.0 to about 5.0. Methods for forming laminate structures, and the laminate structures themselves, are also disclosed.

Growing community of inventors

Lake Jackson, TX, United States of America

Tuoqi Li