Fuji Photo Film Company, Limited

Tsutomu Hamaoka

Masakazu Morigaki

Nobutaka Ohki

Satoru Sawada

Kotaro Nakamura

Motohiko Tsubota

Junkichi Ogawa

Osamu Takahashi

Hiroshi Hayashi

Tetsuro Kojima

Minoru Sakai

Minoru Yamada

Shinzo Kishimoto

Kazunori Hasebe

Takayoshi Kamio

Isao Shimamura

Yosuke Nakajima

Yasuo Kasama

Tooru Harada

Eiji Imatomi

Tsuyoshi Ogawa

A color diffusion transfer photographic element comprising (a) a light sensitive component containing at least one light sensitive silver halide emulsion layer associated with a dye releasing redox compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b) and (c) containing a diffusible hydroquinone type compound having the half wave potential of polarography in the range of from -300 mV to -380 mV measured using a saturated calomel electrode as a reference electrode in a buffer solution having a pH of 13.0.degree. at 25.degree. C. The diffusible hydroquinone type compound has excellent gradation control properties and is particularly suitable for controlling gradation of the toe part in a photographic characteristic curve of a color diffusion transfer photograph. A typical example of a diffusible hydroquinone compound of the invention is: ##STR1##

Color diffusion transfer element with hydroquinone type compound

A color diffusion transfer photographic element is disclosed, comprising (a) a photosensitive component containing at least one photosensitive silver halide emulsion layer combined with a DRR compound, (b) a dye image receiving component and (c) an alkaline processing composition component, wherein the improvement comprises at least one of said components (a), (b), and (c) containing a compound represented by the formula (I) ##STR1## wherein R represents a substituted or unsubstituted alkyl group having from 1 to 18 carbon atoms.

Color diffusion transfer photographic element

A photographic print prepared by a color diffusion transfer process comprising at least a support, a mordant layer containing therein a diffusion transfer dye image, and a white reflection layer constituting the background of the dye image and containing therein at least one compound represented by formula (I): ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 may be the same or different and each represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, an aralkyloxy group, an alkenyl group, an alkenyloxy group, an alkylthio group, an arylthio group, an acyl group, an acylamino group, a diacylamino group, an alkylamino group, a sulfonamido group, an acyloxy group, an alkoxycarbonyl group, or an aryloxycarbonyl group, and A represents a non-metallic atom group necessary for forming a 5- or 6-membered ring.

Photographic prints by color diffusion transfer process

A color photographic silver halide light-sensitive material is described comprising a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.3 can each represent an unsubstituted or substituted alkyl group or an unsubstituted or substituted aryl group, R.sup.2 can represent an unsubstituted or substituted alkyl group, R.sup.4 and R.sup.5 can each represent a hydrogen atom, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aryloxy group, an unsubstituted or substituted alkylthio group, an unsubstituted or substituted arylthio group, a halogen atom, or an acylamino group, and R.sup.1 and R.sup.2, R.sup.1 and R.sup.4, or R.sup.2 and R.sup.5 together can represent atoms forming a condensed ring structure together with the benzene ring of formula (I), provided that the total of carbon atom numbers in R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is at least 16.

Color photographic sensitive material with sulfonamidophenol scavenger

A process for forming photographic images comprising a silver image and a dye image, comprising development processing an imagewise exposed silver halide photographic light-sensitive material containing a 4-alkoxy-1-naphthol represented by the formula (I) ##STR1## wherein R represents an alkyl group, an alkoxyalkyl group, or a hydroxyalkyl group, and the number of carbon atoms in the substituent represented by R is from 1 to 4. The process of this invention is particularly useful in the field of X-ray photography, in order to provide an image of increased density for a given silver content. A novel silver halide photographic light-sensitive material includes the above 4-alkoxy-1-naphthol in a photographic colloid layer thereof, preferably the silver halide emulsion layer.

Process for forming photographic images and photographic light-sensitive

A compound represented by the structural formula: ##STR1## is representative of the compounds disclosed which are utilized within the silver halide layer of photographic light-sensitive materials. The compounds aid in preventing the fading of dye images which are formed by development of color photographic light-sensitive materials as well as aiding in the prevention of discoloration of non-developed areas. The effects of the compounds are particularly noticeable when utilized in combination with magenta couplers or cyan couplers, and other antifading agents in an amount of 2 to 150% by weight based on the weight of the couplers.

Color photographic light-sensitive materials

A silver halide photographic light-sensitive material is described comprising a support having thereon at least one light-sensitive silver halide emulsion layer, said silver halide emulsion layer containing a rhodium salt in an amount sufficient to increase a contrast thereof, and said silver halide emulsion layer or a layer adjacent thereto containing a compound represented by the following formula (I) or (II), and a process for producing a silver halide photographic emulsion containing rhodium salts is also described which comprises adding a rhodium salt into a silver halide photographic emulsion in an amount sufficient to increase a contrast before the conclusion of first ripening and adding a compound represented by the following formula (I) or (II) into the resulting emulsion after washing to remove useless salts ##STR1## wherein R.sub.1 represents hydrogen or a substituted or unsubstituted alkyl group. The silver halide photographic light-sensitive material and a silver halide photographic emulsion each is capable of providing high contrast images and stabilized photographic properties; particularly, gradation properties remain stable during storage.

Silver halide photographic light-sensitive material and process for

Silver halide photographic materials providing wash-off relief images and having excellent shelf life comprising a support having formed thereon at least a silver halide photosensitive emulsion layer and said silver halide emulsion layer or another hydrophilic colloid layer containing a polyhydroxy-spiro-bis-chroman tanning developing agent and a gallic acid alkyl ester is disclosed with a process forming relief images.

Silver halide photographic materials and a process forming relief images

A color photographic light-sensitive material comprising a support having thereon a silver halide emulsion layer containing a 3-anilino-5-pyrazolone type magenta coupler and at least one of the compounds represented by the formula (I) ##STR1## wherein R.sub.1 and R.sub.2 represent each a tertiary alkyl group having 4 to 20 carbon atoms.

A silver halide color photographic light-sensitive material which contains a 3-anilino-5-pyrazolone type of magenta coupler and a novel dye image-stabilizing agent of the general formula (I) as hereinafter defined.

Color photographic light-sensitive material

A color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, a non-diffusible color coupler present in at least one layer on the support and a layer containing at least one compound represented by the following general formula (I) ##STR1## wherein R.sub.1 represents an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group or an alkylsulfonamidoalkyl group; R.sub.2 represents an alkyl group, a hydroxyalkyl group, an alkoxyalkyl group or an alkylsulfonamidoalkyl group, R.sub.3 represents a hydrogen atom, an alkyl group or an alkoxyalkyl group, and R.sub.4 and R.sub.5, which may be the same or different, each represents a hydrogen atom, a halogen atom, a carboxyl group, a sulfo group, a nitro group, a carboxylic acid ester group, an alkyl group or an alkoxyalkyl group.

Color photographic light-sensitive material containing development

A method for processing a silver halide color photographic light-sensitive material which comprises developing an image-wise exposed silver halide color light-sensitive material in the presence of (a) an aromatic primary amine color developing agent, (b) hydroxylamine or a hydroxylamine derivative, and (c) a 1-aryl-3-pyrazolidone derivative containing two substituent groups at the 4-position thereof.

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Minami-ashigara, Japan

Tsutomu Hamaoka