Raychem Limited

Travers K Cammack, Ii

David D Nyberg

Bernard J Lyons

Nicodemus E Boyer

New high voltage insulating compositions are disclosed. The compositions comprise a polymer (e.g. a polysiloxane, epoxide resin or a polymer of one or more olefins or substituted olefins), an antitracking additive (e.g. an alumina hydrate), and certain phosphorus-containing compounds which have been found to provide the compositions with greatly improved resistance to erosion by high voltage stress. The phosphorus-containing compounds include phosphonates, phosphates, phosphites, phosphinates, phosphonites, phosphinites, phosphine oxides and sulfides, and phosphines, and salts and complexes thereof. The phosphorus-containing compound can react in situ with the polymer or other ingredients of the composition.

High voltage insulating compositions containing phosphorus compounds

New high voltage insulating compositions are disclosed. The compositions comprise a polymer (e.g. a polysiloxane, epoxide resin or a polymer of one or more olefins or substituted olefins), an antitracking additive (e.g. an alumina hydrate), and certain organic polymerizable phosphorus-containing compounds which have been found to provide the compositions with greatly improved resistance to erosion by high voltage stress. The phosphorus-containing compounds include phosphonates, phosphates, phosphites, phosphinates, phosphonites, phosphinites, phosphine oxides and sulfides, and phosphines, and salts and complexes thereof. The phosphorus-containing compound can react in situ with the polymer or other ingredients of the composition.

High voltage insulating compositions containing organic polymerizable

An improved high voltage insulating material comprising one or more polymers and an anti-tracking and erosion inhibiting composition comprising a hydrate of alumina and one or more compounds selected from the groups consisting of nickel phosphate, phosphinic acid or a derivative thereof, phosphonous acid or a derivative thereof, and phosphonic acid or a derivative thereof. The composition functions to prevent failure by tracking and to substantially retard failure by erosion.

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Bartlesville, OK, United States of America

Travers K Cammack, Ii