Toray Plastics (america), Inc.

Anagram International, Inc.

Toray Plastics, Inc.

Tracy Paolilli

John Fitch

Steven J Sargeant

Paul Andrew Ansolabehere

Todd Richard Sarnstrom

Nao Yokota

Joshua R Cloutier

Scott Narkevicius

Gianfranco Chicarella

Dean Borchardt

Bonnie Adams

Keunsuk P Chang

Matthew H Brown

Shichen Dou

Harold Egon Koehn

Yu Abe

Jan K Moritz

Douglas James Bower

Robert T Ervolino

Roberto Siu

G Vincent Sharps, Jr

Larissa M Boutin

Delaware Hood

Samuel Hogan

Michael F Brandmeier

Embodiments relate to a film comprising a base layer comprising a biaxially oriented polypropylene (BOPP); a coating layer comprising a polyester, an acrylic, and a crosslinker; and a primer; wherein the film has a haze change, measured according to ASTM D1003, before exposure to boiling water for 30 minutes and after exposure to boiling water for 30 minutes of 4 units or less.

Durable printable label film

The present invention relates to a polymeric film, which may have but is not limited to Biaxially oriented polyester, polypropylene & polylactic acid that has a soft-touch matte coating applied via an in-line coating process. This film also has an increased coefficient of friction of this surface, with a total thickness from 5 to 80 μm. The film of this invention has excellent suitability as external packaging bags with an excellent matte appearance and soft haptic feel which, when the bags are stacked A side to A side (A side being coated), are not subject to slippage between the same. At the same time, this film has also low friction with metal, so it is easy to handle the film in the film making process which contributes to the excellent productivity.

Soft matte non-silicone film

An in-line method to make a polymeric film with soft-feel haptic property includes the continuous, sequential steps of: (a) forming a polymer core layer of one or more polyesters; (b) optionally adding an adhesive layer and/or a skin layer over the polymer core layer to make a base layer; (c) stretching the base layer uniaxially in the machine direction; (d) coating the base layer with a liquid solution of a carbodiimide or polycarbodiimide crosslinker and a coating that includes aliphatic water-borne polyurethanes and one or more additives to enhance haptic properties, including urea-formaldehyde beads, aqueous wax dispersions and hollow sphere polymeric pigment dispersion; (e) heating the coated base layer to dry and crosslink the coating solution to form a coating layer on the base layer to create a coated film; (f) stretching the composite coated film in the transverse direction during or immediately following the drying and crosslinking step, and (g) optionally heat-treating the composite coated film to anneal the composite coated film.

In-line coating method for preparing soft-feel polymeric films and films prepared thereby

Described are transparent oriented polypropylene films with improved barrier properties and methods of making these films. The films and methods include a core layer comprising polypropylene, hydrocarbon resin, and polyethylene wax to improve moisture vapor barrier properties, an optional barrier layer comprising polar polymers to improve oxygen barrier properties, and optional skin layers to improve heat sealing, winding, printing, and/or adhesion.

Transparent oriented polypropylene film with high moisture vapor and oxygen barrier properties

This invention relates to an optically clear film of predominantly thermoplastic polyester base layer and a carbodiimide-crosslinked, polyester and polymethylmethacrylate blend primer layer. The base layer preferably has a particle-free core layer and outer layers containing nonpolyester, organic and/or inorganic particles. The primer layer is preferably applied to the base layer from solution that is organic solvent-free. The primer layer and base layer composite can be laminated with a protective layer of primarily acrylic polymer to form a solar control film. Functional additives, such as UV light blockers, can be present in various layers of the solar control film. Polymethylmethacrylate in the primer, especially in combination with crosslinking by the carbodiimide, provides the acrylic coated polyester base solar control film with notably reduced iridescence. Adhesion between the acrylic layer applied from organic solvent solutions and the polyester layers is durable in moist and warm service conditions.

Method of reducing iridescence

A metal transfer film of thermoplastic polymer includes a polymeric carrier film, a layer of metal to be transferred onto an article, and a layer of retention adhesive suitable for bonding the transferred metal layer to a surface of the article. The transferable metal layer is adjacent between the carrier film and the retention adhesive layer. Optionally, the carrier film has a releasably adhesive layer on the side in contact with the metal. The retention adhesive is a polyvinyl amine crosslinked with citric acid. The retention adhesive is deposited on the metal layer from a liquid solution and dried to a non-tacky, solid coating enabling handling of the metal transfer film in conventional film processing unit operations. The dry retention adhesive can be activated by the metal transfer operator remotely from the adhesive application process and provides significant oxygen, moisture and aroma barrier properties to the metal covered article.

Metal transfer film and method of using same

This invention relates to a highly optically clear, composite film having a predominantly thermoplastic polyester base layer and a primer layer of a polyester and polyurethane blend composition. The base layer preferably has an A/B/C layered structure with a substantially particle-free core layer B of polyester and outer layers A and C of polyester containing nonpolyester, organic and/or inorganic particles. The primer layer is preferably applied to the base layer from solution that is organic solvent-free and is crosslinked using a carbodiimide crosslinking agent. The primer layer and base layer composite can be laminated with a protective layer of primarily acrylic polymer for a solar control film. Various layers of the composite and solar control films can contain effective amounts of functional additives, such as UV light blockers. Polyurethane in the primer, especially in combination with crosslinking by the carbodiimide, provides the acrylic coated polyester base solar control film with notably reduced iridescence and durable adhesion between polyester and acrylic layers in moist and warm service conditions.

Method of making polyester film with a reduced iridescent primer layer

A composite barrier film has a base layer of polyester or polyolefin with a barrier layer modified polyvinyl amine (mPVA). The mPVA is polyvinyl alcohol/polyvinyl amine copolymer crosslinked with citric acid and an optional additional crosslinking agent such as epichlorohydrin. The barrier layer can be applied by deposition of a reactive aqueous solution onto the base layer, heating and drying to remove water and crosslink the reactants. Excellent barrier properties of the film are obtained by applying and crosslinking the barrier layer during the transverse stretching steps of a biaxial oriented polymer film continuous fabrication process. Superior barrier properties are achieved with transverse stretching by a factor of about 3-4 for polyester and 4-10 for polyolefin.

Citric acid-modified polyvinyl amine film

A composite barrier film has a base layer of polyester with a barrier layer modified polyvinyl amine (mPVA). The mPVA is polyvinyl alcohol/polyvinyl amine copolymer crosslinked with citric acid and an optional additional crosslinking agent such as epichlorohydrin. The barrier layer can be applied by deposition of a reactive aqueous solution onto the base layer, heating and drying to remove water and crosslink the reactants. Excellent barrier properties of the film are obtained by applying and crosslinking the barrier layer during the transverse stretching steps of a biaxial oriented polymer film continuous fabrication process. Superior barrier properties are achieved with transverse stretching by a factor of about 3-4.

Polyester film with citric acid-modified polyvinyl amine

Multi-layer films suitable as sealable or peelable sheet that can be used for closing foodstuff containers are described. These multi-layer films includes a polymeric substrate layer and a seal or a peel-seal layer. The multilayer composite film preferably includes four component layers, namely in order, a polymeric base layer for mechanical strength, a thin organic barrier layer, an ethylene polymer-based adhesive layer, and a heat seal layer including an ethylene copolymer, such as ethylene vinyl acetate copolymer. The film is useful as a peelable heat sealable lid for containers of diverse polymer compositions storing various products such as foodstuffs and pharmaceuticals.

Barrier lidding structure based on polypropylene film

A monoaxially oriented film including a metallized layer; a gas barrier layer; and a propylene-based random copolymer and at least about 3 wt % of a low density polyethylene which is oriented at least about 2.5 times in one direction and exhibits excellent linear directional tear properties parallel to the orientation direction and excellent heat seal performance in terms of high heat seal strengths and low seal initiation temperature. This film formulation and orientation is suitable for pouch applications requiring high gas and moisture barrier, an 'easy-tear' linear tear feature, and excellent hermetic seal properties.

High barrier heat sealable film with linear tear properties

A method is presented for making releasable transfer film suitable to provide a metalized embossed composite onto a paper substrate without a release layer between the composite and a polymeric carrier layer. The transfer film includes a polymeric base layer, an embossing material layer and a metal layer. The transfer film is bonded to the paper substrate with an adhesive layer allowing the polymeric barrier layer to peel away from and to expose the metal-backed, embossing material layer. The substrate covered with the metalized embossed composite can be used to impart holographic style images to packaging, printed media products such as magazines.

Method of making releasable metalized embossed transfer film

A moisture vapor and oxygen transmission resistant flexible film has a polymeric base layer and a barrier layer of discrete particles of a first organic polymer dispersed throughout a matrix of a second organic polymer. Preferably, the first and second polymers are water insoluble and water soluble, respectively. The barrier layer is formed by depositing onto the base layer a coating composition of finely divided insoluble organic polymer particles suspended in an aqueous solution of the water soluble organic polymer, a crosslinking agent and surfactant. The coating composition is heated to crosslink the barrier layer polymers and evaporate solvent to provide a barrier film suitable for packaging applications. Optionally, the film can be metalized to increase barrier properties.

Multilayer barrier film having coating composition with organic particles

A laminate film including a first polylactic acid layer; a second metal-receiving layer including PVOH, EVOH, or a blend thereof on a side of the first polylactic acid layer; and a metal layer deposited on a side of the metal-receiving layer opposite the polylactic acid layer. The metal-receiving layer may be coextruded with the polylactic acid first layer or may be a coating applied to one side of the polylactic acid first layer. This laminate film exhibits excellent gas and moisture barrier properties, appearance, and metal adhesion. It may also include a heat sealable or winding improving layer on the side opposite the metal receiving-layer of the first polylactic acid layer.

Multi-layer high moisture barrier polylactic acid film

Described are stretchable and formable lighter than air balloons including a high barrier lamination. The stretchable and formable balloons stretch when overinflated instead of failing. The balloons are formed from a lamination including a polyester film with a total thickness of 4 &#x3bc;m to 12 &#x3bc;m including a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The polyester film has an Elongation % in the transverse direction (TD) or machine direction (MD) of greater than 125%.

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East Greenwich, RI, United States of America

Tracy Paolilli